Sharif Digital Repository

The paper presents a computational model and the corresponding algorithm for estimating the arc energy distribution to conductive, convective and radiative heat transfer in an electric arc furnace (EAF). The proposed algorithm uses channel arc model (CAM) in order to compute the distribution of the arc energy through empirical equations (to approximate arc radius), ideal gas law (to approximate arc density) and results of magneto-hydro-dynamic (MHD) models (to approximate arc pressure, temperature and velocity). Results obtained using the proposed algorithm are comparable with other similar studies; however, in contrast to other arc-energy distribution models, this model requires only two... 

In this paper, a conceptual study and quantification of using a thermophotovoltaic system (TPV) to convert incident radiation on furnace panels to electrical energy is presented. In typical electric arc furnaces (EAF), a considerable amount of energy is wasted during the melting process, that is, steel enthalpy, off-gas extraction, vessel cooling, slag enthalpy, and others. Although a remarkable share of the energy is wasted in circulating water, the contained exergy is simply too low to be considered for heat recovery (under 0.5% of input exergy) in comparison to energy content of the extracted gasses and slag. In the performed study, a TPV power output is calculated as a function of arc... 

The paper presents a conceptual study on modification of the electric arc furnace (EAF) slag doors in order to allow removal of the excess slag from the EAF. The idea behind additional slag doors is to allow deslagging of the bath in certain unfavorable cases when the slag height is too great. Slags which exceed the optimal height cause unnecessary refractory corrosion and additional energy losses. The study proposes symmetric slag doors comprised of two hatches, i.e. upper and lower. The upper hatch is intended to decrease the slag height to the optimal level, while the lower hatch can be used to completely deslag the EAF at tapping. In this manner, tilting of the EAF is not necessary. A... 

The paper presents a comprehensive electric arc furnace (EAF) model, developed for simulation and model-based control of the EAF processes. The model consists of three sub models, i.e., (i) arc model; (ii) chemical and slag model; and (iii) heat-transfer model. Arc model predicts the amount of energy dissipated from the arcs using arc currents and arc lengths; chemical and slag model calculates chemical energy and changes of elements/compounds, slag height and slag quality; while the heat-transfer model uses calculations of the other two models in order to establish a reference energy system (RES) for each zone in the EAF due to the variations in arc length, slag height, and bath height. The... 

This paper presents an electric arc furnace (EAF) optimization framework intended to define optimal control profiles for the EAF, in order to increase its efficiency and thus reduce the energy consumption. The framework aims to minimize controllable losses and to maximize energy transfer to the bath and, consequently, minimize the operational costs. This is achieved through improved actuation of the EAF inputs, i.e., transformer power, oxygen lancing, and carbon addition. To achieve maximal energy transfer to the bath and to reduce the heat losses from the arcs, proper properties of the slag, such as foaminess and basicity, are a subject of considerable attention. The framework is designed... 

The paper studies the effects of solid and liquid steel properties on the heat transfer coefficient (HTC) in electric arc furnaces (EAFs). Mathematically speaking, the HTC is a function of solid and liquid steel properties. Different velocities of the bath cause different flow paths around the solid particles and therefore different HTCs - a computational issue that has not been addressed yet. Therefore, a simplified calculation model is proposed, intended for HTC estimation according to the EAF conditions. Although many studies investigated this topic, most of them either assume unconventional conditions for the EAF operation, are computationally complex or focus on a specific case; and... 

In the present work we obtained a series of NIR luminescent platinum(II) complexes with a pincer N^N^C ligand based on the conjugated {benzoimidazo[1,2-a]pyrazine} system with the [Pt(N^N^C)L]n+ structural motif (L = phosphine, alkynyl or pyridine-type ligands). We have also synthesized two complexes with bidentate phosphines that demonstrate different types of coordination: 1) as chelating ligand (in case of 1,2-bis(diphenylphosphino)benzene), that led to de-coordination of pyridine ring of N^N^C ligand and formation of a [Pt(N^C)dppb]+ complex; 2) as a bridging ligand (in case of bis(diphenylphosphino)methane) between two {Pt(N^N^C)} fragments in a dimeric complex of type... 

The combined action of ultraviolet irradiation and microwave heating onto acetonitrile solution of [Re((Formula presented.))(CO)3(NCMe)]OTf ((Formula presented.) =phenantroline and neocuproine) afforded cis,trans-Re((Formula presented.))(CO)2(NCMe)2]+ acetonitrile derivatives. Substitution of relatively labile NCMe with a series of aromatic N-donor ligands (pyridine, pyrazine, 4,4’-bipyridine, N-methyl-4,4’-bipyridine) gave a novel family of the diimine cis,trans-[Re((Formula presented.))(CO)2(L)2]+ complexes. Photophysical studies of the obtained compounds in solution revealed unusually high absorption across the visible region and NIR phosphorescence with emission band maxima ranging from... 

A Deza graph with parameters (n, k, b, a) is a k-regular graph with n vertices such that any two of its vertices have b or a common neighbours, where b ≥ a. In this paper we investigate spectra of Deza graphs. In particular, using the eigenvalues of a Deza graph we determine the eigenvalues of its children. Divisible design graphs are significant cases of Deza graphs. Sufficient conditions for Deza graphs to be divisible design graphs are given, a few families of divisible design graphs are presented and their properties are studied. Our special attention goes to the invertibility of the adjacency matrices of Deza graphs. © 2020, © 2020 Informa UK Limited, trading as Taylor & Francis Group  

A Deza graph with parameters (Formula presented.) is a k-regular graph with n vertices such that any two of its vertices have b or a common neighbours, where (Formula presented.). In this paper we investigate spectra of Deza graphs. In particular, using the eigenvalues of a Deza graph we determine the eigenvalues of its children. Divisible design graphs are significant cases of Deza graphs. Sufficient conditions for Deza graphs to be divisible design graphs are given, a few families of divisible design graphs are presented and their properties are studied. Our special attention goes to the invertibility of the adjacency matrices of Deza graphs. © 2020 Informa UK Limited, trading as Taylor &... 

