Sharif Digital Repository

Uranium (VI) sorption using an anionic exchanger resin, namely Amberlite IRA910, in the presence of sulfate anions was the subject of current study. Batch sorption experiments were carried out to evaluate the influence of operational parameters such as pH, contact time, initial concentration and existence of various anions (including phosphate, sulfate, chloride, fluoride, and nitrate) in the solution on Amberlite IRA910 sorption behavior. Experiments revealed that uranium adsorption was fulfiled at pH>3 and 50 min to amount of 80%. Kinetics study revealed that the pseudo-second-order model showed better curve-fitting regression of the experimental data than the pseudo-first-order one.... 

Molecular dynamics simulations of four ionic liquids (ILs) based on the [Tf2N] bis(trifluoromethanesulfonyl)imide anion, and imidazolium cations with different alkyl side chains have been performed. These simulations investigate the influence of butyl side chain elimination, tail amine functional addition, and C2 methylation on the dynamics and transport properties of this family of ionic liquids at 400 K. In our earlier work (J. Chem. Eng. Data, 2014, 59, 2834-2849), a suite of thermodynamic quantities and microscopic structures of these ILs were studied by classical molecular dynamics simulations and ab initio calculations. In this work, the dynamics of the ILs are studied by calculating... 

In this study, the feasibility of producing power and hydrogen from the waste heat of different City Gate Stations (CGSs) is investigated to select the optimal working conditions. A thermodynamic model is developed for a proposed system combined of the CGS station, the Rankin cycle and the extended hydrogen production cycle. Initially, six CGS stations are simulated based on energy, exergy-economic and environmental analysis and then a comparative study is conducted between different stations. The results of numerical modeling show that the Mashhad-old station with 5315 kW and 31.062 ton/year has the highest amount of power and hydrogen production among other stations, respectively. It is... 

One of the most important biological components is lipid nanobio membrane. The lipid membranes of alive cells and their mechanical properties play an important role in biophysical investigations. Some proteins affect the shape and properties of the nanobio membrane while interacting with it. In this study a multiscale approach is experienced: first a 100ns all atom (fine-grained) molecular dynamics simulation is done to investigate the binding of CTX A3, a protein from snake venom, to a phosphatidylcholine lipid bilayer, second, a 5 micro seconds coarse-grained molecular dynamics simulation is carried out to compute the pressure tensor, lateral pressure, surface tension, and first moment of... 

A very important part of the living cells of biological systems is the lipid membrane. The mechanical properties of this membrane play an important role in biophysical studies. Investigation as to how the insertion of additional phospholipids in one leaflet of a bilayer affects the physical properties of the obtained asymmetric lipid membrane is of recent practical interest. In this work a coarse-grained molecular dynamics simulation was carried out in order to compute the pressure tensor, the lateral pressure, the surface tension and the first moment of lateral pressure in each leaflet of such a bilayer. Our simulations indicate that adding more phospholipids into one monolayer results in... 

The lipid membranes of living cells form an integral part of biological systems, and the mechanical properties of these membranes play an important role in biophysical investigations. One interesting problem to be evaluated is the effect of protein insertion in one leaflet of a bilayer on the physical properties of lipid membrane. In the present study, an all atom (fine-grained) molecular dynamics simulation is used to investigate the binding of cytotoxin A3 (CTX A3), a cytotoxin from snake venom, to a phosphatidylcholine lipid bilayer. Then, a 5 ms coarse-grained molecular dynamics simulation is carried out to compute the pressure tensor, lateral pressure, surface tension, and first moment... 

Microfluidic devices are beneficial in miniaturizing and multiplexing various cellular assays in a single platform. Chondrogenesis is known to pertain to chemical, topographical, and mechanical cues in the microenvironment. Mechanical cues themselves have numerous parameters such as strain magnitude, frequency, and stimulation time. Effects of different strain magnitudes on the chondrogenic differentiation of adult stem cells have not been explored thoroughly. Here, a new multilayer microdevice is presented for the unidirectional compressive stimulation of cells in a three-dimensional cell culture. Numerical simulations were performed to evaluate and optimize the design. Results showed a... 

Endothelial cell migration is a crucial step in the process of new blood vessel formation - a necessary process to maintain cell viability inside thick tissue constructs. Here, we report a new method for maintaining cell viability and inducing cell migration using a perfused microfluidic platform based on collagen gel and a gradient hydrogel sheet. Due to the helpful role of the extracellular matrix components in cell viability, we developed a hydrogel sheet from decellularized tissue (DT) of the bovine heart and chitosan (CS). The results showed that hydrogel sheets with an optimum weight ratio of CS/DT = 2 possess a porosity of around 75%, a mechanical strength of 23 kPa, and display cell... 

