Sharif Digital Repository

Currently, ammonia, as a clean and sustainable energy carrier, is intensively synthesized from its elements during the Haber-Bosch technology. This process requires a large amount of energy and emits numerous amounts of carbon dioxide, because hydrogen is dominantly produced from fossil fuels through reforming processes. Biomass-derived glycerol steam reforming is an attractive alternative to traditional reforming for reducing the dependence on hydrocarbon resources and mitigating climate change. This research aims to intensify a heat-integrated process for the co-production of ammonia and syngas from glycerol valorization. In this process, glycerol reforming continuously provides hydrogen... 

Catalytic reduction of nitrobenzene is the leading technological step in aniline production. The hydrogen required for this stage, is dominantly produced from fossil fuels through reforming processes, which take much energy and emit large amounts of CO2. Biomass-derived glycerol steam reforming is an attractive alternative to traditional reforming to reduce the dependence on hydrocarbon resources and mitigate climate change. This research aims to analyze a mass- and heat-integrated multi-tubular membrane reactor, containing nitrobenzene hydrogenation (exothermic-side) and glycerol steam reforming (endothermic-side) for co-production of aniline and syngas. In this process, hydrogenation... 

We introduce the concepts of cohering and decohering power of quantum channels. Using the axiomatic definition of the coherence measure, we show that the optimization required for calculations of these measures can be restricted to pure input states and hence greatly simplified. We then use two examples of this measure, one based on the skew information and the other based on the l1 norm; we find the cohering and decohering measures of a number of one-, two-, and n-qubit channels. Contrary to the view at first glance, it is seen that quantum channels can have cohering power. It is also shown that a specific property of a qubit unitary map is that it has equal cohering and decohering power in... 

Hydrogen and syngas, as two effective clean fuels, have a considerable stake in the global fuel market. These are dominantly produced from fossil fuels through reforming processes, which lose a large amount of energy and emit numerous amounts of CO2. Bio-renewable glycerol steam reforming is an attractive alternative to traditional reforming for reducing the dependence on hydrocarbon resources and mitigating climate change. This research aims to manage a heat-integrated reactor with three concentric cylinders, containing exothermic-side (methane tri-reforming), endothermic-side (glycerol steam reforming), and permeation-side for co-production of pure hydrogen and syngas. In this process,... 

We investigate the correlation properties of separable two-qubit states with maximally mixed marginals. These states are divided to two sets with the same geometric quantum correlation. However, a closer scrutiny of these states reveals a profound difference between their quantum correlations as measured by more probing measures. Although these two sets of states are prepared by the same type of quantum operations acting on classically correlated states with equal classical correlations, the amount of final quantum correlation is different. We investigate this difference and trace it back to the hidden classical correlation which exists in their preparation process. We also compare these... 

Doubly fed induction generators (DFIGs) are widely used in wind power systems; hence their reliability model is an important consideration for production assessment and economic analysis of wind energy conversion systems. However, to date mutual influences of reliability analysis, production estimations and economic assessments of wind farms have not been fully investigated. This study proposes a reliability model for DFIG wind turbines considering their subcomponent failure rates and downtimes. The proposed production estimation algorithm leads to an economic assessment for wind farms. A comprehensive spare parts management procedure is then presented in the study. As a case study,... 

Determination of the time lag caused by utilization of different tubes to measure pressure on the surface of a wind tunnel model is an important problem in the field of aerodynamic especially for unsteady measurements where the pressure signature changes continuously with time. In this investigation the time required for the applied pressure at one end of different tubes to reach its original value (applied pressure) at the other end has been measured. Three plastic tubes and two polyethylene tubes with different lengths and different inner diameters; L=2, 5 and 10 m, d=1, 2 and 4 mm, were used to study the time lag. Experimental data show that the response time in a pressure measuring... 

Using a mechanical model and dislocation density based model, the evolutions of dislocation density and flow stress of pure copper during constrained groove pressing (CGP) process are investigated. In this regard, the strain and strain rate are achieved from the mechanical model and then input into the dislocation model. To verify the predicted flow stress, the process of constrained groove pressing is performed on the sheets of pure copper from one to three passes. The predicted flow stresses are compared with the experimental data and a good agreement is observed. Also, it is found that during the straining of the copper sheet in CGP process, the dislocation density and strength dropping... 

In this work, ignition process in a turbulent shear-less methane-air mixing layer is numerically investigated. A compressible large eddy simulation method with Smagorinsky sub-grid scale model is used to solve the flow field. Also, a thickened flame combustion model and DRM-19 reduced mechanism are used to compute species distribution and the heat release. Non-reacting mean and RMS axial velocity profiles and mean mixture fraction are validated against experimental data. Instantaneous mixture fraction contours show that the large bursts penetrate from the fuel stream into that of the oxidizer and vice versa and a random behaviour in the cross-stream direction. Flame kernel initiation, growth... 

Ignition process in a premixed methane-air swirl configuration is studied using a large eddy simulation method with Smagorinsky sub-grid scale model. A developed thickened flame combustion approach with two-step methane-air mechanism is used. Non-reacting mean and RMS axial, tangential and radial velocity profiles are validated against the experimental results. It is shown that the flow field consists of four zones: Inner Recirculation Zone, Inner Shear Layer, Outer Shear Layer and Corner Recirculation Zone. The mean and RMS of velocities and temperature in reacting flow are then validated against the experimental data. Large eddy simulation is used to investigate the ignition sequence by... 

In this work, the inhibitory activity of pyridine N-oxide derivatives against human severe acute respiratory syndrome (SARS) is predicted in terms of quantitative structure-activity relationship (QSAR) models. These models were developed with the aid of multivariate adaptive regression spline (MARS) and adaptive neuro-fuzzy inference system (ANFIS) combined with shuffling cross-validation technique. A shuffling MARS algorithm is utilized to select the most important variables in QSAR modeling and then these variables were used as inputs of ANFIS to predict SARS inhibitory activities of pyridine N-oxide derivatives. A data set of 119 drug-like compounds was coded with over hundred calculated...