Sharif Digital Repository

In this investigation, silica-based iron-metal catalyst was synthesized by the Atomic layer deposited (ALD) method with iron-acetylate (Fe(acac)3) as a precursor in different loading dosages. The synthesized catalyst were characterized by nitrogen absorption and excretion (BET), by Field Emission Scanning Electron Microscope (FESEM), X-ray diffraction (XRD), and Temperature-Programmed Reduction (TPR), Fourier-transform infrared spectroscopy (FTIR), Atomic Emission Spectroscopy (ICP) etc.
The temperature range of 180 to 200 °C was determined for the self-limited chemisorption of Fe(acac)3 on the silica surface as the first and the most important step in a single atomic cycle. Also the... 

Computational grids consist of hardware and software infrastructures which can provide end users with the power of computational networks in a ubiquitous and cheaper manner. In fact, computational grids provide the ability to use the computational power of geographically distributed and heterogeneous resources. One of the new challenges facing researchers in this area involves security in grid environment which is somehow hard to achieve, because of the distributed nature of grid resources and fast changes in resource availabilities. Since availability, integrity and confidentiality are key factors of security and system’s fault tolerance capability is directly related to resource... 

One of the critical challenges in droplet based micro- and nanofluidic devices is handling the droplet breakup such that a controllable droplet size is produced. The experimental and numerical investigations at the microscale indicate that the droplet size can be well controlled by T junction geometries. In the present study we use non-equilibrium molecular dynamics (NEMD) simulations to investigate this phenomenon at the nanoscale. In order to generalize the study the Lennard-Jones type potential between the fluids and the walls have been considered and the strength and the effective range of the potential are changed to consider a wide variety of materials. Our results reveal that the... 

In this research, a general model is proposed aiming at establishment of optimized application of Methane gas with maximum added value. That is, maximum added value of methane for different applications of methane including consumption as fuel, export and injection-to-wells are calculated and compared. Accordingly, results of this study are used for decision making regarding Iran’s most important gas reservoirs. In this study, maximum present net value of investment concerning comparison of petrochemical industry input and export to a number of selected countries in addition to injection in 20 years is calculated based on a specific discount rate. It is noteworthy that the scope of this... 

In this thesis, first of all we introduce the Anderson model, Multifractality, and conformal field theory. Then we try to determine some critical and scaling quantities for the critical wave functions in the 2D systems with spin-orbit interactions We implement a correction-to-scaling analysis by introducing an irrelevant exponent which leads to a proper and sharp evaluation of the critical parameters including correlation exponent, rescaled localization length and the critical disorder. Then, we survey the multifractal properties of this model and obtain some multifractal exponent in the critical point. Finally, we will survey the existence of the conformal invariance symmetry in it. Our... 

Lately, some investigators of polymer engineering group are working to do continuous polymer solution casting process, rather than batch process for flat sheet membrane production. For this, they use a doctor blade system but, they faced some problems during coating process. From experimental observations of the studied system, some inappropriate vorticities were seen. That’s why the system forms a non-uniform film of the solution. Air bubbling occurs at system exit which is undesirable as well. In this study simulation and optimization has been done for forming thin film in doctor blade system. COMSOL Multiphysics 4.3b was used in purpose of simulating which works on numerical finite... 

Nowadays integrated circuits are extremely vulnerable to hardware trojans (HT). Hardware trojans can be injected into the ICs in design or fabricate phase, and damage system’s functionality or security. In this thesis, we first describe hardware trojan definition, classification and types of HTs, negative effects, detection ways and analysis of them. Then we propose a new solution in order to solve the negative points of previous methods  

In this project, two bidirectional loadcell are designed and fabricated to be installed on a walker. Then upper extremities’ forces and moments have been obtained. Results can be used for rehabilitation purposes in Spinal Cord Injuries and Cerebral Palsy cases. The method used in this project is as follows: First, since the commercial multidirectional loadcells are too expensive, the loadcell (and an appropriate electronic board) are fabricated. Ultimately, a complete gait analysis by means of VICON motion analysis and using inverse dynamic method has been held to measure upper extremities’ forces and moments in the wrist, elbow and shoulder. The results for a person with Spinal Cord Injury... 

In this study, the possibility of detecting known and unknown anomalies in a micro jet engine is evaluated. the proposed method is neural network and clustering analysis. The process consists of two main parts, first part is experimental abnormal behavior simulation and second part is validation of proposed detection method. In the first part a micro jet engine (Olympuse HP) were used and we created pre-designed errors in engine normal behavior to record significant changes in its performance. Recorded outputs consist of six different variables: RPM, Exhaust gas temperature, Throttle command, Fuel pump voltage, Thrust and Fuel weight. In the second part, for analyzing data, we used... 

