Sharif Digital Repository

In this study, decolorization of the diazo dye, Reactive Black 5 (RB5) in a Coprinus cinereus peroxidase-catalyzed reaction has been investigated. A bisubstate kinetic model for the reaction rate based on the Ping-Pong mechanism was assumed for the enzymatic decolorization. Experiments were conducted at different RB5 and hydrogen peroxide concentrations in a batch manner to estimate the intrinsic kinetic parameters. These parameters were used for the modeling of decolorization in a continuous reactor that was compared with experimental results. An acceptable agreement was observed between the model and experimental data  

In order to achieve the international climate goals and to keep the global temperature increase below 2 °C, carbon capture and storage in large point sources of CO2 emissions has received considerable attention. In recent years, mitigation of CO2 emissions from the power sector has been studied extensively whereas other industrial point source emitters such as hydrogen industry have also great potential for CO2 abatement. This study aims to draw an updated comparison between different hydrogen and power cogeneration systems using natural gas and coal as feedstock. The goal is to show the relative advantage of cogeneration systems with respect to CO2 emission reduction costs. Accordingly, the... 

In this paper, the authors analyze conditions under which they can be certain on the intensity addition of a given device, such as tapped-delay lines, used in digital incoherent all-optical communication systems. A general expression for phase-induced intensity noise that is applicable to all types of semiconductor lasers is derived by defining an optical self-SNR expression that can be used to analyze and measure phase-induced intensity noise. The result shows that in order to have a minimal phase-induced intensity noise in most digital optical incoherent systems, a large optical self-SNR, e.g., 20 dB or more, is needed. This in turn is shown to place a limit on the maximum rate of... 

An integrated hydrogen and power co-generation system with CO2 capture has been proposed and evaluated techno-economically. The proposed system is an alternative low cost clean power generation while supplying hydrogen for process plants. The baseline configuration has been designed based on the literature. Different cases are simulated in Aspen Plus and are evaluated economically. Thermodynamic models have been validated against the results of previous publications. The co-generation system with different product shares of hydrogen and power has been compared with CO2 captured and CO2-vented hydrogen plants by means of defined techno-economic-environmental indicators. Sensitivity analysis... 

Concepts like peculiar velocity, gravitational force, and power spectrum and their inter-relationships are of utmost importance in the theories of structure formation. The observational implementation of these concepts is usually based on the Newtonian hydro-dynamic equations, but used up to scales where general relativistic effects come in. Using a perturbation of FRW metric in harmonic gauge, we show that the relativistic effects reduce to light cone effects including the expansion of the universe. Within the Newtonian gravitation, the linear perturbation theory of large scale structure formation predicts the peculiar velocity field to be directly proportional to gravitational force due to... 

Colombeau's generalized functions are used to adapt the distributional approach to singular hypersurfaces in general relativity with signature change. Equations governing the dynamics of a singular hypersurface are derived and a specific non-vanishing form for the energy-momentum tensor of the singular hypersurface is obtained. It is shown that matching in the case of de Sitter space in the Lorentzian sector is possible along the boundary with minimum radius but leads to the vanishing of the energy-momentum tensor of the singular hypersurface