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    Single-hydrogen dissociation paths for upright and flat acetophenone adsorbates on the Si(001) surface

    , Article Journal of Physical Chemistry C ; Volume 118, Issue 41 , 16 October , 2014 , Pages 23682-23689 ; ISSN: 19327447 Mehdipour, H ; Sharif University of Technology
    2014
    Abstract
    Using cluster-based density functional theory we investigate adsorption configurations of an acetophenone molecule on a Si(001) surface and their follow-up proton transfer processes. We examine two possible types of dative-adsorption configurations, up-right standing and flat, as well as compute their follow-up kinetically preferable on-dimer, interdimer, and inter-row proton transfers. Energetics of possible conversions between the achieved adsorption configurations are computed as well. Using all the data obtained, we theoretically illustrate reaction pathways leading to detached hydrogen positions captured in STM imaging of a Si(001) surface exposed to acetophenone vapor at room... 

    A study of the electrophoretic deposition of bioactive glass-chitosan composite coating

    , Article Ceramics International ; Volume 38, Issue 1 , January , 2012 , Pages 471-476 ; 02728842 (ISSN) Mehdipour, M ; Afshar, A ; Sharif University of Technology
    2012
    Abstract
    Bioactive glass is coated on implant's surface to improve corrosion resistance and osseointegration, when placed in the body. Bioactive glass particles were synthesized through a sol-gel process and deposited along with chitosan to form a composite coating on a stainless steel substrate using electrophoretic deposition technique. Stable suspensions of chitosan-bioactive glass were prepared using bioactive glass particles (<1 μm) and 0.5 g/l chitosan solution. The influence of ethanol-water ratio on deposition yield was investigated. For all process conditions, best results were achieved with suspension of 30 vol% water in ethanol-water containing 2 g/l bioactive glass. FTIR studies showed... 

    Chitosan–Bioactive Glass Composite Coating on Nd-Fe-B Magnetic Alloy Substrate by Electrophoretic Deposition

    , M.Sc. Thesis Sharif University of Technology Mehdipour, Mehrad (Author) ; Afshar, Abdollah (Supervisor)
    Abstract
    This research work deals with application of poly-saccharide to improve coating process of bioactive ceramic composite on aNd-Fe-B magnetic alloy substrate. Bioactive glass particles were synthesized through a sol-gel process and coated in the form of composite with poly-saccharide onto a magnetic substrate by electrophoretic deposition technique. Stable suspensions of 0.5 gr/lit polysaccharide polymer-ceramic were prepared using bioactive glass particles (<1µm), acetic acid 1%. The influence of added water to ethanol, pH and tri-ethanol-amine (TEA) additive on suspension stability, deposition rate and coating’s structure was investigated. It was shown that by increasing the water to ethanol... 

    Development of Procedures, Forms and Tools for Post-Earthquake Reconnaissance

    , M.Sc. Thesis Sharif University of Technology Mehdipour, Reza (Author) ; Mahsuli, Mojtaba (Supervisor)
    Abstract
    This study aims to design and develop procedures, forms, and tools for post-earthquake reconnaissance. The current procedure for data collection is based on the sending of groups to identify the dimensions of the evidence and its consequences by the executive and responsible institutions. Studying and reviewing the reports that have been produced by this method shows that there is not any systematic mechanism for collecting data on a wide scale and from all aspects of the evidence. The limited data collected by the executive and responsible institutions are scattered in the reports and are less documented in the database. Therefore, it is necessary to collect big data on the severity and... 

    Electrophoretic deposition of bioactive glass coating on 316L stainless steel and electrochemical behavior study

    , Article Applied Surface Science ; Volume 258, Issue 24 , 2012 , Pages 9832-9839 ; 01694332 (ISSN) Mehdipour, M ; Afshar, A ; Mohebali, M ; Sharif University of Technology
    Elsevier  2012
    Abstract
    In this research, submicron bioactive glass (BG) particles were synthesized by a sol-gel process and were then coated on a 316L stainless steel substrate using an electrophoretic deposition (EPD) technique. Stable suspension of bioactive glass powders in ethanol solvent was prepared by addition of triethanol amine (TEA), which increased zeta potential from 16.5 ± 1.6 to 20.3 ± 1.4 (mv). Thickness, structure and electrochemical behavior of the coating were characterized. SEM studies showed that increasing EPD voltage leads to a coating with more agglomerated particles, augmented porosity and micro cracks. The results of Fourier transformed infrared (FTIR) spectroscopy revealed the adsorption... 

