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    Slot-Die coated copper indium disulfide as hole-transport material for perovskite solar cells

    , Article Sustainability (Switzerland) ; Volume 15, Issue 8 , 2023 ; 20711050 (ISSN) Mahmoodpour, S ; Heydari, M ; Shooshtari, L ; Khosroshahi, R ; Mohammadpour, R ; Taghavinia, N ; Sharif University of Technology
    MDPI  2023
    Abstract
    Perovskite photovoltaics have the potential to significantly lower the cost of producing solar energy. However, this depends on the ability of the perovskite thin film and other layers in the solar cell to be deposited using large-scale techniques such as slot-die coating without sacrificing efficiency. In perovskite solar cells (PSCs), Spiro-OMeTAD, a small molecule-based organic semiconductor, is commonly used as the benchmark hole transport material (HTL). Despite its effective performance, the multi-step synthesis of Spiro-OMeTAD is complex and expensive, making large-scale printing difficult. Copper indium disulfide (CIS) was chosen in this study as an alternative inorganic HTL for... 

    Development of a triple-cation Ruddlesden–Popper perovskite structure with various morphologies for solar cell applications

    , Article Journal of Materials Science: Materials in Electronics ; Volume 31, Issue 4 , January , 2020 , Pages 2766-2776 Mirhosseini, M ; Bakhshayesh, A. M ; Khosroshahi, R ; Taghavinia, N ; Abdizadeh, H ; Sharif University of Technology
    Springer  2020
    Abstract
    The present research sheds new light on the development of a triple-cation quasi-two-dimensional (2D) perovskite family with the general formula of (S1−xS′x)2[Cs0.05(FA1−xMAx)0.95]3Pb4(I1−xBrx)13, in which two spacers, namely 5-ammonium valeric acid iodide (S) and tetra-n-octylammonium bromide (S′) were simultaneously incorporated. Morphology, crystal structure, optical properties, photovoltaic performance, and internal resistances of such compound were systemically studied in comparison with an analogous single-cation 2D counterpart (i.e. (S)2(FA)3Pb4I13) as a reference. X-ray diffraction set forth that the films deposited based upon these compounds had a 2D perovskite crystal structure... 

    The Effect of Social Security on Retirement Decision in Iran

    , M.Sc. Thesis Sharif University of Technology Khosroshahi, Amir Reza (Author) ; Nili, Masoud (Supervisor)
    Abstract
    The main question of this thesis is if and to what extent does the Social Security retirement benefits cause early retirement. This is important because the more individuals are willing to retire earlier, the larger are the Social Security liabilities to pay the retirement benefts, and also it means that more people are leaving the labor force, hence a lower labor force participation. The research was conducted on a sample of men extracted from the Social Security Or-ganization data sets, employing Option Value and Peak Value models to estiamte a binary choice model. The results indicate that Social Security (in the form of retirement benefits) have a significant effect on retirement ... 

    Data-Driven Pricing Based on Demand Prediction Using Machine Learning Methods

    , M.Sc. Thesis Sharif University of Technology Khosroshahi, Fatemeh Zahra (Author) ; Sedghi, Nafiseh (Supervisor)
    Abstract
    Pricing plays an important and essential role in the profit and income of companies. The importance of pricing is not only related to its role in the company's profitability, but it also changes the customer's understanding and loyalty towards the company and can create the company's reputation or destroy it. Determining the right price will increase product sales and increase customer loyalty and create a competitive advantage for the company. One of the most important and influential variables in product pricing is the amount of demand. The main challenge of companies for product pricing is the uncertainty in their demand. In order to deal with this problem, data-driven pricing is used.... 

