Sharif Digital Repository

TiO2 is a promising photoanode material for photoelectrochemical (PEC) water splitting, but its severe bulk recombination of photogenerated carriers, sluggish oxygen evolution reaction (OER) kinetics and poor visible light response are the main bottleneck problems. Here, the carbon quantum dots (CQDs) modified anatase/rutile TiO2 photoanode (CQDs/A/R-TiO2) was designed by growth of anatase TiO2 nanothorns on rutile TiO2 nanorods and further surface modification of CQDs. The results revealed that the A/R-TiO2 heterojunction significantly suppressed the bulk recombination of photogenerated carriers. With further incorporation of CQDs into A/R-TiO2, dramatical improvement of OER kinetics and... 

There are very limited researches carried out to investigate the influence of saturation degrees, freezing-thawing, and curing times on geotechnical properties of lime concrete (LC) and lime-cement concrete (LCC) due to the capillary action and changes in groundwater table. Subsequently, the primary goal of this research is to investigate the influence of these parameters on mechanical properties of LC and LCC using unconfined compression tests, namely uniaxial compressive strength (UCS), stress-strain behavior, deformability index (I D ), secant modulus (E S ), failure strain, bulk modulus (K), resilient modulus (M R ), brittleness index (I B ), and shear modulus (G). At first, the... 

Nickel oxide (NiOx) is a promising hole transport material in inverted organic-inorganic metal halide perovskite solar cells. However, its low intrinsic conductivity hinders its further improvement in device performance. Here, we employ a trimercapto-s-triazine trisodium salt (TTTS) as a chelating agent of Ni2+ in the NiOx layer to improve its conductivity. Due to the electron-deficient triazine ring, the TTTS complexes with Ni2+ in NiOx via a strong Ni2+-N coordination bond and increases the ratio of Ni3+:Ni2+. The increased Ni3+ concentration adjusts the band structure of NiOx, thus enhancing hole density and mobility, eventually improving the intrinsic conductivity of NiOx. As a result,... 

The present experimental and analytical study aims to modify conventional cement to create a higher strength-to-weight ratio concrete using hybrid nanomaterials, i.e., Carbon Nanotubes (CNTs) and Nano-Silica (NS), as a partial replacement for cement (Nano-blended cement). In this study, three CNTs and four NS contents were chosen to evaluate the mechanical properties of concrete. 234 tests for specimens at 7, 28, and 90 days were carried out to achieve the optimum composition of the nanoparticles for the compressive strength and splitting tensile strength. Test results of the specimens examined at 28 days illustrate that the compressive strength and tensile strength were improved by 125 % by... 

This research explored the influences of shielding gases on the appearance of weld beads and the microstructures and mechanical properties of thin-wall samples using conventional gas metal arc welding as the heat source by using 5356 aluminium alloy welding wire as the raw materials and nitrogen (N2) and argon (Ar) as the shielding gases. The results showed that under the same parameters and after mono-layer single-bead welding was performed using N2 as the shielding gas, the bead height was higher, the bead width was narrower, and the penetration depth was shallower. The grain size of the thin-wall sample protected by N2 was 43.5–47.8 % smaller than that obtained under Ar protection.... 

Aluminum alloys and high density polyethylene are utilized in a wide variety of industrial applications. In the present work the feasibility of friction stir butt welding between AA5059 alloy and high density polyethylene sheets is examined. The bonding mechanism, joint strength, and microhardness are considered in this study. Various welding parameters and tool alignment were investigated until sound joints were achieved by positioning approximately 85% of the rotating tool in the aluminum material on the advancing side (1.4 mm offset) at constant spindle speed and traverse speed of 710 rpm and 63 mm/min, respectively. The results indicate that AA5059 aluminum and high density polyethylene... 

