Sharif Digital Repository

Monomer grafting, a unique technique for polysaccharide modification, is always performed under inert (e.g., N2) atmosphere. This work is the first report related to evaluating the possibility and efficiency of the grafting of acrylonitrile (AN) onto starch in presence of oxygen. Thus, corn starch (in both granular and gelatinized states) as well as soluble starch were grafted by AN using a ceric-carbohydrate redox initiating system. Graft copolymerizations were performed under nitrogen, air, and oxygen atmospheres at similar conditions. Grafting occurrence was verified using chemical and spectral proofs. The polymerization mechanism and kinetics were investigated by recording the... 

Acrylonitrile (AN) was grafted onto various natural and modified polysaccharides (i.e., gum arabic, gum tragacanth, xanthan gum, sodium alginate, chitosan, sodium carboxymethyl cellulose, hydroxyethyl cellulose, methyl cellulose) by using ceric-carbohydrate redox initiating system. After overcoming practical problems, mainly from the high viscosity of the aqueous solutions of the different substrates, the graft copolymerization reactions were run either in air or in N2 atmosphere under similar conditions. Grafting was confirmed using chemical and spectral (FTIR) proofs. The reactions were kinetically investigated using semi-empirical expressions and time-temperature profiles. An anomalous... 

As a result of adopting various sample preparation techniques and optical measurement strategies, there are different experimental datasets available for presenting the complex dielectric function of gold. Therefore, evaluating them and selecting the most reliable ones seem essential for the corresponding optical-based designs and applications. The Brendel-Bormann model, one of the most accurate theoretical models for rendering the complex dielectric function of materials, is considered an appropriate criterion for this purpose. Despite the model's computational complexity, MS Excel has been employed as a fast and accessible tool for calculating the model. According to the results, ‘Palik'... 

The relation between porosity and permeability parameters in carbonated rocks is complicated and indistinct. Flow units are defined with aim of better understanding reservoir unit flow behavior and relation between porosity and permeability. Flow units reflect a group of rocks with same geological and physical properties which affect fluid flow, but they do not necessarily coincide with boundary of facies. In each flow unit homogeneity of data is preserved and this homogeneity fades in the boundaries. Here, in this study, three methods are used for identification of flow units and estimation of average porosity and permeability in three wells of Tabnaak gas field located in south of Iran.... 

A combination of silica chloride and wet SiO2 was used as an effective deacetalizating agent for the conversion of acetals to their corresponding carbonyl derivatives under mild and heterogeneous condition  

Call admission control schemes are crucially Important concepts ID researches on cellular mobile networks. One of them is the new thinning scheme. In this study we define a confidence interval for threshold and the numerical results show the performance of the scheme in defined interval. Also we discuss the sensitivity of the scheme (in sample-based sensitivity method) at different thresholds. The results show the better performance in confidence thresholds and sensitivity of scheme into variations of thresholds  

In this paper, the simulation of biomolecules manipulation using molecular dynamics (MD) is studied. In order to investigate the manipulation behavior, we have used the ubiquitin as biomolecule, a single-walled carbon nanotube (SWCNT) as manipulation probe, a two-layer graphene sheet as substrate. Along this line, a series of simulations are conducted to study the effects of different conditions on the success of manipulation process. These conditions include tip diameter, vertical gap between the tip and substrate, initial orientation of protein, and the tip position with respect to the biomolecule  

This paper presents an effective hybrid optimal modulation technique for a cascaded H-bridge (CHB) multilevel inverter. The introduced method is generalized optimal pulsewidth modulation, which can be extended to any m-level CHB multilevel inverter operating at any switching frequency. The presented hybrid optimal modulation strategy includes the pattern exchange and optimal modulation techniques. In the optimal modulation technique, the hybrid interior-point algorithm, which is more flexible and efficient than conventional optimization techniques, is applied. The proposed hybrid optimal modulation strategy yields balanced units' output fundamental voltages, and low total harmonic distortion...