    Polyvinylcarbazole as an efficient interfacial modifier for low-cost perovskite solar cells with CuInS2/Carbon hole-collecting electrode

    , Article Solar RRL ; Volume 5, Issue 7 , 2021 ; 2367198X (ISSN) Ghavaminia, E ; Behrouznejad, F ; Forouzandeh, M ; Khosroshahi, R ; Darbari, S ; Zhan, Y ; Taghavinia, N ; Sharif University of Technology
    John Wiley and Sons Inc  2021
    Abstract
    Different polymers have been already introduced for passivating the interfacial defects at the interface of perovskite and the organic hole transport material, meanwhile as an environmental barrier in perovskite solar cells (PSCs). Herein, polyvinylcarbazole (PVK) compared to polymethylmethacrylate (PMMA) at the interface of the perovskite (Cs0.05(MA0.83FA0.17)0.95Pb(Br0.17I0.83)3) layer and CuInS2/carbon as a low-cost inorganic hole-collecting electrode are investigated. By suppressing interfacial recombination using PMMA and PVK, saturation current density (in dark current) decreases one order of magnitude from 7.9 × 10−10 to 4.0 × 10−11 mA cm−2 by adding PMMA and two orders of magnitude... 

    Multiwavelength Study of Structural Parameters of Early Type Galaxies

    , M.Sc. Thesis Sharif University of Technology Mirkazemi, Mohammad (Author) ; Rahvar, Sohrab (Supervisor) ; Khosroshahi, Habib (Supervisor)
    Abstract
    During the past decades, structural parameters are used as a tool for studying the formation and evolution of galaxies. Sersic parameter is one of these parameterswhich also known as shape parameter. Sometimes, measuring such parameters depend on the observed wavelength. So far, this dependence has been rarely attended. In this thesis we are trying to know how and why these parameters depend on the wavelength  

    Functional Design of a Coating System for the Telescope Mirrors, A Recognition to Telescope of Iranian National Observatory

    , M.Sc. Thesis Sharif University of Technology Mahdizadeh, Sajjad (Author) ; Moshfegh, Alireza (Supervisor) ; Khosroshahi, Habib (Co-Advisor)
    Abstract
    Functional design of coating system for the primary mirror of the Iranian National Observatory (INO) is done. This telescope has a 3.4 m primary mirror in diameter, made of Zerodur from Schott. Although similar coating systems are in use since years ago, this is the first attempt to design a system for such a large surface case in Iran. Systematic approach led us first to clarify and identifying the design requirements. Lower limit of 80% for reflectance on all wavelength range from 325-1000 nm, thickness of 100 nm with un-uniformity of 5 nm, adhesion enough to pass the selotape test and surface roughness of less than 8 nm. Study of the available methods for coating and selection of the best... 

    Using Vitamin B1 as a Catalyst in Performing Multi-Component Reactions and Synthesis of Affinity Column ChromatograpHy for Purification of Recombinant Proteins

    , M.Sc. Thesis Sharif University of Technology Lohi Khosroshahi, Ameneh (Author) ; Kalhor, Hamid Reza (Supervisor)
    Abstract
    Due to the importance of using pure proteins in the industry and basic research in order to study them in the structural contexts and interactions of proteins in recent years, purification methods have been extensively developed. The purification steps usually depend on the size of the protein, its physical and chemical properties, the binding affinity and the biological activity of the protein in question, In the purification process, the protein portion is separated from the non-protein portion. The biggest challenge is when we want to separate different proteins. Different chromatographic methods are used, depending on the properties of the impure proteins. One of these chromatographic... 

    Evolution of Luminosity Gap Statistics in Galaxy Systems with Redshift

    , M.Sc. Thesis Sharif University of Technology Erfanianfar, Ghazaleh (Author) ; Rahvar, Sohrab (Supervisor) ; Khosroshahi, Habib (Supervisor)
    Abstract
    The luminosity gap between the two brightest galaxies of the galaxy groups and clusters is a statistics criteria for studying the time of the formation of these gravitational systems. So far, the luminosity gap of galaxy systems is studied in local universe (z~0). This parameter is a good criteria to understand the structure formation models. In this project we investigate the evolution of luminosity gap statistic in high redshift universe (z~0.4). The evolution of luminosity with redshift is a proper tool for investigating the evolution of galaxies in different environments during the time  

