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Theoretical and Experimental Investigation of Die Swell Phenomenon for Polymer Nano-Composites
, M.Sc. Thesis Sharif University of Technology ; Ramezani Saadat Abadi, Ahmad (Supervisor)
Abstract
This thesis was conducted both numerically and experimentally. In the experimental investigations aqueous solutions of high molecular weight Carboxymethylcellulose (CMC) was used. The experimental set-up was composed of a glass syringe, and a piston which can easily move through the syringe. Different die with aspect ratio ranging from 5.25 to 28.8 can be attached to the syringe. The syringe then is filled with the CMC solution with different weight fractions. Then using a force exerting on the piston, the solution comes out of the die and exiting velocity was calculated from weight of CMC solution that exit from die in a definite time. High quality photographs were taken from extrudate...
Simulation of flow of short fiber suspensions through a planar contraction
, Article Scientia Iranica ; Volume 19, Issue 3 , June , 2012 , Pages 579-584 ; 10263098 (ISSN) ; Ramazani S. A. A ; Kamyabi, A ; Hosseini Amoli, H ; Sharif University of Technology
2012
Abstract
In this study, the flow of a fiber filled viscoelastic matrix through planar contractions is investigated. It was found that by adding fiber to the matrix vortex, the intensity increases. Fiber orientation along "x" and "y" axes was studied too. It was found that fiber orientation could be used for determining the flow regime through the contraction geometry. The rigidity condition of fibers, which needs the trace of the orientation tensor to be unity everywhere in the domain, is correct except near walls and the reentrant corner, which is slightly less than one. In these regions, the stress magnitude is higher, which results in more numerical errors, and which further leads to some error in...
Flow of a PTT fluid through planar contractions - Vortex inhibition using rounded corners
, Article ASME 2010 International Mechanical Engineering Congress and Exposition, IMECE 2010, Vancouver, BC, 12 November 2010 through 18 November 2010 ; Volume 7, Issue PARTS A AND B , November , 2010 , Pages 601-607 ; 9780791844441 (ISBN) ; Ramazani S. A, A ; Hosseini Amoli, H ; Behrang, A ; Kamyabi, A ; Sharif University of Technology
2010
Abstract
Contraction flow is one of important geometries in fluid flow both in Newtonian and non-Newtonian fluids. In this study, flow of a viscoelastic fluid through a planar 4:1 contraction with rounded corners was investigated. Six different rounding ratios (RR =0, 0.125, 0.25, 0.375, 0.438, 0.475, 0.488) was examined using the linear PTT constitutive equation at creeping flow and isothermal condition. Then the resulting PDE set including continuity, momentum, and PTT constitutive equations were implemented to the OpenFOAM software. The results clearly show vortex deterioration with increasing rounding diameter, so that when rounding corner exceeds a critical value, the vortex disappears...
The ion streaming effect on weibel instability in the relativistic dense plasma
, Article Contributions to Plasma Physics ; Volume 57, Issue 8 , 2017 , Pages 351-356 ; 08631042 (ISSN) ; Mahdavi, M ; Sharif University of Technology
2017
Abstract
The Weibel instability plays an important role in stopping hot electrons and energy deposition mechanism in fast ignition of inertial fusion process. In this paper, the ion Weibel instability in counter propagating electron-ion plasmas is investigate. The obtained results show that the growth rate of Weibel instability will be decreased about 40% with the anisotropy velocity as vxe = 2vze = 20; the ion density ratio, b = n0i1/n0i2, and density gradient, are increasing 50 and 90% respectively. The ion streaming in density gradient of dense plasma leads to increasing the Weibel instability growth rate and its amplification through ion streaming in the large wavenumber. The maximum unstable...
Preparation of Titania based solid strong acid and study of its catalytic activity in esterification of Phthalic anhydride and Sebacic acid
, Article Materials Letters ; Volume 60, Issue 6 , 2006 , Pages 715-719 ; 0167577X (ISSN) ; Gholami, M. R ; Sharif University of Technology
2006
Abstract
Esterification of Phthalic anhydride with 2-Octanol and Sebacic acid with Ethanol has been studied in the presence of Sulfated Titania. This study showed that Sulfated Titania has strong catalytic effect on esterification reactions. The effect of some factors such as reaction temperature, molar ratio of acid to alcohol, amount of catalyst used, reaction time, calcination temperature, drying temperature and calcination atmosphere has been investigated. Equilibrium composition achieved in 80 min for Diethyl Sebacate and 20 min for Dioctyl Phthalate in various conditions. © 2005 Elsevier B.V. All rights reserved
Acidic derivatives of melamine as template in copolymerization of aniline and metanilic acid
, Article Polymer - Plastics Technology and Engineering ; 2017 , Pages 1-10 ; 03602559 (ISSN) ; Najafi Moghadam, P ; Hashemi, M. M ; Sharif University of Technology
2017
Abstract
In this paper, new polymer composites were synthesized by template copolymerization of aniline and metanilic acid in the presence of prepared melamine triacetic acid and poly(melamine-co-citric acid) as polyacids and dopants. The properties of the poly(aniline-co-metanilic acid) composites were studied by Fourier transform infrared, X-ray diffraction, scanning electron microscope, CV, and differential scanning calorimeter analysis. The four-point probe technique was used for evaluating the electrical conductivity of the composites. The scanning electron micrographs disclosed that the products had the morphology with agglomerated distorted spherical shapes with the average size of 40–50 nm....