The influence of the addition of the nonionic surfactants C12DMPO, C14DMPO, C10OH, and C10EO5 at concentrations between 10-5 and 10-1 mmol/L to solutions of β-casein (BCS) and β-lactoglobulin (BLG) at a fixed concentration of 10-5 mmol/L on the dilational surface rheology is studied. A maximum in the viscoelasticity modulus |E| occurs at very low surfactant concentrations (10-4 to 10-3 mmol/L) for mixtures of BCS with C12DMPO and C14DMPO and for mixtures of BLG with C10EO5, while for mixture of BCS with C10EO5 the value of |E| only slightly increased. The |E| values... 

The aim of this work was to study the treatment of strong beet sugar wastewater by an upflow anaerobic fixed bed (UAFB) at pilot plant scale. Three fixed bed bioreactors (each 60 L) were filled with standard industrial packing, inoculated with anaerobic culture (chicken manure, cow manure, anaerobic sludge digested from domestic wastewater) and operated at 32-34 °C with 20 h hydraulic retention time (HRT) and influent COD ranging between 2000-8000 mg/L. Under these conditions the maximum efficiency of organic content reduction in the reactor ranged from 75% to 93%. The reactor filled with standard pall rings made of polypropylene with an effective surface area of 206 m2/m3 performed best in... 

Let two coordinate systems, in possession of Alice and Bob, be related to each other by an unknown rotation R∈ SO (3). Alice is to send identical states | ψ⟩ to Bob who will make measurements on the received state and will determine the rotation R. The task of Bob is to estimate these parameters of the rotation R by the best possible measurements. Based on the quantum Fisher information, we show that Greenberger–Horne–Zeilinger (GHZ) states are near optimal states for this task. We show concrete measurements which will allow Bob to determine the rotation R. This shows that GHZ states, as superposition of macroscopically distinct states, are useful in yet another context in quantum... 

A Deza graph G with parameters (n,k,b,a) is a k-regular graph with n vertices such that any two distinct vertices have b or a common neighbours. The children GA and GB of a Deza graph G are defined on the vertex set of G such that every two distinct vertices are adjacent in GA or GB if and only if they have a or b common neighbours, respectively. A strongly Deza graph is a Deza graph with strongly regular children. In this paper we give a spectral characterisation of strongly Deza graphs, show relationships between eigenvalues, and study strongly Deza graphs which are distance-regular. © 2021 Elsevier B.V  

A Deza graph G with parameters (n,k,b,a) is a k-regular graph with n vertices such that any two distinct vertices have b or a common neighbours. The children GA and GB of a Deza graph G are defined on the vertex set of G such that every two distinct vertices are adjacent in GA or GB if and only if they have a or b common neighbours, respectively. A strongly Deza graph is a Deza graph with strongly regular children. In this paper we give a spectral characterisation of strongly Deza graphs, show relationships between eigenvalues, and study strongly Deza graphs which are distance-regular. © 2021 Elsevier B.V  

The reaction of thiooxindoles with various 2- and 3-substituted pyridinium salts afforded a variety of functionalized thiazocinoindoles. The products have been prepared in good to excellent yields by regioselective dinucleophilic C/S-cyclocondensation of thiooxindoles with pyridinium salts  

This paper presents synthesis and photophysical investigation of a very rare type of the ReI diimine complexes, [Re(diimine)(CO)3(OPR3)]+, R = Ph, Cy; diimine – phenanthroline and neocuproine, containing monodentate (unsupported) phosphine oxide ligands. The obtained compounds have been structurally characterized in solid phase by using XRD crystallography, which revealed unusual distortions in the pseudo octahedral rhenium environment, which may be ascribed to intramolecular interligand (phosphine oxide – diimine) interaction rather than to crystal packing effect. Optimization of the ground state structure of these molecules with the DFT method also confirmed intramolecular origin of the... 

Perovskite solar cells have been constructed under the standard procedure by employing soluble tetratriphenylamine-substituted Zn phthalocyanine as hole transporting material. Solution processed device construction was carried out under ambient conditions of 50–60% ambient humidity. Triphenylamine substitution played the double role of imparting solubility to the core metal phthalocyanine as well as to introduce electron-rich ligands, which could enhance the role of Zn phthalocyanine as hole transporter. Indeed, the obtained material was functional. The present data highlight tetratriphenylamine-substituted Zn phthalocyanine as hole transporting material but also highlight the importance of... 

Soils are usually weak in tension therefore different materials such as geosynthetics are used to address this inadequacy. Worldwide annual consumption of geosynthetics is close to 1000 million m2, and the value of these materials is probably close to US$1500 million. Since the total cost of the construction is at least four or five times the cost of the geosynthetic itself, the impact of these materials on civil engineering construction is very large indeed. Nevertheless, there are several significant problems associated with geosynthetics, such as creep, low modulus of elasticity, and susceptibility to aggressive environment. Carbon fiber reinforced polymer (CFRP) was introduced over two... 

It is known that no quantum process can produce a predetermined superposition of unknown arbitrary states. It has already been shown that with some partial information about the states, one can produce with some probability such superpositions. In general the success probability of these machines, even for orthogonal states, are less than unity. Here we show that there are specific machines that can produce superpositions of orthogonal qubit states with unit probability. © 2017 American Physical Society