    Scaling Relations in Dwarf Galaxies of the Coma Cluster of Galaxies

    , Ph.D. Dissertation Sharif University of Technology Kourkchi, Ehsan (Author) ; Mansouri, Reza (Supervisor) ; Khosroshahi, Habib (Supervisor)
    Abstract
    We study the fundamental and the photometric plane of a sample of 50 dwarf galaxies within the core of Coma cluster observed with DEIMOS on Keck II down to R-band luminosity of -15 Magnitudes. The Calcium triplet lines in the wavelength range between 7500 to 10,000 ˚A, allow us to obtain the velocity dispersion for the sample galaxies with high precision. We also performed a comprehensive error analysis to better estimate the uncertainties of this key observable. We also carried out a galaxy structure modeling using the ACS I-band images for a larger sample. We found larger velocity dispersions for fainter dwarfs than what expected from mass-luminosity trends of brighter Coma galaxies. In... 

    Cooling+Heating flows in galaxy clusters: Turbulent heating, spectral modeling, and cooling efficiency

    , Article Astrophysical Journal ; Volume 884, Issue 1 , 2019 ; 0004637X (ISSN) Zhoolideh Haghighi, M. H ; Afshordi, N ; Khosroshahi, H. G ; Sharif University of Technology
    Institute of Physics Publishing  2019
    Abstract
    The discrepancy between expected and observed cooling rates of X-ray emitting gas has led to the cooling-flow problem at the cores of clusters of galaxies. A variety of models have been proposed to model the observed X-ray spectra and resolve the cooling-flow problem, which involves heating the cold gas through different mechanisms. As a result, realistic models of X-ray spectra of galaxy clusters need to involve both heating and cooling mechanisms. In this paper, we argue that the heating timescale is set by the magnetohydrodynamic (MHD) turbulent viscous heating for the Intracluster plasma, parameterized by the Shakura-Sunyaev viscosity parameter, α. Using a cooling+heating flow model, we... 

    Optimization of CuIn1-XGaXS2 Nanoparticles and Their Application in the Hole-Transporting Layer of Highly Efficient and Stable Mixed-Halide Perovskite Solar Cells

    , Article ACS Applied Materials and Interfaces ; Volume 11, Issue 34 , 2019 , Pages 30838-30845 ; 19448244 (ISSN) Khorasani, A ; Marandi, M ; Khosroshahi, R ; Malekshahi Byranvand, M ; Dehghani, M ; Zad, A. I ; Tajabadi, F ; Taghavinia, N ; Sharif University of Technology
    American Chemical Society  2019
    Abstract
    Inorganic hole-transport materials (HTMs) have been frequently applied in perovskite solar cells (PSCs) and are a promising solution to improve the poor stability of PSCs. In this study, we investigate solution-processed copper indium gallium disulfide (CIGS) nanocrystals (NCs) as a dopant-free inorganic HTM in n-i-p type PSCs. Moreover, Cs0.05(MA0.17-FA0.83)0.95Pb(I0.83Br0.17)3 mixed-halide perovskite with proper crystalline quality and long-time stability was utilized as the light-absorbing layer under ambient conditions. To optimize the cell performance and better charge extraction from the perovskite layer, the Ga concentration in the Cu(In1-XGaX)S2 composition was changed, and the X... 