Acidic derivatives of melamine as template in copolymerization of aniline and metanilic acid
, Article Polymer - Plastics Technology and Engineering ; Volume 57, Issue 10 , 2018 , Pages 965-974 ; 03602559 (ISSN) ; Najafi Moghadam, P ; Hashemi, M. M ; Sharif University of Technology
Taylor and Francis Inc
2018
Abstract
In this paper, new polymer composites were synthesized by template copolymerization of aniline and metanilic acid in the presence of prepared melamine triacetic acid and poly(melamine-co-citric acid) as polyacids and dopants. The properties of the poly(aniline-co-metanilic acid) composites were studied by Fourier transform infrared, X-ray diffraction, scanning electron microscope, CV, and differential scanning calorimeter analysis. The four-point probe technique was used for evaluating the electrical conductivity of the composites. The scanning electron micrographs disclosed that the products had the morphology with agglomerated distorted spherical shapes with the average size of 40–50 nm....
Polysaccharide-based nanocomposites for biomedical applications: a critical review
, Article Nanoscale Horizons ; Volume 7, Issue 10 , 2022 , Pages 1136-1160 ; 20556756 (ISSN) ; Shokrani, A ; Sajadi, S. M ; Khodadadi Yazdi, M ; Seidi, F ; Jouyandeh, M ; Zarrintaj, P ; Kar, S ; Kim, S. J ; Kuang, T ; Rabiee, N ; Hejna, A ; Saeb, M. R ; Ramakrishna, S ; Sharif University of Technology
Royal Society of Chemistry
2022
Abstract
Polysaccharides (PSA) have taken specific position among biomaterials for advanced applications in medicine. Nevertheless, poor mechanical properties are known as the main drawback of PSA, which highlights the need for PSA modification. Nanocomposites PSA (NPSA) are a class of biomaterials widely used as biomedical platforms, but despite their importance and worldwide use, they have not been reviewed. Herein, we critically reviewed the application of NPSA by categorizing them into generic and advanced application realms. First, the application of NPSA as drug and gene delivery systems, along with their role in the field as an antibacterial platform and hemostasis agent is discussed. Then,...
Effects of insulated and isothermal baffles on pseudosteady-state natural convection inside spherical containers
, Article Journal of Heat Transfer ; Volume 132, Issue 6 , April , 2010 , Pages 1-10 ; 00221481 (ISSN) ; Hosseinizadeh, S. F ; Khodadadi, J. M ; Sharif University of Technology
2010
Abstract
The effects of insulated and isothermal thin baffles on pseudosteady-state natural convection within spherical containers were studied computationally. The computations are based on an iterative, finite-volume numerical procedure using primitive dependent variables. Natural convection effect is modeled via the Boussinesq approximation. Parametric studies were performed for a Prandtl number of 0.7. For Rayleigh numbers of 104, 105, 106, and 107, baffles with three lengths positioned at five different locations were investigated (120 cases). The fluid that is heated adjacent to the sphere rises replacing the colder fluid, which sinks downward through the stratified stable thermal layer. For...
Synthesis of Conductive Magnetite Nanocomposite based on Polyaniline/Poly(maleic acid-co-acrylic acid) with Core-Shell Structure
, Article Advances in Polymer Technology ; 2016 ; 07306679 (ISSN) ; Najafi Moghadam, P ; Mahmoodi Hashemi, M ; Sharif University of Technology
John Wiley and Sons Inc
2016
Abstract
In this study, a new type of magnetite nanocomposite with a core-shell structure was synthesized using Fe3O4 nanoparticles as a core and polyaniline (PANI) as a shell. For this propose, the surface of Fe3O4 was chemically modified with hexamethylenediisocyanate (HMDI) to improve its compatibility and interphase interaction with the polymeric matrix. Thereafter, the PANI was reacted with modified Fe3O4 to anchor them to PANI by covalent bands which acted as a shell. In the second step, the poly (maleic acid-co-acrylic acid) (P(MAc-co-AA)) as polymeric dopant for the PANI was synthesized. Finally, the PANI anchored to Fe3O4 was immersed in an aqueous solution of poly (maleic...
