Sharif Digital Repository

Background: Integrated sewage sludge handling and heavy metal management are important issues that scientists are working to solve today. Methods: Hydrothermal carbonization of dewatered digested sewage sludge (DDSS) under various conditions is carried out in this work, followed by alkali activation. The response surface methodology is used to investigate the operating process conditions and optimize them in order to produce hydrochar with the highest modified adsorption capacity (yield and Pb2+ adsorption). Significant Findings: The ideal conditions are 182.4°C, 4.9 hours, 5.025 (w/w) water/DDSS ratio, and 3.5 (w/w) ZnCl2/DDSS ratio. In addition, the Langmuir isotherm (qmax =109.3 mg/g) and... 

Today, sugarcane bagasse (SB) is used for bioethanol and biodiesel production, energy generation, and adsorbent synthesis. The goal of this project is to determine the optimized conditions for producing adsorbent from sugarcane bagasse using hydrothermal carbonization (HTC) and KOH activation. To optimize process parameters such as reaction temperature, residence time, ZnCl2/SB mixing ratios, and water/SB mixing ratios, response surface methodology was used. The results revealed that the optimum modified adsorption occurred at 180 °C, 11.5 h, a water to biomass ratio of (5:1), and a ZnCl2 to precursor ratio of (3.5:1). The physicochemical features of optimum activated hydrochar were... 

Integrated biomass waste management and fresh water supply are crucial environmental problems that researchers are laboring to clarify today. The co-hydrothermal carbonization (co-HTC) of sugarcane bagasse (SB) and digested sewage sludge (DSS), with KOH activation, for SB and DSS waste management, was accomplished. In this research, the effect of process parameters and biomass ratio during co-HTC on modified hydrochar adsorption capacities was critically evaluated. To optimize operating parameters (temperature, time, catalyst/precursor ratio, water/precursor ratio, and SB/DSS ratio, response surface methodology was used. The optimum condition was 180 °C, 9.6 h, 3/1 DSS/SB ratio ([Formula... 

In the present study, the effect of the number of stages of Tesla Micro-Valve (TMV), as well as the dependency of Reynolds number, Re, on the valve performance has been analyzed. For this purpose, different layouts include one to four-stage with different sizes are investigated numerically. The main criterion for evaluation of valves performance is diodicity, Di. Unsteady and steady flow in valve have been simulated and compared. It is shown that although there are some difference but the trend is similar for both responses. Finally, 2-D and steady state computations of the fluid flow have been utilized that reveal a strong dependence of Di on Re and pressure drop, ΔP. The results showed... 

In this study, the performance of Tesla-type microvalves, used in micropumps for low frequency driving force, is examined. Three-dimensional and unsteady numerical analysis of fluid flow inside a valveless reciprocating micropump in the range of low working frequencies is carried out. Reciprocating movement of flow actuator provides the actuation and pumping of the working fluid. Ferrofluidic valveless micropump is one practical sample of this kind of micropumps that operate in the range of low working frequencies. To model the reciprocating movement of flow actuator, two time varying functions that includes sinusoidal and step excitation are employed. Also, the performance of... 

In nanometer-scale process technologies, the effects of process variations are observed in Multiprocessor System-on-Chips (MPSoC) in terms of variations in frequencies and leakage powers among the processors on the same chip as well as across different chips of the same design. Traditionally, worst-case values are assumed for these parameters and then a deterministic optimization technique is applied to the MPSoC application under design. We show that such worst-case-based approaches are not optimal with the increasing variation observed at system-level, and instead, statistical approaches should be employed. We consider the problem of simultaneously choosing MPSoC architecture and task... 

Colloidal gas aphron (CGA) based fluids have recently been introduced to develop depleted hydrocarbon reservoirs due to their ability in controlling fluid losses. Bubbles size of CGAs plays an important role in pore blockage ability as the controlling mechanism in fluid invasion reduction. However, fundamental understanding of how bubble size distribution is controlled by polymer and surfactant concentrations is not well discussed in the available literature. Almost all reported experiences on CGAs sizing were conducted on single bubble behavior, and little attention has been given to the variation of bubble size distribution (BSD) of CGAs at different levels of polymer/surfactant... 

Recently, Colloidal Gas Aphron (CGA) based fluids have been introduced to further develop depleted hydrocarbon reservoirs. This fluid system has been employed in an attempt to control drilling fluid invasion and, thus, reducing formation damage occurred during drilling operations. Understanding the mechanisms of fluid invasion control is of great importance for successful design and application of CGA-based fluids in drilling operations. Although fluid flow of conventional foams has been studied extensively in the available literature, little attention has been paid to CGA fluids flow, especially in heterogeneous fractured porous media. Here, an experimental study was conducted to achieve... 