    Effect of indium ratio in CuInxGa1-xS2/carbon hole collecting electrode for perovskite solar cells

    , Article Journal of Power Sources ; Volume 475 , 2020 Forouzandeh, M ; Behrouznejad, F ; Ghavaminia, E ; Khosroshahi, R ; Li, X ; Zhan, Y ; Liao, Y ; Ning, Z ; Taghavinia, N ; Sharif University of Technology
    Elsevier B.V  2020
    Abstract
    Perovskite solar cells (PSCs) have excellent photovoltaic properties. There are, however, challenges of materials cost and device stability to be solved before commercializing them. Utilizing low-cost inorganic hole transport materials (HTM) as a replacement for spiro-OMeTAD, and replacing the Au electrode with printable carbon could be important steps in this regard. For this purpose, CuInxGa1-xS2 (x = 1, 0.75, 0.5, 0.25, 0) nanoparticle layers are deposited as inorganic HTMs with carbon composite electrode as the back electrode. Photovoltaic properties of PSCs with CuInxGa1-xS2/Carbon hole collecting electrodes are studied by changing the In ratio in the HTM layer. Results from impedance... 

    Preparation of Colloidal Chalcopyrite Nanoparticles Aimed for Device-Quality Thin Films Used in Solar Cell Applications

    , M.Sc. Thesis Sharif University of Technology Khosroshahi, Rouhollah (Author) ; Taghavinia, Nima (Supervisor) ; Bagherzadeh, Mojtaba (Supervisor)
    Abstract
    In this research, the technology of fabrication and deposition of nanoparticle inks from chalcogenide compounds and then use of them in the fabrication of CuInGaS2 and Perovskite thin-film solar cells have been considered. In the first step, the synthesis of CuInGaS2 family compounds with variable In / Ga ratio and also the change of the stoichiometric ratio of Cu component using oleylamine solvent is investigated. In addition to these compounds, the synthesis of CuSnS, CuBaSnS, and CuZnSnS nanoparticles is also investigated. The synthesized nanoparticles were analyzed by XRD, DLS, UV-Vis, ICP, PL, SEM, EDX, and TEM. Then, the stability of the ink made of CuInGaS2 nanoparticles in different... 

    Probing the Local Bubble with Diffuse Interstellar Bands (DIBs)

    , Ph.D. Dissertation Sharif University of Technology Farhang Nia, Amin (Author) ; Khosroshahi, Habib (Supervisor) ; Bahmanabadi, Mahmoud (Supervisor)
    Abstract
    We present a new high signal to noise ratio spectroscopic survey of the Northern hemisphere to probe the Local Bubble and its surroundings using the 5780Å and 5797Å Diffuse Interstellar Bands (DIBs). We have observed 432 sightlines to a distance of 200 pc over a duration of 3 years. In this study, for both inside and outside the Local Bubble, we establish the 5780and 5797correlations with Na i, Ca iiand E(B-V). The correlations show that among all neutral and ionized atoms, the Na ihas more similarity with 5780and Ca iihas strong correlation with 5797, which suggest that the ionization level of 5797is more than 5780. We study the 5780correlation with 5797, which shows a tight correlation... 

    IGM Heating in Fossil Galaxy Groups

    , Ph.D. Dissertation Sharif University of Technology Miraghaei Jafari, Halimehossadat (Author) ; Khosroshahi, Habib (Supervisor) ; Rahvar, Sohrab (Supervisor)
    Abstract
    Fossil galaxy groups, famed to have undisturbed inter-galactic gas due to lack of recent group scale mergers, are energetically and morphologically ideal environments to study the IGM heating. In this article, we study the role of active galactic nuclei in heating the IGM in a sample of five fossil galaxy groups by employing their GMRT observations at 610 MHz and 1.4 GHz. We find that only two of the dominant galaxies in fossil groups are associated with the radio lobes. We evaluate the PdV work of the radio lobes and their corresponding heating power and compare to the X-ray emission loss within cooling radius. Our results show that the power due to mechanical heating is not sufficiently... 

