Sharif Digital Repository

AgxPt100−x (x = 0, 25, 50, 75 and 100) nanoparticles were grown on the surface of magnetic graphene oxide nanosheets (Fe3O4@GO) for the first time. The as-prepared nanocomposites were characterized using various techniques such as Fourier transform infrared spectroscopy, powder X-ray diffraction, field emission scanning electron microscopy, energy-dispersive X-ray spectroscopy, transmission electron microscopy, Brunauer–Emmett–Teller surface area analysis, vibrating sample magnetometry and thermogravimetric analysis. The Fe3O4@GO-AgxPt100−x catalysts were applied in the reduction of 4-nitrophenol (4-NP) to 4-aminophenol using sodium borohydride (NaBH4). The synthesized nanocomposites... 

In this study, AgxNi100-x, and CoxNi100-x (x = 0, 20, 40, 60, 80, and 100) bimetallic nanoparticles were successfully decorated on the surface of CeO2 nanorods derived from Ce-metal organic frameworks (Ce-MOF). The as-synthesized products were characterized using different techniques including XRD, FE-SEM, EDX, TEM, ICP, and BET. The as-prepared nanocomposites showed remarkable catalytic activity towards the reduction of organic pollutants such as 4-nitrophenol (4-NP), and rhodamine-B dye (RhB) by NaBH4 solution, with high stability and reusability for five consecutive cycles. The obtained results indicated that among these nanocomposites, Ag80Ni20@CeO2, and Co60Ni40@CeO2 exhibited the best... 

In this study, Fe3O4@Au/metal-organic frameworks (Fe3O4@Au/MOF) nanocomposite with flower-like core-shell structure was successfully synthesized via a hydrothermal route. The as-prepared catalyst was characterized using different techniques such as FT-IR, XRD, TEM, EDX, VSM, TGA, BET, and ICP. This nanocomposite exhibited an excellent catalytic performance in selective oxidation of cyclohexene to 2-cyclohexene-1-one by using molecular oxygen as green oxidant. The influence of reaction conditions including, pressure of molecular oxygen, temperature, time, solvent, and amount of catalyst on conversion and selectivity of products were evaluated. The activation energy (Ea) of the reaction was... 

Abstract: Au nanoparticles supported on cerium oxide/graphitic carbon nitride (CeO2@g-C3N4) was synthesized and used as heterogeneous catalyst in redox reaction. The catalyst was characterized by different techniques such as FT-IR, XRD, FE-SEM, EDS, TEM, BET, TGA, and ICP. The as-prepared ternary nanocomposite was used as an effective catalyst for the reduction of toxic 4-nitrophenol to useful 4-aminophenol by NaBH4. The rate constant value of reduction reaction reached up to 0.106 s−1 by Au/CeO2@g-C3N4, which was 3.8, and 8.8 times higher than that of Au@CeO2 (0.028 s−1), and Au@g-C3N4 (0.012 s−1) nanocomposites, respectively. The superior catalytic performance of as-prepared catalyst in... 

CuxNi100-x (x = 0, 20, 40, 60, 80, and 100) nanoparticles were uniformly grown on the surface of CeO2 by the liquid impregnation method. The as-prepared nanocomposite abbreviated CuxNi100-x-CeO2 was characterized by various techniques including, X-ray powder diffraction, field emission scanning electron microscopy, energy dispersive X-ray spectroscopy, Brunauer-Emmett-Teller surface area analyzer, and transmission electron microscopy. The catalytic activity of CuxNi100-x-CeO2 nanocomposites was investigated in 4-nitrophenol (4-NP) reduction reaction. Among the synthesized nanocomposites, Cu60Ni40-CeO2 exhibited the best catalytic activity (rate constant as 0.1654 s-1) with high recyclability... 

