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    , M.Sc. Thesis Sharif University of Technology Boraghi, Mahsa Sadat (Author) ; Parsafar, Gholamabbas (Supervisor)
    Abstract
    In 2009, a general equation of state (EOS-III) based on an effective near-neighbor pair interaction of an extended Lennard-Jones (3, 6, 12) type has been introduced as : , where is the compressibility factor, p and ρ stand for pressure and molar density , respectively, T is Temperature , and e, f and g are the temperature dependent coefficient of the equation of state . the Z_th and Z_in are the thermal and internal contributions of pressure in the compressibility factor, respectively. this equation of state gives a good description of all types of nano- and bulk –solid and bulk fluid at entire temperature and pressure ranges for which thee is experimental data. Investigation show that... 

    Modified WK-Recursive Topology for an Optical Network-on-Chip

    , M.Sc. Thesis Sharif University of Technology Mahdavian, Hojjat (Author) ; Hesabi, Shahin (Supervisor)
    Abstract
    Nowadays, a large proportion of the power consumption in high-performance multi-processor architectures on chip belongs to connections. Reducing power consumption while maintaining high efficiency in these architectures is one of the main concerns. Networks on Chip (NoC) originally were introduced to improve efficiency, but now, given the importance of power, we must provide some solutions to reduce power consumption, and delay in NOCs. Connections in chip can be divided into three categories: global, intermediate and local, while the length of global connections is almost constant in different scales, local connections are scalable. As a result improving efficiency of a small number of... 

    Synthesis and Comparative Study on Complex Formation of Azo-bearing Nitrogen-Donor Macrocyclic Ligands with Fullerene C60 and Cu(II) Cation

    , Ph.D. Dissertation Sharif University of Technology Mahdavian, Mahsa (Author) ; Ghanbari, Bahram (Supervisor)
    Abstract
    In the present research, a series of bimacrocyclic tweezer anchored through azobenzene moiety were synthesized and characterized by applying IR spectroscopy, 1H and 13C{1H} NMR, fluorescence spectroscopy, UV-visible spectroscopy, mass spectrometry and elemental analysis and in some cases by X-ray crystallography. Firstly, UV-visible spectroscopy established that the irradiation of the tweezers with UV light promoted the trans to cis isomerization. On the other hand, thermal cis-trans isomerization behavior of the azobenzene moiety in tweezers was surveyed in which the cis isomers were formed of the heating at 50 oC for 5 minutes. Where the -OH group was replaced with 4-toluenesulfonyl... 

    A Survey on the Effect of Travel Mode Choice on Citizens’ Subjective Wellbeing

    , M.Sc. Thesis Sharif University of Technology Mahdavian, Naeimeh (Author) ; Kermanshah, Mohammad (Supervisor)
    Abstract
    Different definitions of the term ‘subjective well-being’ have been defined by different researchers. While there is no definite definition for this concept, it can be related to one's life evaluation. The issue of citizens’ subjective well-being has not usually been considered in transportation policies, such as reducing single occupancy vehicle. However, subjective well-being reflects the individuals’ quality of life and can be one of the main priorities of any society. This study tries to find the effect of using various modes of travel including passenger car, motorcycle, public transportation and walking on citizens' subjective well-being. Subjective well-being is measured by... 

    Photoelectrocatalytic Performance of Mesoporous TiO2 Nanostructures Decorated with Cu-Ag-Zn Particles for CO2 Conversion

    , M.Sc. Thesis Sharif University of Technology Adel Rastkhiz, Mahsa Sadat (Author) ; Simchi, Abdolreza (Supervisor)
    Abstract
    The rise in carbon dioxide levels has led to the manifestation of numerous environmental challenges. Currently, the absorption and conversion of carbon dioxide into valuable fuel resources such as synthetic gas, methane, and ethylene are deemed crucial from both environmental and economic standpoints. Despite the presentation of photocatalysts such as titanium oxide and electrocatalysts such as copper, silver, and zinc, their efficiency in CO2 conversion is found to be insufficient. One potential solution to this problem is the utilization of photoelectrocatalytic CO2 recovery. In this study, the aim was to enhance the photoelectrocatalytic reduction of CO2 by designing and manufacturing... 