    Optimization of selenization process to remove Ga-induced pin-holes in CIGS thin films

    , Article Solar Energy ; Volume 236 , 2022 , Pages 175-181 ; 0038092X (ISSN) Khosroshahi, R ; Dehghani, M ; Tehrani, N. A ; Taghavinia, N ; Bagherzadeh, M ; Sharif University of Technology
    Elsevier Ltd  2022
    Abstract
    In thin-film solar cells, deposition of pinhole and the crack-free absorber layer, with the right chemical stoichiometry is highly important for high-performance solar cell devices. In solution-based CIGS solar cell technology, a nanoparticle ink approach provides phase stability of the final chalcogenide absorber layer. However, the sintering of small nanoparticles to form large grains with reduced grain boundaries is an important challenge in the fabrication process. This is usually realized by annealing in the Se atmosphere, i.e. selenization process. However, the presence of Ga in CIGS films leads to pinholes after selenization. In this study, the synthesis and deposition of high-quality... 

    The fingerprint of charge transport mechanisms on the incident photon-to-current conversion efficiency spectra of perovskite solar cells

    , Article Solar Energy Materials and Solar Cells ; Volume 253 , 2023 ; 09270248 (ISSN) Behrouznejad, F ; Li, X ; Umar, A. A ; Zhang, X ; Khosroshahi, R ; Md Saad, S. K ; Ahmed, I ; Taghavinia, N ; Zhan, Y ; Sharif University of Technology
    Elsevier B.V  2023
    Abstract
    Perovskite solar cells (PSCs), the most promising nanostructured solar cells for large-scale production, have been fabricated with different types of electron and hole collectors to improve efficiency and stability. Incident photon-to-current conversion efficiency (IPCE) is an important measurement to evaluate the optical/electrical behavior of the structure to modify the device structure. In this research, we have investigated how different mechanisms affect the IPCE spectra and the difference between short-circuit current density (Jsc) recorded from the current density-voltage (J-V) and the IPCE curves of n-i-p PSCs. Results show that by removing the electron-transport layer (ETL) in a... 

    Engineering of CIGS nanoparticle inks for colloidal stability, uniform film formation and application as HTL for perovskite solar cells

    , Article Journal of Industrial and Engineering Chemistry ; 2021 ; 1226086X (ISSN) Khosroshahi, R ; Tehrani, N. A ; Forouzandeh, M ; Behrouznejad, F ; Taghavinia, N ; Bagherzadeh, M ; Sharif University of Technology
    Korean Society of Industrial Engineering Chemistry  2021
    Abstract
    In this work, synthesis of CuIn0.75Ga0.25S2 (CIGS) nanoparticles, the formation of stable dispersion, deposition of high-quality films and, fabrication of thin-film Perovskite solar cells are reported. The stability of nanoparticle ink is crucial in the formation of device-quality films. The chalcogenide-based materials are widely used in thin-film solar cells; in particular, Cu(In,Ga)S2 are used as an absorber and hole transporting layer. In the present study, the nanoparticles of about 20 nm size and bandgap of 1.5 eV are synthesized using a heat-up method. A variety of solvents are used as dispersing media and the stability of the inks is evaluated by precise optical monitoring. We... 

    Engineering of CIGS nanoparticle inks for colloidal stability, uniform film formation and application as HTL for perovskite solar cells

    , Article Journal of Industrial and Engineering Chemistry ; Volume 106 , 2022 , Pages 253-261 ; 1226086X (ISSN) Khosroshahi, R ; Tehrani, N. A ; Forouzandeh, M ; Behrouznejad, F ; Taghavinia, N ; Bagherzadeh, M ; Sharif University of Technology
    Korean Society of Industrial Engineering Chemistry  2022
    Abstract
    In this work, synthesis of CuIn0.75Ga0.25S2 (CIGS) nanoparticles, the formation of stable dispersion, deposition of high-quality films and, fabrication of thin-film Perovskite solar cells are reported. The stability of nanoparticle ink is crucial in the formation of device-quality films. The chalcogenide-based materials are widely used in thin-film solar cells; in particular, Cu(In,Ga)S2 are used as an absorber and hole transporting layer. In the present study, the nanoparticles of about 20 nm size and bandgap of 1.5 eV are synthesized using a heat-up method. A variety of solvents are used as dispersing media and the stability of the inks is evaluated by precise optical monitoring. We...