In this work, PtxPd1-x (x = 0, 0.5, and 1)nanoparticles (NPs)were synthesized on the surface of SiO2@graphene oxide which covered by 1-butyl-3-methylimidazolium hexafluorophosphate ([bmim]PF6)ionic liquid (IL)layer. FT-IR spectroscopy, zeta potential, CHN elemental analysis, XRD, XPS, SEM, EDX, TEM, TGA, BET, and ICP-AES techniques were applied for the characterization of the multiphasic catalyst. The as-prepared nanocomposite was used as an effective heterogeneous catalyst for the oxidation of cyclohexene by molecular oxygen, as a green oxidant. Different experimental conditions such as oxygen pressure, reaction time, reaction temperature and amount of catalyst were investigated in this... 

Solvatochromic UV-vis shifts of three probes 4-nitroaniline, 4-nitroanisol, and Reichardt's dye in binary mixtures of polyethylene glycol p-(1,1,3,3-tetramethylbutyl)-phenyl ether (Triton X-100 or TX-100) with methanol, ethanol, 1-propanol, and water have been investigated at 298 K. Structural and intermolecular interactions of solvatochromic probes were determined in these systems. Solvatochromic parameters, including normalized polarity (ETN), dipolarity-polarizability (π∗), hydrogen-bond donor (α), and hydrogen-bond acceptor (β) abilities, were measured at a wide range of mole fraction (0 ≤ X ≤ 1) with 0.1 increment. Interestingly, a similar behavior of ETN and α is observed in... 

The behaviour of solvatochromic absorbance probes (4-nitroaniline, 4-nitroanisole, and Reichardt's dye) within binary mixtures of polyethylene glycol p-(1,1,3,3-tetramethylbutyl)-phenyl ether (Triton X-100 or TX-100)/organic solvents (2-propanol, hexanol, butyl acetate, THF, toluene, and p-xylene) was extensively explored by using solvatochromism and the quantum theory of atoms in molecules (QTAIM). To be more precise, the polarity parameters, ET N, and Kamlet-Taft parameters, such as the hydrogen bond donor ability (HBD) (α), hydrogen bond acceptor ability (HBA) (β), and dipolarity/polarizability (π∗), have been investigated in selected mixtures at 298 K. All binary mixtures exhibit complex... 

In this work, the role of dissolved oxygen in the solar and the photo-Fenton-mediated E. coli inactivation process was put under scrutiny. The effect of transient species that were produced in the presence of various natural organic matter isolates (NOM), namely Suwannee River (SR) NOM, Nordic Reservoir (NR) NOM, SR Humic acid (SRHA), and SR Fulvic acid (SRFA) was studied in detail. The role of 1 O2 in this reaction was systematically evaluated by modifying the O2 concentration (N2/O2 purging) and the matrix composition (10, 50, and 100% deuterium oxide (D2O) v/v). In the presence of NOM, 1 O2 was generated and the enhancement of E. coli inactivation rate due to charge transfer from triplet... 

In this work, Ag nanoparticles were loaded on ZIF-67 covered by graphene oxide (Ag/ZIF-67@GO), and its catalytic performance was studied for the heterogeneous activation of peroxymonosulfate (PMS) under visible-light. The catalyst surface morphology and structure were analyzed by FT-IR, XRD, XPS, DRS, FE-SEM, EDX, TEM, BET, ICP-AES and TGA analysis. The efficacy of PMS activation by the Ag/ZIF-67@GO under visible light was assessed by phenol degradation and E. coli inactivation. Phenol was completely degraded within 30 min by HO•, SO4•− and O2•− generated through the photocatalytic PMS activation. In addition, total E. coli inactivation was attained in 15 min that confirmed the highly... 

This research demonstrates the feasibility to enhance solar disinfection (SODIS) treatment by addition of peroxymonosulfate (PMS) and peroxydisulfate (PDS) by the generation of sulfate (and hydroxyl) radicals through different activation routes. The different promoters were i) sunlight irradiation, ii) mild heat (40 °C), and iii) μM amounts of Fe2+, all present during actual field SODIS experiments, or voluntarily added alongside PMS/PDS. In a first approach, the promoters were studied separately, in pairs and finally all together in a combined process (CP). In all the cases, PMS showed a higher efficiency than PDS in E. coli removal, requiring lower concentration and a faster reaction time...