The open or in-filled trenches are often used in engineering practice to mitigate ground vibration induced by different types of vibration sources. A novel approach which is considering the effect of Rayleigh wavelength on the efficiency of open and in-filled trenches coupled with regular specific normalized dimensions was implemented in this study. While impact loading is a very common type of loading (in, e.g., machine foundations, driven pile installation), it was rarely studied in the past. The loading is selected to consist of 12 impact pulses. In this study, it was shown that Rayleigh wavelength controls the effect of trench-normalized dimensions on its performance, and therefore,... 

The open or in-filled trenches are often used in engineering practice to mitigate ground vibration induced by different types of vibration sources. A novel approach which is considering the effect of Rayleigh wavelength on the efficiency of open and in-filled trenches coupled with regular specific normalized dimensions was implemented in this study. While impact loading is a very common type of loading (in, e.g., machine foundations, driven pile installation), it was rarely studied in the past. The loading is selected to consist of 12 impact pulses. In this study, it was shown that Rayleigh wavelength controls the effect of trench-normalized dimensions on its performance, and therefore,... 

Because of the compatibility with tandem devices and the ability to be manufactured at low temperatures, inverted perovskite solar cells have generated far-ranging interest for potential commercial applications. However, their efficiency remains inadequate owing to various traps in the perovskite film and the restricted hole blocking ability of the electron transport layer. Thus, in this work, a wide-bandgap n-type semiconductor, 4,6-bis(3,5-di(pyridin-4-yl)phenyl)-2-phenylpyrimidine (B4PyPPM), to modify a perovskite film via an anti-solvent method is introduced. The nitrogen sites of pyrimidine and pyridine rings in B4PyPPM exhibit strong interactions with the undercoordinated lead ions in... 

Urea is a major source of nitrogen pollution in domestic sewage and its denitrification is difficult since it is very likely to be converted into ammonia or nitrate instead of expected N2. Herein, we propose an exhaustive denitrification method for urea via the oxidation of amine/ammonia-N with chlorine oxide radical, which induced from a bi-functional RuO2//WO3 anode, and the highly selective reduction of nitrate-N on cathode in photoelectrochemical cell (PEC). Under illumination, the WO3 photoanode side promotes the quantities hydroxyl and reactive chlorine radical, and these radicals are immediately combined to stronger chlorine oxide radical by RuO2 side, which obviously enhances the... 

The Electrorheological (ER) disk is a widely used smart material in various engineering applications due to its ability to change its mechanical properties in response to electric fields. The vibration analysis of such a disk is essential for understanding its dynamic behavior and designing efficient control strategies. In this paper, the hyperbolic differential quadrature method (HDQM) is applied to investigate the vibration responses of the ER disk. Both first and higher-order shear deformation theories are incorporated for modeling displacement fields in sandwich disks. In the interface of the layers’ compatibility conditions are applied. The HDQM is a numerical technique based on the... 

Sulfur-containing gaseous contaminant treatment is a key issue in the healthy and sustainable development of industry, especially SO2 and H2S occur with natural gas extraction and fossil fuel burning. Traditionally, the commercial method for H2S or SO2 requires numerous desiccants and enormous energy consumption. Encouragingly, electrochemical coupling system, which provide an efficient, sustainable, and economic pathway for sulfur-containing gaseous contaminants removal, can convert H2S and SO2 to recyclable substance in a moderate environment and simultaneously transfer the energy contained in them to other more valuable product. The current review discusses the mechanism and principle of... 

In this work, single- and double-layer electromagnetic wave absorbers were prepared by as-prepared MWCNTs/BaTiO3/pitted carbonyl iron composites. MWCNT/BaTiO3 (MW/BTO) was prepared via sol-gel method whereas the carbonyl iron particles (CI) were corroded via pitting corrosion method. The structural, microstructural, magnetic and microwave absorption properties of the composites were evaluated via X-ray diffraction (XRD), field emission scanning electron microscopy (FESEM), vibrating sample magnetometer (VSM) and vector network analyzer (VNA) methods. CST studio software was employed to simulate the microwave absorption characteristics of double-layer absorbers. Moreover, the effects of... 

