Sharif Digital Repository

In 2009, a general equation of state (EOS-III) based on an effective near-neighbor pair interaction of an extended Lennard-Jones (3, 6, 12) type has been introduced as : , where is the compressibility factor, p and ρ stand for pressure and molar density , respectively, T is Temperature , and e, f and g are the temperature dependent coefficient of the equation of state . the Z_th and Z_in are the thermal and internal contributions of pressure in the compressibility factor, respectively. this equation of state gives a good description of all types of nano- and bulk –solid and bulk fluid at entire temperature and pressure ranges for which thee is experimental data. Investigation show that... 

The rise in carbon dioxide levels has led to the manifestation of numerous environmental challenges. Currently, the absorption and conversion of carbon dioxide into valuable fuel resources such as synthetic gas, methane, and ethylene are deemed crucial from both environmental and economic standpoints. Despite the presentation of photocatalysts such as titanium oxide and electrocatalysts such as copper, silver, and zinc, their efficiency in CO2 conversion is found to be insufficient. One potential solution to this problem is the utilization of photoelectrocatalytic CO2 recovery. In this study, the aim was to enhance the photoelectrocatalytic reduction of CO2 by designing and manufacturing... 

Preformed particle gels (PPGs) due to its advatantage over commonly used in situ gels has been successfully applied for controlling excess water production in mature oil reservoirs. Field results of using PPGs in oil fields shows that commonly used PPGs are highly sensitive to hard reservoir conditions such as high temperature and salinity and can not effectively block fractures and high permeability layers.Objects of this study are synthesis and evaluating performance of this novel polymer based hydrogel in oil reservoirs with high temperature and salinity. Central composite design ( which is a experiment design approach) was used for synthesizing thirteen gel samples and optimal sample was... 

Biological layers are one of the main problems related to water transfer with pipe lines which are formed through time in the inner surface of the pipes by the water nutrients. Hence, the inner surfaces in the pipe lines and water refineries should be made in order not to let these biological layers to be made. The reason is that when the biofilm is formed on these surfaces, the traversing water is polluted. Dredging of these pipes is not only necessary in most of the countries in the world and needs huge amounts of water but is also very complex and expensive.In this research, nanomaterials, namely ZnO, T〖iO〗_2،S〖iO〗_2 have been used to cover the surface of concrete and steel pipes (The... 

Sand production from oil reservoirs leads to various problems, such as well productivity reduction, operating equipment corrosion, and increased production costs. Therefore, controlling sand production in unconsolidated reservoirs is crucial for operating companies. Chemical injection into the formation in order to strengthen and reduce sand production is one of the most important methods of sand control. In this study, a hydrogel nanocomposite was designed and its effectiveness in sand control was investigated. Various tests were carried out to define and assess its efficacy, as follows: Morphological tests demonstrated the creation of a dense, homogeneous, and porous structure. Structural... 

As fossil fuels are still the world's most important source of energy, as well as the maturity of most of the world's oil reservoirs, there is a need for enhanced oil recovery methods to meet the world's increasing oil demands. MEOR methods are new and promising methods that are still in the research and development stage. One of the MEOR methods is the use of biosurfactants, which increase the oil recovery by two mechanisms: 1) reducing the interfacial tension between water and oil and 2) changing the wettability of the rock. In this study, the performance of two glycolipid biosurfactants, rhamnolipid and sophorolipid, in increasing oil recovery has been investigated. Initially, surface... 

During the production of crude oil from reservoirs, the production of quantities of formation water along with this oil, causes the crude oil does not have the necessary indicators for transportation, refining and ultimately export. The presence of water and salt along with crude oil causes corrosion of refinery and transmission equipment and makes oil unfavorable in terms of economic efficiency (both for domestic use and for export). water and salt produce stable emulsion with oil that can be stable for a long time and can not be easily separated from crude oil. Therefore, separation of water and salt from crude oil is one of the most important issues in the oil industry. Breaking this... 

Considering the limitations of fossil fuels in recent years, as well as increasing demand for biofuels, it is anticipated that future attention to biofuels will increase further. Among biofuels, due to some disadvantages of bioethanol and biodiesel fuel, there is a tendency to use biobutanol, which does not have the disadvantages of the mentioned fuels. The cost of chemical production of butanol also led researchers to use biotechnology production of butanol. According to studies, butanol production can be achieved by fermenting some sugars such as glucose, xylose, and ... by anaerobic microorganism, but the cost of using these sugars has resulted in the use of natural sources of these... 

The methods of Enhanced Oil Recovery (EOR) from reservoirs have been taken into consideration recently due to the decline in oil reserves and the rise in energy demand. Studies and investigations indicate the tremendous potential of chemical approaches based on injecting ionic liquids into the porous media with the goal of improving oil recovery. Additionally, hydrogels and polymers, which are two of the process' primary materials, are thought to be good alternatives. In the current study, a hydrogel based on carboxymethyl cellulose was first created and synthesized. Ionic liquids based on imidazolium and triflate anion were then added, and their effectiveness in enhancing the properties... 

The notable share of housing sector in GDP (approximately five percent) shows this sector’s relation with macroeconomic activities. On the other hand, House as an asset leads housing sector to be affected by monetary and fiscal variables. A dynamic panel data was used in this study to evaluate the relations between housing sector and some macroeconomic variables in metropolises of Iran. As results show, in long term growth of liquidity, GDP per capita and sharp ratio have positive effects, and land per capita has negative effect on housing price in metropolises of Iran. Price increases have not been equal in different cities. Inequality of land price between metropolises and between... 