Nearly 1.2 million people die in road crashes each year, and as many as 50 million are injured in the world. In Iran, approximately 800 thousand crashes occur annually killing up to 43 people per day. Given that over 90% of accidents are related to human factors, using models that incorporate driver’s attitudes and behavior can be highly predictive of crashes. The main objective of the current research is to examine the impact of drivers’ attitudes on road crashes along with other factors such as socio-demographic characteristics and vehicle type. This study uses data from a self-completed questionnaire among a representative sample of Iranian drivers living in Tehran. The Questionnaire... 

Our main goal in this project is to calculate the cell survival fraction (SF) in unhealthy tissue after carbon ion beams are emitted and hit the target tissue. At present, in the stages of carbon therapy, it usually takes a long time to make the necessary calculations for that particular person, and this makes the treatment process progress slowly, but in this project, we intend to address this problem with Eliminating the use of neural network. The main reason is the use of carbon ions to increase efficiency in the treatment of tumors and deep cancerous tissues. To do this project, we first convert the carbon ion energy to the dose absorbed at the desired point. For this phase of the... 

Various contaminants and their leachate, when they penetrate into the soil, cause changes in soil microstructure, this change in microstructure leads to changes in soil permeability and volume. In this study, first, the effects of soil microstructure change on the hydraulic conductivity of saturated soil were investigated using the change in initial saturation degree during compaction for compacted samples and the change in sample construction in reconstituted samples. Also, the simultaneous effect of changing the initial microstructure and salt solution on the hydraulic conductivity of saturated silty clay soils using a three-axial permeability device with the ability to measure volume... 

In today’s world, social networks have become one of the primary sources for the creation and propagation of news. Social news aggregators are one of the main actors in this area in which users create news items and use positive or negative votes to indicate their preference
toward a news item. This approach suffers from several problems raging from being prone to the dominance of a united adversary to difficulty in decerning between correct and fake new news and lack of incentive for honest behaviors. In this paper, we propose a graphbased news aggregator in which instead of voting on new items, users submit their votes on the relations between news items. This method of voting... 

Rough surfaces and growth process are the important and significant problems of theoretical and condensed matter physics to model phenomena ranging from the extremely small (biological phenomena) to largest one (Earth’s relief). Although the equations that describe these processes are well defined, but the question of how to characterize these surfaces which display large fluctuations, is open. The existence of (often) scale invariant clusters and very large fluctuations in surface growth process are reminiscent of critical fluctuations in equilibrium systems. Therefore, it is natural to try characterizing the surface by means of critical exponents, i.e., by the scaling dimensions of various... 

Due to special physical and mechanical properties of intermetallic compounds,somehow in between of the metallic and ceramic extremes, their applications are increased in different industries. Among these materials, titanium aluminides due to their low density, high specific strength and excellent corrosion and oxidation resistance has got more attention. Because of similar high temperature properties and lower density, these compounds are suitable alternatives for nickel base superalloys. Accumulative Roll Bonding (ARB) of pure metallic sheets and the following heat treatment in production of intermetallic compounds can be considered as a manufacturing process. The goal of this study is... 

Equal Channel Angular Pressing (ECAP) is one of the most applicable severe plastic deformation procedures (SPD) which results in improvement of strength and ductility through grain refinement. WE43 magnesium alloy belongs to a group of alloys for medical industry because of its good biocompatibility. In this study, equal channel angular pressing was performed at different temperatures, strain rates and number of passes on strip-shape samples to achieve proper mechanical properties. Tensile properties, hardness and microstructural evolutions were evaluated and the results were analyzed according to the EDS test. Results shows that at 380 ℃ and 440 ℃ grain refinement was accomplished by... 

The numerical solution of the parabolized Navier-Stokes (PNS) equations for accurate computation of hypersonic axisymmetric flowfield with real gas effects is obtained by using the fourth-order compact finite-difference method. The PNS equations in the general curvilinear coordinates are solved by using the implicit finite-difference algorithm of Beam and Warming type with a high-order compact accuracy. A shock fitting procedure is utilized in the compact PNS scheme to obtain accurate solutions in the vicinity of the shock. To stabilize the numerical solution, numerical dissipation term and filters are used. The main advantage of the present formulation is that the basic flow variables... 

Nowadays many of us spend a big part of our daily times on social media.One of the most important research problems in social media analysis is how to engage users. The trace of user activity over these websites is a valuable resource for user understanding and engagement, but this data is very huge and unstructured. An approach to deal with this problem is user behavior modeling. In this process, first a behavioral model is considered for users, then using the activity data and the behavioral model, some parameters are learned. Finally, using the learned parameters, a user profile is constructed for each user. This profile can be used for user engagement and many other applications....