Sharif Digital Repository

Esterification of Phthalic anhydride with 2-Octanol and Sebacic acid with Ethanol has been studied in the presence of Sulfated Titania. This study showed that Sulfated Titania has strong catalytic effect on esterification reactions. The effect of some factors such as reaction temperature, molar ratio of acid to alcohol, amount of catalyst used, reaction time, calcination temperature, drying temperature and calcination atmosphere has been investigated. Equilibrium composition achieved in 80 min for Diethyl Sebacate and 20 min for Dioctyl Phthalate in various conditions. © 2005 Elsevier B.V. All rights reserved  

Various ionic liquids (ILs) and their mixtures were coated on the Pt/Al2O3 catalyst and the resulting IL-coated catalysts were used in the synchronous hydrogenation of cyclohexene and acetone. The rate constant (k) and selectivity (S) toward CO hydrogenation were determined for several catalysts in various solvents. The solvatochromic parameters (ETN, normalized polarity parameter; π*, dipolarity-polarizability; β, hydrogen-bond acceptor basicity; α, hydrogen-bond donor acidity) were determined for the used ILs and solvents and the obtained selectivities were modeled based on the solvatochromic parameters of the IL layer and bulk solvent while using the Multiparameter Linear Regression (MLR)... 

Synchronous heterogeneous catalytic hydrogenation of cyclohexene and acetone, catalyzed by Pt/Al2O3, was carried out in solutions of 2-hydroxy ethylammonium formate (a room temperature ionic liquid, RTIL) with ethanol and propan-1-ol at 25 °C. Rate constants and selectivity of the reaction (relative to cyclohexene hydrogenation) increase with mole fraction of the ionic liquid (IL). The reactants tendency to the catalyst surface increases by addition of the ionic liquid and thus the reaction rate increases, especially for cyclohexene hydrogenation. Consequently the selectivity to cyclohexene hydrogenation was increased. Single-parameter correlations of log kvs.π* (dipolarity/polarizibility)... 

Structural and intermolecular interactions of solvatochromic probes 4-nitroaniline, 4-nitroanisole, and Reichardt’s dye were investigated in the binary mixtures of 2-hydroxy ethylammonium formate as an ionic liquid with N,N-dimethyl formamide, dimethyl amine, and dimethyl sulfoxide. Solvatochromic parameters (ETN, normalized polarity parameter; π*, dipolarity/polarizability; β, hydrogen-bond acceptor basicity; α, hydrogen -bond donor acidity) were determined in ionic liquid mixtures at 25 °C using UV−vis spectroscopy. ETN parameters obtained from absorbance of Reichardt’s dye within various mixtures of ionic liquid were observed to be higher than predicted values from ideal additive... 

Solvatochromic parameters (E T N , normalized polarity parameter; π, dipolarity/polarizability; β, hydrogen-bond acceptor basicity; α, hydrogen-bond donor acidity) have been determined for binary mixtures of propan-2-ol, propan-1-ol, ethanol, methanol and water with recently synthesized ionic liquid (IL; 2-hydroxyethylammonium formate) at 25 °C. In all solutions except aqueous solution, E T N values of the media increase abruptly with the ILs mole fraction and then increase gradually to the value of pure IL. A synergistic behavior is observed for the α parameter in all solutions. The behavior of π and β are nearly ideal for all solutions except for solutions of methanol with the IL. The... 

Synchronous heterogeneous catalytic hydrogenation of cyclohexene and acetone, catalyzed by Pt/Al2O3, was carried out in solutions of 2-hydroxy ethylammonium formate (a room temperature ionic liquid, RTIL) with ethanol and propan-1-ol at 25 °C. Rate constants and selectivity of the reaction (relative to cyclohexene hydrogenation) increase with mole fraction of the ionic liquid (IL). The reactants tendency to the catalyst surface increases by addition of the ionic liquid and thus the reaction rate increases, especially for cyclohexene hydrogenation. Consequently the selectivity to cyclohexene hydrogenation was increased. Single-parameter correlations of log k vs. π* (dipolarity/polarizibility)... 

Heterogeneous catalytic hydrogenation of cyclohexene, catalyzed by Pt/Al2O3, was carried out in solutions of 2-hydroxyethylammonium formate (a room temperature ionic liquid, RTIL) mixed with methanol, ethanol and propan-2-ol at 25 °C. The rate constants of the reaction in ionic liquid alcohol mixtures were higher than alcohol alone. First-order rate constant of the reaction in the RTIL relative to propan-2-ol is approximately 28. Furthermore, the rate constant of the reaction increases with the mole fraction of the ionic liquid. Single-parameter correlations of log k vs. normalized polarity parameter (ETN), hydrogen-bond acceptor basicity (β) and hydrogen-bond donor acidity (α) do not give... 

The oil-based compounds are widely used in modern human life, and the accidental release or leakage of these compounds is led to water and soil pollution and creates many problems for the environment. The purpose of this study was to determine the efficiency of photo-catalytic degradation of pyrene using Fe-doped TiO2 in the presence of UV. This experimental study was carried out at laboratory scale in a 2 L pilot reactor. The nanoparticle was synthesized by the sol-gel method. Pyrene degradation was investigated under different conditions of pH, reaction time, nanoparticle concentration and pollutant concentration. For the statistical analysis, SPSS V.16 software and one-way analysis of... 