In this research, an Index of Iran informal economy in response to the government interventions in credit, labor and product markets is stimated by EMIMIC model. To do this, first these interventions are measured using principal components analysis. In the model, the variables GDP and employment are used as indicators and taxation rates, government distortions in credit, labor and product markets, government expenditure, per capita income, unemployment and inflation as causes of the informal economy. We conclude these government interventions have affected Iran informal economy and their influence is more than indirect interventions influence such as taxation. The estimated index of Iran... 

With altering natural state and increasing impervious surfaces, traditional urbanization leads to deteriorating the environment and water catchments. During the years most efforts in order to control the urban runoff outflow, have been focused on quantity; and awareness about improving water quality has been raised just in the last few years and, which emphasizes on pollution source control. Standard water quality sampling methods are time consuming, expensive and because of sampling in broad geographic areas, difficult; however modeling is a more efficient way in assessing water quality and as worries about non-point source pollution grows, different kinds of models have been used to... 

The role of government in economy has been a controversial subject in economics. Lately, there has been some fundamental change in evaluating this subject. One could mention two of these as 1) realizing the importance of micro-founded macro model for evaluating policy, and 2) taking into consideration the rent-seeking behavior of politicians. In this research, a general equilibrium in a micro-founded macro model will be discussed and then in political economics framework, the effect of government on this equilibrium will be investigated. Only the redistribution role of government has been considered. First, the model in which a benevolent government is seeking optimal policy is Discussed.... 

Gini coefficient is the most prevalent index for the measurement of inequality and is usually extracted by means of nominal variables based on income or expenditures of households. In this study we have extracted more accurate Gini coefficients. By using the raw data of Households Budget Survey (HBS) and STATA software, a special CPI for each household of the sample is extracted. Subsequently nominal expenditures are deflated by these special CPIs, and at last, Gini coefficients are extracted from real expenditures. Our findings indicate that in recent years, extracted Gini coefficients are remarkably higher than prevailing ones.
 

This paper investigates the behavior of the Y-shaped bracing system. Because of the special type of eccentricity in this system, the behavior of the frame is strongly dependent on the geometrical changes of the braces. So that even in the elastic region, it shows the geometrically nonlinear behavior. The amount of eccentricity is very effective on the nonlinear behavior of the frame. Also the ratio of cross sections of the bracing members has a very important impact on the expected performance of the frame. The results show that this system tolerates large displacements, and can act like a base isolation system. Firstly, using a two-dimensional accurate modeling related to the geometrical... 

The Overstrength, Ductility and the Response Modification Factor (R) for 70 steel X-braced , Inverted-V-Braced and Offcenter Bracing System frames were evaluated by performing pushover analysis of model structure with various stories (3,6,9,12&15 story) and span length (4,6&8 meter). Some result were compared with those from nonlinear dynamic analysis. According to the analysis result the R factors obtained from nonlinear dynamic analysis are 15% more than obtained from pushover analysis and R factors computed from pushover analysis were generally smaller than the values given in the design codes. R factors in Irregular structure in height are about 90% of R values in regular structure in... 

Maghemite (γ-Fe2O3) nanoparticles were produced after high temperature oxidation of gelatin-Fe3O4 nanocomposite, obtained from a common coprecipitation process of Fe2+ and Fe3+ ions in an alkaline medium in the presence of a gelatin protein as an effective mediator. Size, shape, surface morphology and magnetic properties of the prepared γ-Fe2O3 nanoparticles were characterized using XRD, FTIR, TEM, SEM and VSM data. The results revealed that primary, gelatin-Fe3O4 nanocomposite had been formed and next, the gelatin decomposition in furnace produced a spinel structure of γ-Fe2O3. The effects of furnace temperature and time of heating together with the amount of gelatin on the produced... 

The Response modification factor R represents the behavior of the structure such as ductility, overstrength and the inherent redundancy. This factor shall be defined according to the type of lateral force resisting system. However, there are some complexities and/or uncertainties in codes related to the R factor according to the height, form of irregularities and structural systems. Therefore, from the scientific point of view as well as reliability, it is very clear that the R factor cannot be similar for all kinds of structures, categorized as a specific group. In this investigation, assuming a low-rise, vertically irregular structure with a heliport which has a dual structural system... 

Maintaining the quality of water is of paramount importance for lakes with tourist attraction capacity. Inaccurate prediction of the quality state of lake in design phase may lead to some trouble in future. Kan River known as the main source of water feeding for the urban lake located in the north of Chitgar park passes through various villages and restaurants discharging nutrients via runoff and wastewater in the aforementioned river. Previous investigations reveal that phosphorous plays a central role in the water quality of this river and the associated downstream lake. In this research, Kan watershed,located in in the north-west of Tehran, was simulated. Considering the "Total Maximum... 

Findings of economics in last decade shows that social and economic institutions have direct influence on economic performance of a society. However, these institutions are determined by the state. In different regimes, the political power is in the hand of different social groups with different preferences and goals; as a result, different social and economic policies and institutions are take place in different political regimes. In this research, we study economic performance of a society under control of two different political regimes: in first, the majority rules the state and in second, there is a totalitarian regime in which; the political power is concentrated in hand of a group of...