Sharif Digital Repository

In this study, the effect of adding 5–12.5 wt% CuO to TiO2 on photocatalytic properties of the nano-composite TiO2/CuO was investigated. The products were characterized by X-ray diffractometer, SEM, Brunauer–Emmett–Teller (BET), and DRS. BET-specific surface area of the TiO2/CuO composites was lower than that of the pure TiO2. Incorporation of CuO into TiO2 shifted absorption spectra to the visible region. As the CuO content increased from 0 to 12.5%, a clear decrease in optical band gap from 2.95 to 2.30 eV was observed. The photocatalytic performance was determined by methyl orange degradation and cyanide photo-oxidation under ultraviolet irradiation. However, the excessive incorporation... 

Photocatalysts that are used for waste water treatment are often suspended in the waste water during processing and then must be removed from the water after treatment. To reduce the post-degradation expenses and time, separation is facilitated by an immobilization process. The effect of immobilized TiO2 geometries on the photocatalytic behavior of the photocatalyst is investigated in this work. Powder, fiber, film, and network-shaped TiO2 nanocatalysts were produced by using different templates. The cellulose fiber and ceramic templates were used as substrates for fiber and film/network geometry production. The products were characterized by x-ray diffraction (XRD),... 

In this work, the effect of addition of ZrO2 to TiO2 and catalyst geometry on photocatalytic properties of the nanocomposite TiO2/ZrO2 was investigated. The traditional use of powdery photocatalyst for the degradation of organic compounds has post-treatment problems which means much higher time and costs. A novel method to minimize these problems is immobilization by insertion onto an inert substrate. Several geometries of TiO2–10%ZrO2 (T-10Z) nano-photocatalysts (powder, fiber, film, and network-shaped) were produced using different templates. The products were characterized by X-ray diffraction, field emission scanning electron microscopy, Brunauer–Emmett–Teller, and diffuse reflectance... 

In typical photocatalytic processes slurry reactors are used in which catalyst particles have to be separated from the solution after the process ends which means much higher time and costs. Hence, immobilizing process is carried out on the catalyst to overcome this problem. In this work, fiber and network geometries were produced by particle precipitation on substrates. The obtained structures were characterized by XRD, SEM, and Brunauer–Emmett–Teller analyses. Photocatalytic performance of the samples was investigated by methyl orange degradation and also by hydrogen generation from water/methanol splitting. From the SEM images, the size range of the TiO2 particles in the network... 

Self-propagating exothermic reactions during mechanical milling of FeCl 3/CoCl 2 mixture together with sodium seeds resulted in formation of Fe 50Co 50 nanoparticles. Highly exothermic reactions resulted in temperature raise and formation of Fe 50Co 50 phase within the first 5min; however Fe 50Co 50 single-phase was obtained after 30min of milling. The products were characterized by XRD, SEM, EDS, TEM and VSM. Obtained results showed that both milling time and NaCl salt matrix affected the size, morphology, microstructure and magnetic properties of the produced particles  

The one-dimensional cutting stock problem has many applications in industries and during the past few years has been one of the centers of attention among the researchers in the field of applied operations research. In this paper, a revised version of Ant Colony Optimization (ACO) technique is presented to solve this problem. This paper is a sequel to the previous ACO algorithm presented by the authors. In this algorithm, according to some probabilistic rules, artificial ants will select cutting patterns and generate a feasible solution. Computational results show the high efficiency and accuracy of the proposed algorithm for solving one- dimensional cutting stock problem  

Introduction: The COVID-19 pandemic has considerably affected human beings most of whom are healthcare workers (HCWs) combating the disease in the front line. Methods: This cross-sectional study aims to explore the effects of stress and anxiety caused by COVID-19 on the quality of sleep and life in HCWs, including physicians, nurses, and other healthcare staff. In this global study, we asked 1,210 HCWs (620 and 590 volunteers from Iran and European countries, including Germany, the Netherlands, and Italy, respectively), who age 21–70, to participate in the test. Several measures of COVID-related stress, anxiety, sleep, and life quality, including the 12-item General Health Questionnaire...