    Urchin-like hierarchical ruthenium cobalt oxide nanosheets on Ti3C2T: XMXene as a binder-free bifunctional electrode for overall water splitting and supercapacitors

    , Article Nanoscale ; Volume 14, Issue 4 , 2022 , Pages 1347-1362 ; 20403364 (ISSN) Asen, P ; Esfandiar, A ; Mehdipour, H ; Sharif University of Technology
    Royal Society of Chemistry  2022
    Abstract
    Synthesizing efficient electrode materials for water splitting and supercapacitors is essential for developing clean electrochemical energy conversion/storage devices. In the present work, we report the construction of a ruthenium cobalt oxide (RuCo2O4)/Ti3C2Tx MXene hybrid by electrophoretic deposition of Ti3C2Tx MXene on nickel foam (NF) followed by RuCo2O4 nanostructure growth through an electrodeposition process. Owing to the strong interactions between RuCo2O4 and Ti3C2Tx sheets, which are verified by density functional theory (DFT)-based simulations, RuCo2O4/Ti3C2Tx MXene@NF can serve as a bifunctional electrode for both water splitting and supercapacitor applications. This electrode... 

    Influence of ion interaction on lead removal by a polyamide nanofiltration membrane

    , Article Desalination ; Volume 362 , April , 2015 , Pages 84-92 ; 00119164 (ISSN) Mehdipour, S ; Vatanpour, V ; Kariminia, H. R ; Sharif University of Technology
    Elsevier  2015
    Abstract
    Retention of lead(II) ions on a polyamide nanofiltration membrane was investigated. Effects of different factors including operating pressure, lead ion concentration, anion nature, pH and composition of feed on the lead ion rejection were studied. The solutions used consisted of Pb(NO3)2, PbCl2 and PbSO4 in the single-salt solution system and Pb(NO3)2, Cu(NO3)2, Zn(NO3)2, Cd(NO3)2, NaNO3 and NH4NO3 in the binary-salt solution system. The influence of divalent and monovalent cations including cadmium, copper, zinc, sodium and ammonium on the rejection of lead ion was examined. The transmembrane pressure and lead ion concentration varied between 10 and 40bar and 20 and 400mg Pb2+/L,... 

    Three Phase Modeling of Fluid Flow in the Well Tubing to predict Asphaltene Deposition

    , M.Sc. Thesis Sharif University of Technology Mehdipour, Hossein (Author) ; Ayatollahi, Shahaboddin (Supervisor)
    Abstract
    In this thesis, by focusing on the hydraulics of three phase flow in vertical tubing to investigate asphaltene deposition problem, the solid particles behaviors in a turbulent flow is fully studied. Reasonable size distribution for particles (based on previous works and researches) was assumed and a model for 2 sections of a Marrat oil field well to evaluate their asphaltene deposition problem was developed. Three phase liquid-gas-solid flow in the well tubing was simulated. Asphaltene deposition profile on the well tubing, mean and maximum of the deposition rate and particle concentrations in the flow regime were calculated and compared with real field data. Better agreement with field data... 

    Multivariable Fragility Curves for Reinforced Concrete Columns

    , M.Sc. Thesis Sharif University of Technology Mehdipour, Ramina (Author) ; Mohtasham Dolatshahi, Kiarash (Supervisor)
    Abstract
    This paper presents a new approach for developing multivariable fragility curves, which examines the effects of the variation of multiple design parameters on the probability of reaching different damage states. The database of this study comprises the results of 260 RC columns tested under the quasi-static cyclic loading. The push of the cyclic plots, technically named the backbone curve, is also extracted for the entire database by the authors. Accordingly, the RC columns are classified into four levels of damage based on the resisting lateral force observed throughout cyclic loading, derived from the backbone of the hysteresis curves. Considering the drift ratio as the primary variable... 

    Numerical Evaluation for Optimal Design of Number and Positions of Controllers In 2d Frames under Earthquake and Wind Loadings Using Different Active Control Algorithms

    , M.Sc. Thesis Sharif University of Technology Mehdipour Picha, Zabihollah (Author) ; Bakhshi, Amin (Supervisor)
    Abstract
    Structures which are designed in accordance with previously used design codes are usually weak to sustain dynamic loading and therefore they shall be rehabilitated. One approach for rehabilitation is to use active control. In this study, active tendon is used as a structural device control. Various arrangements of controllers can be used to limit the response of the structure but it is desired to find an arrangement at which the cost of the placement will be minimized. The aim of this thesis is to find the best placement of active tendons on a frame such that the placement satisfies two general restrictions; namely structural response and control forces. Genetic algorithm is applied to the... 