Recently, colloidal gas aphron (CGA) fluids technology has been employed to drill depleted oil and gas reservoirs. Almost all reported experience on CGA fluids were conducted at ambient conditions, and little attention has been paid on the behavior of CGAs at high pressures which is more close to real conditions. In this study, high pressure experiments were conducted by using High Pressure Microscope cell to visualize/monitor the behavior of CGAs at elevated pressures. Single bubble behavior and bubble size distribution (BSD) of CGAs were investigated under different scenarios of pressure change. Results of experiments revealed that BSD of CGAs is controlled by the path of pressure changes,... 

Application of light-weight drilling fluids is essential to develop depleted hydrocarbon reservoirs. Recently, colloidal gas aphron (CGA)-based fluids have been introduced for such applications due to their ability in controlling fluid losses. In this work, a comprehensive experimental study was performed to choose the best formulation for CGA fluids by implementing static stability tests, rheological behavior measurements, and bubble size analyses of CGAs. Xanthan gum polymer and sodium dodecyl benzene sulfonate (SDBS), an anionic surfactant, and cetyl trimethyl ammonium bromide (CTAB), a cationic surfactant, were utilized to prepare CGAs. For the range of experiments conducted, the... 

Purpose: The purpose of this paper is to evaluate the galvanic corrosion of nitinol orthodontic wires with six dental alloys in artificial saliva and consider the effect of initiated localized corrosion and real surfaces of anode and cathode on galvanic current. Design/methodology/approach: Linear polarization and cyclic polarization curves for each alloy in de-aerated Duffo and Castillo's artificial saliva are obtained. Galvanic corrosion investigation is conducted by polarization curve intersection and mixed potential theory methods. In order to verify the initiation of localized corrosion, scanning electron microscopy is used. Findings: Initiation of localized corrosion on the anode... 

Synthesis of dithiocarbamates by the one-pot three-component Markovnikov addition reaction of an amine, carbon disulfide and an alkyl vinyl ether or N-vinylpyrrolidone is reported in polyethylene glycol (PEG) under a mild and green procedure with high yields and completely regiospecific. Also, the products were used as efficient starting materials for amidoalkylation of electron-rich arenes such as naphthols and indoles  

Development of novel engineering techniques that can promote new clinical treatments requires implementing multidisciplinary in-vitro and in-vivo approaches. In this study, we have implemented microfluidic devices and in-vivorat model to study the mechanism of neural stem cell migration and differentiation.These studies can result in the treatment of damages to the neuronal system. In this research, we have shown that by applying appropriate ranges of biochemical and biomechanical factors as well as by exposing the cells to electromagnetic fields, it is possible to improve viability, proliferation, directional migration and differentiation of neural stem cells. The results of this study can... 

Feeding a laboratory furnace with the gaseous kerosene, the resulting two-phase turbulent flame is simulated to study the effects of injecting soot nano-particles into the inflow air on the emissions of smoke aerosol, CO, and CO2species pollutants, and the resulting radiation heat transfer. We use our past experiences in aerosol modeling of soot nano/micro particles in turbulent nonpremixed flames burning simple hydrocarbon fuels and extend them to study the effects of injecting gaseous kerosene on the aforementioned parameters. To model the evolutionary process of soot nanoparticle formation, i.e., the nucleation, coagulation, surface growth, and oxidation, we employ a two-equation soot... 

In this paper, we study the frost formation and growth at the walls of a duct with uniform wall temperature variation. The simulation is performed for laminar flow regime considering suitable semi-empirical models incorporated with computational fluid dynamics (CFD) method. The frost growth is considered to be normal to the duct surface. Since the duct aspect ratio is high, we perform our simulations in two-dimensional zones. To simulate the frost layer properly, we solve both the energy and mass balance equations implementing some semi-empirical correlations on the frost side. At this stage, we suitably predict the required heat flux value at the solid boundary and the heat transfer... 

In this work, we study the gas mixing behavior in a micro T-mixer using the direct simulation Monte Carlo (DSMC) method. The gas mixing process is monitored through a T-mixer, which is fed by two different CO and N2 gases; flowing into the T-mixer through the upper and lower inlets. We investigate the effects of axial and lateral wall temperature gradients on the mixing evolution at different rarefaction levels. The achieved results show that any temperature difference between the channel walls would result in an increase in mixing length for the chosen wall temperature gradient ranges and the studies pressure cases. Our observations show that a positive temperature gradient toward the... 

Gupta et al. [J. Opt. Soc. Am. B. 24, No. 5 (2007)] have introduced a localized upward plasma density ramp to overcome the defocusing of a laser beam. We report that there are fundamental mistakes in their work. First, the density profile formula that they have introduced is dimensionally incorrect. Second, the calculated dielectric constant is wrong as well, which renders their main spot size equation and the quantitative results unacceptable, and it seriously falters the results of the self-focusing. We correctly derived a new equation of the spot size, and the computational curves are also presented