Sharif Digital Repository

Supercapacitors represent a new class of energy storage devices that have been attracted many researchers in last few years. Graphene with unique properties such as superior electrical conductivity and large specific surface area is one of the most suitable materials in supercapacitor applications. Besides, metal oxides are being used as active compounds in supercapacitors due to their role in redox reactions. In this research, synthesis and characterization of supercapacitor electrodes based on graphene and MnO2 nanostructured materials was studied under different conditions. For this purpose, Graphene oxide (GO) was synthesized by Hummers’ method and then, it was deposited on a nickel foam... 

Nowadays we see competition between organizations to maintain excellence and survival in business. Organizations should focus on maintaining and satisfying their customers in their services and products, because it is the customers who, as buyers of services and products, provide the company's revenue stream. With the advancement of computer technology today, a large amount of customer data can be stored and maintained. This data is a valuable resource for analyzing customer behavior and making the right decisions for the organization. Organizations need to use customer behavioral data to make their marketing activities smart and data-driven. In fact, organizations need to move towards... 

The concurrent flow of oil and water is a common occurrence in the field of multiphase flow in different fields including petroleum industry. In oil and gas, production engineers often face a situation in which more than one phase is flowing through the producers. In such conditions an accurate assessment of pressure loss inside the well plays a vital role in efficient and effective production planning. Changes in well orientation, wellbore diameter, reservoir and fluid properties as well as fluid flow rates are among parameters in which will affect the flow patterns that can occur inside a well during its life time. These flow patterns are created as a result of a competition between... 

Casing design is one of the most expensive parts in the drilling of oil wells, and any cost reduction with the basic design of these casing strings will significantly reduce the total cost of the operation. In recent years, occurring scenarios-based casing design has become popular; Because in many cases, it eliminates non-occurring scenarios such as gas kick and saves on drilling costs. In this study, we have tried to investigate all scenarios that may occur during the lifetime of the well, whether drilling or production, and for each well, based on its own field information, possible scenarios for each casing part are selected separately and the applying loads are calculated. For this... 

The electrochemical oxidation behavior of the anti-inflammatory drug piroxicam was investigated. A carbon nanoparticle (CNP)-chitosan (CS) film-coated graphite electrode (PGE) was fabricated and the electrochemical behaviors of piroxicam on its surface was investigated by the means of cyclic voltammetry (CV), linear sweep voltammetry (LSV) and electrochemical impedance spectroscopy (EIS). In comparison to the bare PGE, at the surface of the CNP-CS film modified electrode, the oxidation peak current of piroxicam increased significantly and the peak potential shifted negatively. Consequently, a simple and sensitive electroanalytical method was developed for the determination of piroxicam. The... 

There are high attractions in the development of conducting polymer (CP) coatings to improve the electrochemical properties and biocompatibility of electrodes in the area of biosensors. In the first part of this thesis, a new type of modified electrodes, constructing multi-walled carbon nanotubes (MWCNTs) and polypyrrole is prepared in a layer-by-layer process. In this procedure, the glassy carbon electrode is casted first by a drop suspension of MWCNTs, leading to formation a thin film on its surface. In the second step, electrochemical polymerization of pyrrole in the presence of tiron (used as doping anion) is performed on the surface of the MWCNTs pre-coated electrode. The modification... 

In the present work, edge-functionalaized graphene was used as electrode material and its electrochemical properties were systematically characterized by electrochemical impedance spectroscopy and cyclic voltammetry. Two methods were applied to modify the gold electrode surface. First method was the self assembling process of graphene nanosheets on gold electrode surface. Second method was simply casting specific amounts of graphene suspension on the gold electrode surface. Nyquist plots show decrease of the charge transfer resistance on the electrode surface at both cases. In cyclic voltammetry studies, first electrode shows no significant changes while the second electrode exhibits... 

Graph Theory and Combinatorial Analysis like the other branches of science use the probability for solving their problems. At the first , we will introduce the most common tools from probability used in Discrete Mathematics, such as “The Lovasz Local Lemma”. Most of them are based on Linearity of Expectation, Concentration Theorems and some other innovative methods such as Deletation Method. We will present different examples for these techniques. Also we will introduce “Random Graphs” and their importance. Specially we will explain how to use “Threshold Functions” to obtain different properties about the majority of graphs. Rainbow Connection, is a natural and interesting quantifiable way... 

At the first part of this thesis, a pyrolitic graphite electrode (PGE) modified with new coccine/multi-walled carbon nanotubes film (NC/MWCNT) was applied as a sensitive electrochemical sensor for determination and study of electrochemical behavior of tyrosine (Tyr) in aqueous solutions. The results showed that NC/MWCNT caused a remarkable increase in the peak current so the NC/MWCNT/PGE electrode surface was far more sensitive to the concentration of Tyr than the PGE surface. The determination of Tyr was investigated by linear sweep voltammetry (LSV). Experimental parameters, such as scan rate, pH and amount of the modifier used on the PGE surface were optimized by monitoring the LSV... 

There are many papers in which some graphs are assigned to algebraic structures such as rings groupsThe concept of regular graph related to a ring was rst investigated by DF Anderson and A Badawi in Assume that R is a commutative ring and Z??R denotes the set of zerodivisors of R and Reg??R R n Z??R The regular graph of R which is denoted by Reg????R is a graph whose vertex set is Reg??R and two vertices x and y are adjacent if and only if x y ?? Z??R This can be generalized to a non commutative ring For the vertex set we consider the set of left ??right zerodivisors and join two elements if their sum is a left ??right zerodivisor Let R be the ring of n n matrices over a eld F with... 

For an undirected graph G, a zero-sum flow is an assignment of non-zero real numbers on the edges of G such that the total sum of all edges incident with any vertex of G is zero. A zero-sum k-flow for a graph G is a zero-sum flow with labels from the set {±1, . . . , ±(k ? 1)}. In this thesis for a graph G, a necessary and sufficient condition forthe existence of zero-sum flow is given. It has been conjectured that if a graph G has azero-sumflow, then it has a zero-sum 6-flow. Also, it has been proved that this conjectureand Bouchet’s Conjecture for bidirected graphs are equivalent. It is shown that the con-jecture is true for 2-edge connected bipartite graphs, and every r-regular graph...