    The effect of sol-gel surface modified silver nanoparticles on the protective properties of the epoxy coating

    , Article RSC Advances ; Volume 6, Issue 23 , 2016 , Pages 18996-19006 ; 20462069 (ISSN) Ghazizadeh, A ; Haddadi, S. A ; Mahdavian, M ; Sharif University of Technology
    Royal Society of Chemistry  2016
    Abstract
    In this study, the effect of surface modified silver nanoparticles on the corrosion protection of an epoxy coating on mild steel was studied. An organosilane (3-methoxy silyl propyl metacrylate) was used as a surface modifier to increase the dispersability of the inorganic nanoparticles in the organic epoxy coating matrix. Fourier transform infrared spectroscopy (FTIR) and thermogravimetric analysis (TGA) were used to characterize the surface modified nanoparticles. Differential scanning colorimetry (DSC) was employed to study the effects of modified and unmodified nano-silver on the curing heat and glass transition temperature of the epoxy coatings. Salt spray and electrochemical impedance... 

    Coating of Sewage Pipes with Appropriate Nanomaterials Aimed at Preventing Biological Growth (Algae+Biofilm)

    , M.Sc. Thesis Sharif University of Technology Nezameddin, Mahsa Sadat (Author) ; Borghei, Mehdi (Supervisor) ; Ghasemi, Shahnaz (Co-Supervisor)
    Abstract
    Biological layers are one of the main problems related to water transfer with pipe lines which are formed through time in the inner surface of the pipes by the water nutrients. Hence, the inner surfaces in the pipe lines and water refineries should be made in order not to let these biological layers to be made. The reason is that when the biofilm is formed on these surfaces, the traversing water is polluted. Dredging of these pipes is not only necessary in most of the countries in the world and needs huge amounts of water but is also very complex and expensive.In this research, nanomaterials, namely ZnO, T〖iO〗_2،S〖iO〗_2 have been used to cover the surface of concrete and steel pipes (The... 

    Synthesis and Application of Preformed Viscoelastic Hydrogels in Enhanced Oil Recovery

    , M.Sc. Thesis Sharif University of Technology Aqcheli, Farzad (Author) ; Taghikhani, Vahid (Supervisor) ; Baghban Salehi, Mahsa (Supervisor)
    Abstract
    Preformed particle gels (PPGs) due to its advatantage over commonly used in situ gels has been successfully applied for controlling excess water production in mature oil reservoirs. Field results of using PPGs in oil fields shows that commonly used PPGs are highly sensitive to hard reservoir conditions such as high temperature and salinity and can not effectively block fractures and high permeability layers.Objects of this study are synthesis and evaluating performance of this novel polymer based hydrogel in oil reservoirs with high temperature and salinity. Central composite design ( which is a experiment design approach) was used for synthesizing thirteen gel samples and optimal sample was... 

    Design and Manufacture of Polymeric Nanocomposite in Order to Control the Production and Migration of Sand in Reservoirs

    , Ph.D. Dissertation Sharif University of Technology Saghandali, Farzin (Author) ; Taghikhani, Vahid (Supervisor) ; Baghban Salehi, Mahsa (Supervisor)
    Abstract
    Sand production from oil reservoirs leads to various problems, such as well productivity reduction, operating equipment corrosion, and increased production costs. Therefore, controlling sand production in unconsolidated reservoirs is crucial for operating companies. Chemical injection into the formation in order to strengthen and reduce sand production is one of the most important methods of sand control. In this study, a hydrogel nanocomposite was designed and its effectiveness in sand control was investigated. Various tests were carried out to define and assess its efficacy, as follows: Morphological tests demonstrated the creation of a dense, homogeneous, and porous structure. Structural... 