In a MIMO (Multiple Input Multiple Output) radar system, proper design of transmit signal and receive filter is an advantageous tool to improve the detection performance. Thus, in this paper, we consider the problem of transmit code and receive filter design, in order to maximize the Signal to Noise Ratio (SNR) at the receiver while enforcing a similarity constraint between the transmit space-time code (STC) and a reference STC which has a desirable ambiguity function. We will show that by solving such constrained optimization problem through successive iterations, our proposed method leads to satisfactory results  

Weighting elements to achieve radiation patterns with desired characteristics is a classical work in phased array antennas. These characteristics can be low sidelobe level, narrow beamwidth, high directivity, pattern nulling in special angle and etc. For each of these characteristics, different methods have been introduced. Most of methods have been presented for uniform arrays, however there are lots of methods to obtain a desired pattern for antennas with non-uniform element distances. The problem with these methods is complexity or not very good results. In this paper, fast and easy methods based on Least Square Error that leads to good results are presented. In addition, weighting of... 

Distributed generation connected with AC, DC, or hybrid loads and energy storage systems is known as a microgrid. Campus microgrids are an important load type. A university campus microgrids, usually, contains distributed generation resources, energy storage, and electric vehicles. The main aim of the microgrid is to provide sustainable, economical energy, and a reliable system. The advanced energy management system (AEMS) provides a smooth energy flow to the microgrid. Over the last few years, many studies were carried out to review various aspects such as energy sustainability, demand response strategies, control systems, energy management systems with different types of optimization... 

This paper resolve the salinity-dependent interactions of polar components of crude oil at calcite-brine interface in atomic resolution. Molecular dynamics simulations carried out on the present study showed that ordered water monolayers develop immediate to a calcite substrate in contact with a saline solution. Carboxylic compounds, herein represented by benzoic acid (BA), penetrate into those hydration layers and directly linking to the calcite surface. Through a mechanism termed screening effect, development of hydrogen bonding between –COOH functional groups of BA and carbonate groups is inhibited by formation of a positively-charged Na+ layer over CaCO3 surface. Contrary to the common... 

An important tool for assessing a radar's performance is the ambiguity function. On the other hand, many different schemes have been designed for the transmit waveforms of a MIMO radar. For each one, a criterion has been chosen to improve the performace, e.g. achieving better missed detection. In this paper, considering the ambiguity function as the benchmark, we propose a waveform design scheme, which optimizes the ambiguity function of the MIMO radar system  

Flow hydrodynamics of laminar falling film of aqueous Li Br solution (Li Br - H2O) on a horizontal elliptical tube has been investigated in this research. The film velocity distribution and film thickness, namely, the flow characteristics are determined by solving analytically simultaneous simplified Navier - Stokes equations and continuity equation in polar and Cartesian coordinates. The analysis is based on steady state laminar flow of falling liquid film of Li Br - H2O on a horizontal elliptical tube in polar model and Cartesian model (CM), for cases in which traction on the film surface is considered negligible. Models are compared with each other in three cases of aspect ratios (Ar),... 

Velocity distributions in (r,θ) directions are evaluated by solving simultaneous simplified Navier-Stokes equations (NSE) and continuity equation (CE) in polar coordinate. The analysis is based on steady state laminar flow of thin falling liquid film on a horizontal circular tube, for cases in which traction on the film surface is considered negligible. It is a common geometry for part of engineering problems such as evaporator, condenser, absorber, generator of absorption chillers and other similar units in mechanical and chemical engineering. Knowledge of the velocity profiles is usually needed for: 1 - solving governing energy and species equations 2- estimating the average and film... 

Velocity distributions in (r,θ) directions are evaluated by solving simultaneous simplified Navier-Stokes equations (NSE) and continuity equation (CE) in polar coordinate. The analysis is based on steady state laminar flow of thin falling liquid film on a horizontal circular tube, for cases in which traction on the film surface is considered negligible. It is a common geometry for part of engineering problems such as evaporator, condenser, absorber, generator of absorption chillers and other similar units in mechanical and chemical engineering. Knowledge of the velocity profiles is usually needed for: 1- solving governing energy and species equations 2- estimating the average and film... 

This work concerns the experimental investigation of surfactant alternating CO 2 injection in carbonate rocks. The core samples provided from a low-temperature fractured light oil reservoir, located in southwest Iran. The experiments were designed to observe the effect of CO 2-foam injection on gas mobility and oil recovery at different surfactant concentrations. The core samples were initially saturated with synthetic/field brine, 5,000 ppm, and then flooded with live oil to reach connate water saturation at reservoir condition, 115F and 1,700 psia. The commercial surfactant used was sodium lauryl sulfate as an anionic surfactant. The results of this work, along with field-scale simulation...