Synthesis of conductive magnetite nanocomposite based on polyaniline/poly(maleic acid-co-acrylic acid) with core–shell structure
, Article Advances in Polymer Technology ; Volume 37, Issue 4 , 2018 , Pages 1041-1049 ; 07306679 (ISSN) ; Najafi moghadam, P ; Mahmoodi hashemi, M ; Sharif University of Technology
John Wiley and Sons Inc
2018
Abstract
In this study, a new type of magnetite nanocomposite with a core–shell structure was synthesized using Fe3O4 nanoparticles as a core and polyaniline (PANI) as a shell. For this propose, the surface of Fe3O4 was chemically modified with hexamethylenediisocyanate (HMDI) to improve its compatibility and interphase interaction with the polymeric matrix. Thereafter, the PANI was reacted with modified Fe3O4 to anchor them to PANI by covalent bands which acted as a shell. In the second step, the poly (maleic acid-co-acrylic acid) (P(MAc-co-AA)) as polymeric dopant for the PANI was synthesized. Finally, the PANI anchored to Fe3O4 was immersed in an aqueous solution of poly (maleic...
Effects of sucrose, skim milk and yeast powder on survival of lactobacillus rhamnosus gg encapsulated with alginate during one-week storage at room conditions
, Article Applied Food Biotechnology ; Volume 9, Issue 3 , 2022 , Pages 251-259 ; 23455357 (ISSN) ; Tabandeh, F ; Alemzadeh, I ; Soltani, M ; Sharif University of Technology
National Nutrition and Food Technology Research Institute
2022
Abstract
Background and Objective: During the manufacture and storage of probiotic products, there are always possibilities that probiotics be exposed to harmful stresses such as high temperature, low pH, various osmotic pressures and high oxygen levels, which can decrease the number of living cells. Encapsulation is one of the methods used to protect living cells such as probiotic bacteria from environmental challenges. Up-to-date, various compounds with abilities to protect bacteria during freeze-drying and to increase viability during storage have been identified. In this study, alginate with calcium chloride was used to encapsulate probiotic bacteria using extrusion method. Then, effects of...
A recourse policy to improve number of successful transplants in uncertain kidney exchange programs
, Article Journal of Optimization Theory and Applications ; Volume 197, Issue 2 , 2023 , Pages 476-507 ; 00223239 (ISSN) ; Najafi, M ; Yazdi, M. M ; Sharif University of Technology
Springer
2023
Abstract
Uncertainty of kidney exchange programs (KEP) is one of the main challenges that cause failure in most planned transplants to proceed to surgery. Unfortunately, this challenge usually decreases KEP performance in the real world. To face this challenge, we develop an efficient approach, consisting of scheduling methodology and recourse actions, to recover failing pairs and improve the number of successful transplants in KEPs. The developed policy can be implemented in two different schemes. The first scheme receives an optimal matching as an input and determines recourse actions and the sequence of disjoint cycles and chains for the given optimal matching. However, the second scheme does not...
Fully supramolecular vesicles as anticancer drug delivery systems
, Article New Journal of Chemistry ; Volume 37, Issue 2 , 2013 , Pages 295-298 ; 11440546 (ISSN) ; Adeli, M ; Yazdi, M ; Sharif University of Technology
2013
Abstract
A supramolecular linear-dendritic copolymer consisting of a polystyrene backbone and hanging hyperbranched polyglycerols was prepared and characterized. Host-guest interactions between β-cyclodextrin incorporated in the core of polyglycerol as a host and aromatic rings of polystyrene as guests lead to the formation of a supramolecular linear-dendritic copolymer. Supramolecules formed micelles in aqueous solutions which were able to encapsulate and transfer paclitaxel with a high loading capacity
Modeling (r, Q) policy in a two-level supply chain system with fuzzy demand
, Article International Journal of Uncertainty, Fuzziness and Knowlege-Based Systems ; Volume 18, Issue 6 , 2010 , Pages 819-841 ; 02184885 (ISSN) ; Modarres Yazdi, M ; Sharif University of Technology
2010
Abstract
In this paper a two level supply chain system is studied, in which the final demand is assumed to be fuzzy with triangular membership function. The inventory control policy of (r, Q) is followed for this system and unsatisfied demand is assumed to be back ordered. The objective is to minimize the total cost of the system, including ordering, holding and shortage costs. The model happens to be a nonlinear programming. Considering the complexity arising from the model, we also develop a genetic algorithm to obtain a near-optimal solution. The method is illustrated through some numerical examples
Time-variant seismic risk analysis of transportation networks considering economic and socioeconomic impacts
, Article Journal of Earthquake Engineering ; 2018 , Pages 1-29 ; 13632469 (ISSN) ; Mahsuli, M ; Sharif University of Technology
Taylor and Francis Ltd
2018
Abstract
This paper puts forward a new methodology for time-variant seismic risk analysis of transportation networks. Risk here denotes the probability of exceeding the sum of direct loss due to repair costs of bridges in the network and indirect loss due to the reduced capacity for traffic flow. The proposed methodology employs reliability methods and a host of probabilistic models for earthquake events, damage, repair cost, downtime, and travel time, while accounting for time-varying phenomena of aging and discounting. A comprehensive application on the transportation network of Isfahan, Iran, is presented that features 64 bridges subject to seismicity from seven sources. © 2018 Taylor & Francis...