    Hybrid particle swarm-based-simulated annealing optimization techniques

    , Article IECON 2006 - 32nd Annual Conference on IEEE Industrial Electronics, Paris, 6 November 2006 through 10 November 2006 ; 2006 , Pages 644-648 ; 1424401364 (ISBN); 9781424401369 (ISBN) Sadati, N ; Zamani, M ; Feyz Mahdavian, H. R ; Sharif University of Technology
    2006
    Abstract
    Particle Swarm Optimization (PSO) algorithms recently invented as intelligent optimizers with several highly desirable attributes. In this paper, two new hybrid Particle Swam Optimization schemes are proposed. The proposed hybrid algorithms are based on using the Particle Swarm Optimization techniques in conjunction with the Simulated Annealing (SA) approach. By simulating three different test functions, it is shown how the proposed hybrid algorithms offer the capability of converging toward the global minimum or maximum points. More importantly, the simulation results indicate that the proposed hybrid particle swarm-based simulated annealing approaches have much superior convergence... 

    Robust multiple model adaptive control using fuzzy fusion

    , Article 2010 42nd Southeastern Symposium on System Theory, SSST 2010, Tyler, TX, 7 March 2010 through 9 March 2010 ; March , 2010 , Pages 19-24 ; 9781424456901 (ISBN) Sadati, N ; Dumont, G. A ; Feyz Mahdavian, H. R ; Sharif University of Technology
    2010
    Abstract
    A robust multiple model adaptive control strategy using fuzzy fusion (RMMAC-FF) is presented in this paper. The main idea in multi-model controllers is to identify the best model of the system at any instant of time and apply the appropriate control input to it. RMMAC-FF, integrates a fuzzy robust controller, with the fuzzy multiple model adaptive estimation and a fuzzy switching to come up with a new strong methodology to control complex systems. Simulation results of the RMMAC-FF on a two-cart system, used as a benchmark problem, verify the theory and confirm the effectiveness of the proposed controller  

    Adsorption of eco-friendly carthamus tinctorius on steel surface in saline solution: a combination of electrochemical and theoretical studies

    , Article Colloids and Surfaces A: Physicochemical and Engineering Aspects ; Volume 601 , 20 September , 2020 Nematian, B ; Ramazani Saadat Abadi,A ; Mahdavian, M ; Bahlakeh, G ; Haddadi, S. A
    Elsevier B.V  2020
    Abstract
    In this study, the different parts of carthamus tinctorius plant, including petal (SPE), leaf (SLE), and shoot (SSE), have been extracted. Adsorption of the extracts on mild steel in 3.5 wt. % NaCl solution was evaluated employing electrochemical impedance spectroscopy (EIS), potentiodynamic polarization, and electrochemical noise measurements (EN). The field-emission scanning electron microscopy (FE-SEM) and attenuated total reflectance Fourier transform infrared spectroscopy (ATR-FTIR) were employed to appraise the morphology of the samples surface subjected to the test solutions. According to the EIS results, the maximum adsorption efficiency belonged to the solution containing 1 g L−1 of... 

    Falcaria vulgaris leaves extract as an eco-friendly corrosion inhibitor for mild steel in hydrochloric acid media

    , Article Scientific Reports ; Volume 13, Issue 1 , 2023 ; 20452322 (ISSN) Alimohammadi, M ; Ghaderi, M ; Ramazani Saadatabadi, A ; Mahdavian, M ; Sharif University of Technology
    Nature Research  2023
    Abstract
    Undoubtedly, metal corrosion is one of the most challenging problems faced by industries. Introducing corrosion inhibitors is a reasonable approach to protecting the metal surface. Due to environmental concerns and the toxicity of industrial organic corrosion inhibitors, researchers are continually exploring acceptable replacements. The current study focused on the application of Falcaria Vulgaris (FV) leaves extract to mitigate mild steel (MS) corrosion in a 1 M HCl environment. The polarization findings demonstrated that the corrosion current density decreased from 264.0 µA/cm2 (for the sample submerged in the blank solution) to 20.4 µA/cm2 when the optimal concentration of 800 ppm of FV... 