The treatment of refractory wastewater and energy utilization are challenging environmental issues. Carbonate as the most common anion abounds in the aquatic environment. Here, we proposed a novel method to degrade carbonate-containing wastewater and simultaneous electricity generation via the combined oxidation of CO3[rad]− and O2[rad]− radicals. The CO3[rad]− radical was produced by the photoelectrode of TiO2/Si photovoltaic cell with the rear Si photovoltaic cell providing external bias, and the O2[rad]− radical was produced from the generation of H2O2 on a gas diffusion electrode (GDE), and they were both further enhanced from the activation reaction of H2O2 with HCO3− electrolyte. The... 

The paper at hand intends to evaluate thermoelastic damping (TED) in circular plates by incorporating nonlocal effect within the constitutive and heat conduction frameworks. To attain this purpose, nonclassical coupled thermoelastic equations are established on the basis of nonlocal elasticity theory and Guyer–Krumhansl (GK) heat conduction model. By considering symmetric time–harmonic vibrations, the size-dependent thermoelastic frequency equation is derived. By solving this nonclassical eigenvalue problem, real and imaginary parts of damped natural frequency are separated. According to the definition of TED in the framework of complex frequency approach, a closed-form expression... 

Electric power system and its components, most of which developed based on the rising electricity demand during economic growth periods of 1970s and 1980s, have aged and some are not being replaced quickly. In addition, the integration of variable sources of energy has changed the way assets are being managed for optimal operation. Aging assets and uncertainty in power system load profile and demand management create a challenge for the optimal operation and maintenance of the electricity grid. This special section aims at addressing the challenges and opportunities in deployment of smart grid technologies such as wireless sensors for condition monitoring and intelligent electronic devices... 

In this paper, the problem of content caching in 5G cellular networks relying on social-aware device-to-device (D2D) communications is investigated. Our focus is on how to efficiently select important users (IUs) and how to allocate content files to the storage of these selected IUs to form a distributed caching system. We aim at proposing a novel approach for minimizing the downloading latency and maximizing the social welfare simultaneously. In particular, we first model the problem of maximizing the social welfare as a many-to-one matching game based on the social property of mobile users. We study this game by exploiting users’ social properties to generate the utility functions of the... 

In this paper, the problem of content caching in 5G cellular networks relying on social-aware device-to-device communications (DTD) is investigated. Our focus is on how to efficiently select important users (IUs) and how to allocate content files to the storage of these selected IUs to form a distributed caching system. We aim at proposing a novel approach for minimizing the downloading latency and maximizing the social welfare simultaneously. In particular, we first model the problem of maximizing the social welfare as a many-to-one matching game based on the social property of mobile users. We study this game by exploiting users' social properties to generate the utility functions of the... 

Hydroxyapatite (HA) coatings were deposited on commercially pure titanium plates using a hydrothermal-electrochemical deposition method in an electrolyte containing calcium and phosphate ions. The deposition conditions used in this study were the followings: electrolyte temperature (33-80 °C), current density (1-8 mA/cm2), and deposition time (10-120 min). Needle-like and granular crystals of apatite coating were created with different concentrations of calcium (0.0021-0.042 M) and phosphate (0.00125-0.025 M) salts. The size of HA crystals of the coating was considerably changed with different concentration of calcium and phosphate salts, temperature of the electrolyte, and deposition time.... 

Electrochemical co-deposition approach was expanded to prepare composite bio-ceramic coating of hydroxyapatite (HA)/polyvinyl acetate on the surface of titanium. The role is to improve the bioactive and crystallization properties. The results of XRD, XPS, SEM and TEM characterization showed that by increasing amount of vinyl acetate in the composite bio-ceramic coating before and after immersing in the simulated body fluid (SBF), an oriented growth of HA planes on the (0 0 2) direction had been observed on titanium substrate. Also significant surface morphology changes were obtained