The Weibel instability plays an important role in stopping hot electrons and energy deposition mechanism in fast ignition of inertial fusion process. In this paper, the ion Weibel instability in counter propagating electron-ion plasmas is investigate. The obtained results show that the growth rate of Weibel instability will be decreased about 40% with the anisotropy velocity as vxe = 2vze = 20; the ion density ratio, b = n0i1/n0i2, and density gradient, are increasing 50 and 90% respectively. The ion streaming in density gradient of dense plasma leads to increasing the Weibel instability growth rate and its amplification through ion streaming in the large wavenumber. The maximum unstable... 

In this paper, new polymer composites were synthesized by template copolymerization of aniline and metanilic acid in the presence of prepared melamine triacetic acid and poly(melamine-co-citric acid) as polyacids and dopants. The properties of the poly(aniline-co-metanilic acid) composites were studied by Fourier transform infrared, X-ray diffraction, scanning electron microscope, CV, and differential scanning calorimeter analysis. The four-point probe technique was used for evaluating the electrical conductivity of the composites. The scanning electron micrographs disclosed that the products had the morphology with agglomerated distorted spherical shapes with the average size of 40–50 nm.... 

In this paper, new polymer composites were synthesized by template copolymerization of aniline and metanilic acid in the presence of prepared melamine triacetic acid and poly(melamine-co-citric acid) as polyacids and dopants. The properties of the poly(aniline-co-metanilic acid) composites were studied by Fourier transform infrared, X-ray diffraction, scanning electron microscope, CV, and differential scanning calorimeter analysis. The four-point probe technique was used for evaluating the electrical conductivity of the composites. The scanning electron micrographs disclosed that the products had the morphology with agglomerated distorted spherical shapes with the average size of 40–50 nm.... 

In this study the ability of artificial neural network (ANN) in forecasting the daily NASDAQ stock exchange rate was investigated. Several feed forward ANNs that were trained by the back propagation algorithm have been assessed. The methodology used in this study considered the short-term historical stock prices as well as the day of week as inputs. Daily stock exchange rates of NASDAQ from January 28, 2015 to 18 June, 2015 are used to develop a robust model. First 70 days (January 28 to March 7) are selected as training dataset and the last 29 days are used for testing the model prediction ability. Networks for NASDAQ index prediction for two type of input dataset (four prior days and nine... 

The effects of insulated and isothermal thin baffles on pseudosteady-state natural convection within spherical containers were studied computationally. The computations are based on an iterative, finite-volume numerical procedure using primitive dependent variables. Natural convection effect is modeled via the Boussinesq approximation. Parametric studies were performed for a Prandtl number of 0.7. For Rayleigh numbers of 104, 105, 106, and 107, baffles with three lengths positioned at five different locations were investigated (120 cases). The fluid that is heated adjacent to the sphere rises replacing the colder fluid, which sinks downward through the stratified stable thermal layer. For... 

In this study, a new type of magnetite nanocomposite with a core-shell structure was synthesized using Fe3O4 nanoparticles as a core and polyaniline (PANI) as a shell. For this propose, the surface of Fe3O4 was chemically modified with hexamethylenediisocyanate (HMDI) to improve its compatibility and interphase interaction with the polymeric matrix. Thereafter, the PANI was reacted with modified Fe3O4 to anchor them to PANI by covalent bands which acted as a shell. In the second step, the poly (maleic acid-co-acrylic acid) (P(MAc-co-AA)) as polymeric dopant for the PANI was synthesized. Finally, the PANI anchored to Fe3O4 was immersed in an aqueous solution of poly (maleic... 

In this study, a new type of magnetite nanocomposite with a core–shell structure was synthesized using Fe3O4 nanoparticles as a core and polyaniline (PANI) as a shell. For this propose, the surface of Fe3O4 was chemically modified with hexamethylenediisocyanate (HMDI) to improve its compatibility and interphase interaction with the polymeric matrix. Thereafter, the PANI was reacted with modified Fe3O4 to anchor them to PANI by covalent bands which acted as a shell. In the second step, the poly (maleic acid-co-acrylic acid) (P(MAc-co-AA)) as polymeric dopant for the PANI was synthesized. Finally, the PANI anchored to Fe3O4 was immersed in an aqueous solution of poly (maleic... 

Background and Objective: During the manufacture and storage of probiotic products, there are always possibilities that probiotics be exposed to harmful stresses such as high temperature, low pH, various osmotic pressures and high oxygen levels, which can decrease the number of living cells. Encapsulation is one of the methods used to protect living cells such as probiotic bacteria from environmental challenges. Up-to-date, various compounds with abilities to protect bacteria during freeze-drying and to increase viability during storage have been identified. In this study, alginate with calcium chloride was used to encapsulate probiotic bacteria using extrusion method. Then, effects of...