    Development of an active/barrier bi-functional anti-corrosion system based on the epoxy nanocomposite loaded with highly-coordinated functionalized zirconium-based nanoporous metal-organic framework (Zr-MOF)

    , Article Chemical Engineering Journal ; 2020 Ramezanzadeh, M ; Ramezanzadeh, B ; Bahlakeh, G ; Tati, A ; Mahdavian, M ; Sharif University of Technology
    Elsevier B.V  2020
    Abstract
    For the first time, the UIO-66, NH2-UIO, and NH2-UIO particles covalently functionalized by Glycidyl Methacrylate (GMA@NH2-UIO), were utilized as the novel functional anti-corrosive fillers. The functionality, high surface area, phase composition, excellent thermal properties as well as chemical stability of the Zr-MOFs were proved by FT-IR, BET, XRD, TGA, and water stability tests, respectively. The smart pH-sensitive controlled-release activity of the corrosion inhibitors (i.e., Zr ions and organic compounds) from the prepared Zr-MOFs was proved by the water stability test of the Zr-MOFs particles in the acidic (pH = 2), neutral (pH = 7.5), and alkaline (pH = 12) solutions containing 3.5... 

    Epoxy nanocomposite coatings with enhanced dual active/barrier behavior containing graphene-based carbon hollow spheres as corrosion inhibitor nanoreservoirs

    , Article Corrosion Science ; Volume 185 , 2021 ; 0010938X (ISSN) Haddadi, S. A ; Ramazani Saadatabadi, A ; Mahdavian, M ; Arjmand, M ; Sharif University of Technology
    Elsevier Ltd  2021
    Abstract
    Graphene-based carbon hollow spheres (CHSs) fabrication, doped with 2-mercaptobenzimidazole (MBI) was successfully done in previous work. The active/barrier corrosion protection performance (CPP) of epoxy coatings was evaluated using salt spray test, electrochemical impedance spectroscopy (EIS), and scanning vibrating electrode technique (SVET). Results proved the active/barrier CPP enhancement of epoxy coatings in the presence of 3 wt. % MBI@CHSs. While the presence of MBI and empty CHSs in epoxy coatings did not further improve the active performance. An improvement in the adhesion loss of the epoxy coating, ca. 58 %, was observed in the presence of 3 wt. % MBI@CHSs. © 2021  

    Development of an active/barrier bi-functional anti-corrosion system based on the epoxy nanocomposite loaded with highly-coordinated functionalized zirconium-based nanoporous metal-organic framework (Zr-MOF)

    , Article Chemical Engineering Journal ; Volume 408 , 2021 ; 13858947 (ISSN) Ramezanzadeh, M ; Ramezanzadeh, B ; Bahlakeh, G ; Tati, A ; Mahdavian, M ; Sharif University of Technology
    Elsevier B.V  2021
    Abstract
    For the first time, the UIO-66, NH2-UIO, and NH2-UIO particles covalently functionalized by Glycidyl Methacrylate (GMA@NH2-UIO), were utilized as the novel functional anti-corrosive fillers. The functionality, high surface area, phase composition, excellent thermal properties as well as chemical stability of the Zr-MOFs were proved by FT-IR, BET, XRD, TGA, and water stability tests, respectively. The smart pH-sensitive controlled-release activity of the corrosion inhibitors (i.e., Zr ions and organic compounds) from the prepared Zr-MOFs was proved by the water stability test of the Zr-MOFs particles in the acidic (pH = 2), neutral (pH = 7.5), and alkaline (pH = 12) solutions containing 3.5... 