Time-variant seismic risk analysis of transportation networks considering economic and socioeconomic impacts
, Article Journal of Earthquake Engineering ; Volume 24, Issue 5 , March , 2020 , Pages 745-773 ; Mahsuli, M ; Sharif University of Technology
Taylor and Francis Ltd
2020
Abstract
This paper puts forward a new methodology for time-variant seismic risk analysis of transportation networks. Risk here denotes the probability of exceeding the sum of direct loss due to repair costs of bridges in the network and indirect loss due to the reduced capacity for traffic flow. The proposed methodology employs reliability methods and a host of probabilistic models for earthquake events, damage, repair cost, downtime, and travel time, while accounting for time-varying phenomena of aging and discounting. A comprehensive application on the transportation network of Isfahan, Iran, is presented that features 64 bridges subject to seismicity from seven sources. © 2018, © 2018 Taylor &...
Designing instrumented walker to measure upper-extremity’s efforts: a case study
, Article Assistive Technology ; 2018 , Pages 1-9 ; 10400435 (ISSN) ; Arab Baniasad, M ; Arazpour, M ; Farahmand, F ; Zohoor, H ; Sharif University of Technology
Taylor and Francis Inc
2018
Abstract
The high prevalence of shoulder pain in using walkers in patients who have spinal cord injury (SCI). Also, the limited options available to economically measure grip forces in walkers, which drove the need to create one. This article describes a method to obtain upper-extremities’ forces and moments in a person with SCI by designing an appropriate instrumented walker. First, since the commercial multidirectional loadcells are too expensive, custom loadcells are fabricated. Ultimately, a complete gait analysis by means of VICON motion analysis and using inverse dynamic method has been held to measure upper-extremities’ efforts. The results for a person with SCI using a two-wheel walker in low...
Designing instrumented walker to measure upper-extremity’s efforts: A case study
, Article Assistive Technology ; Volume 31, Issue 5 , 2019 , Pages 267-275 ; 10400435 (ISSN) ; Baniasad, M. A ; Arazpour, M ; Farahmand, F ; Zohoor, H ; Sharif University of Technology
Taylor and Francis Inc
2019
Abstract
The high prevalence of shoulder pain in using walkers in patients who have spinal cord injury (SCI). Also, the limited options available to economically measure grip forces in walkers, which drove the need to create one. This article describes a method to obtain upper-extremities’ forces and moments in a person with SCI by designing an appropriate instrumented walker. First, since the commercial multidirectional loadcells are too expensive, custom loadcells are fabricated. Ultimately, a complete gait analysis by means of VICON motion analysis and using inverse dynamic method has been held to measure upper-extremities’ efforts. The results for a person with SCI using a two-wheel walker in low...
Solvatochromic parameters for binary mixtures of an ionic liquid with various protic molecular solvents
, Article Monatshefte fur Chemie ; Volume 140, Issue 3 , 2009 , Pages 329-334 ; 00269247 (ISSN) ; Habibi Yangjeh, A ; Gholami, M. R ; Sharif University of Technology
2009
Abstract
Solvatochromic parameters (E T N , normalized polarity parameter; π, dipolarity/polarizability; β, hydrogen-bond acceptor basicity; α, hydrogen-bond donor acidity) have been determined for binary mixtures of propan-2-ol, propan-1-ol, ethanol, methanol and water with recently synthesized ionic liquid (IL; 2-hydroxyethylammonium formate) at 25 °C. In all solutions except aqueous solution, E T N values of the media increase abruptly with the ILs mole fraction and then increase gradually to the value of pure IL. A synergistic behavior is observed for the α parameter in all solutions. The behavior of π and β are nearly ideal for all solutions except for solutions of methanol with the IL. The...