    PO43--Loaded zif-8-type metal-organic framework-decorated multiwalled carbon nanotube synthesis and application in silane coatings for achieving a smart corrosion protection performance

    , Article Industrial and Engineering Chemistry Research ; Volume 61, Issue 32 , 2022 , Pages 11747-11765 ; 08885885 (ISSN) Mohammadkhani, R ; Ramezanzadeh, M ; Fedel, M ; Ramezanzadeh, B ; Mahdavian, M ; Sharif University of Technology
    American Chemical Society  2022
    Abstract
    In this research study, interfacial assembled nanoporous zeolitic imidazolate framework (ZIF-8) multiwalled oxidized carbon nanotubes (MW-OCNTs) were developed and introduced into a silane coating. To analyze the destructive behavior of the nanoparticles exposed to salty solutions with three distinctive pHs of 2, 7.5, and 12, various types of tests such as X-ray diffraction (XRD), field emission scanning electron microscopy (FESEM), and inductively coupled plasma (ICP) were accomplished. The XRD test revealed that the main characteristic peaks of ZIF-8 were eliminated and/or their intensity decreased. In accordance with the obtained data from the XRD test, nanoparticles at pH = 2 had been... 

    PH-Sensitive polydopamine–La (III) complex decorated on carbon nanofiber toward on-demand release functioning of epoxy anti-corrosion coating

    , Article Langmuir ; Volume 38, Issue 38 , 2022 , Pages 11707-11723 ; 07437463 (ISSN) Ghaderi, M ; Saadatabadi, A. R ; Mahdavian, M ; Haddadi, S. A ; Sharif University of Technology
    American Chemical Society  2022
    Abstract
    The high aspect ratio and unique thermal and electrical characteristics of carbon nanofiber (CNF) made it an ideal physical barrier against the penetration of corrosive ions. However, the poor compatibility of the CNF with the polymer matrix and the lack of active corrosion inhibitors are the key limitations of this nanomaterial, resulting in short-term anti-corrosion resistance. An intelligent self-healing epoxy (EP) coating, including CNF modified with a polydopamine (PDA)-La3+ complex, was successfully fabricated to overcome these issues. Electrochemical impedance spectroscopy (EIS) evaluation implied that mild steel (MS) submerged in a 3.5 wt % NaCl solution containing the CNF-PDA-La... 

    A detailed atomic level computational and electrochemical exploration of the Juglans regia green fruit shell extract as a sustainable and highly efficient green corrosion inhibitor for mild steel in 3.5 wt% NaCl solution

    , Article Journal of Molecular Liquids ; Volume 284 , 2019 , Pages 682-699 ; 01677322 (ISSN) Haddadi, S. A ; Alibakhshi, E ; Bahlakeh, G ; Ramezanzadeh, B ; Mahdavian, M ; Sharif University of Technology
    Elsevier B.V  2019
    Abstract
    Seawater, which has been frequently applied in cooling and injection water systems, imposes severe pitting corrosion to mild steel. Addition of green and sustainable inhibitors based on renewable sources is one of the promising methodologies for restricting metal corrosion in chloride-containing electrolytes. In this study, for the first time, from both theoretical and experimental faces, the role of Juglans regia green fruit shell (JRS) extract as a sustainable potent corrosion inhibitor for mild steel was studied. The chemical structure of the JRS extract was deliberated by Fourier transform infrared spectroscopy (FT-IR). By electrochemical techniques including polarization, EIS and... 

    Butanol Production from Bagasse Sugarcane Black Liquor by Native Strain and Clostridium Acetobutylicum Species

    , M.Sc. Thesis Sharif University of Technology Hassani Atashgah, Milad (Author) ; Shayegan, Jalaleddin (Supervisor) ; Vossoughi, Manouchehr (Supervisor) ; Sedighi, Mahsa (Co-Supervisor)
    Abstract
    Considering the limitations of fossil fuels in recent years, as well as increasing demand for biofuels, it is anticipated that future attention to biofuels will increase further. Among biofuels, due to some disadvantages of bioethanol and biodiesel fuel, there is a tendency to use biobutanol, which does not have the disadvantages of the mentioned fuels. The cost of chemical production of butanol also led researchers to use biotechnology production of butanol. According to studies, butanol production can be achieved by fermenting some sugars such as glucose, xylose, and ... by anaerobic microorganism, but the cost of using these sugars has resulted in the use of natural sources of these...