    Simulation of Charge Carrier Dynamics at Interface of Two Semiconductors in Photoelectrochemical Cell Using Nonadiabatic Molecular Dynamics Approach

    , Ph.D. Dissertation Sharif University of Technology Mehdipour, Hamid (Author) ; Moshfegh, Alireza (Supervisor) ; Taeifeh Rezakhani, Ali (Supervisor)
    Abstract
    Nowadays, the population growth and industrial development have caused pollution of air, water, and soil, which this turned into in a global challenge. Thus, replacing the running-out fossil fuels with renewable sources of energy is an important issue facing research and scientific communities. One of the methods to generate clean energy is hydrogen production through water splitting reaction inside photoelectrochemical cells using an appropriate semiconductor. Upon the light illumination, rates of charge transfer and recombination in semiconductors heterostructure (as photoanodes) are determining factors for efficiency of these cells. If electron transfer occurs faster (in a shorter time... 

    Shedding light on pseudocapacitive active edges of single-layer graphene nanoribbons as high-capacitance supercapacitors

    , Article ACS Applied Energy Materials ; Volume 2, Issue 5 , 2019 , Pages 3665-3675 ; 25740962 (ISSN) Qorbani, M ; Esfandiar, A ; Mehdipour, H ; Chaigneau, M ; Irajizad, A ; Moshfegh, A. Z ; Sharif University of Technology
    American Chemical Society  2019
    Abstract
    In the field of energy storage by high-rate supercapacitors, there has been an upper limit for the total interfacial capacitance of carbon-based materials. This upper limit originates from both quantum and electric double-layer capacitances. Surpassing this limit has been the focus of intense research in this field. Here, we precisely investigate the effect of chemical functional groups and physical confinement on the electrochemical performance of graphene nanoribbons. We present the results of a quasi-one-dimensional single-layer graphene nanoribbon (120 nm in width and -100 μm in length) microelectrode fabricated by mechanical exfoliation of graphite, followed by electron beam lithography... 

    Degradation of Dye in Wastewater Using iron Based Porous Nanocatalyst in a Batch Reactor

    , M.Sc. Thesis Sharif University of Technology Mehdipour, Mohammad Hossein (Author) ; Ghotbi, Cyrus (Supervisor) ; Mahmoudi, Niaz Mohammad (Supervisor)
    Abstract
    consumption of which (especially azo dyes) have been increasing nowadays, causing the increase of textile wastewaters. Usually, these wastewaters contain an immense number of dyes, and if these dyes release in the environment especially in waters, they cause some problems, such as the change of watercolor as well as taste, and affect creatures' lives severely. Moreover, If the dyes are left untreated in aquatic ecosystems, they can remain in the environment for a very long time, resulting in harmful and irreversible effects. Azo dyes are classified as mono, di-, three, azo dyes due to their bonds. Because dyes are increasingly used, nowadays, different methods are developed for the treatment... 

    Temporary skin grafts based on hybrid graphene oxide-natural biopolymer nanofibers as effective wound healing substitutes: pre-clinical and pathological studies in animal models

    , Article Journal of Materials Science: Materials in Medicine ; Volume 28, Issue 5 , 2017 , 73 ; 09574530 (ISSN) Mahmoudi, N ; Eslahi, N ; Mehdipour, A ; Mohammadi, M ; Akbari, M ; Samadikuchaksaraei, A ; Simchi, A ; Sharif University of Technology
    Springer New York LLC  2017
    Abstract
    Abstract: In recent years, temporary skin grafts (TSG) based on natural biopolymers modified with carbon nanostructures have received considerable attention for wound healing. Developments are required to improve physico-mechanical properties of these materials to match to natural skins. Additionally, in-deep pre-clinical examinations are necessary to ensure biological performance and toxicity effect in vivo. In the present work, we show superior acute-wound healing effect of graphene oxide nanosheets embedded in ultrafine biopolymer fibers (60 nm) on adult male rats. Nano-fibrous chitosan-based skin grafts crosslinked by Genepin with physico-mechanical properties close to natural skins were... 

    Tuning composition of electrospun ZnO/CuO nanofibers: toward controllable and efficient solar photocatalytic degradation of organic pollutants

    , Article Journal of Physical Chemistry C ; Volume 121, Issue 6 , 2017 , Pages 3327-3338 ; 19327447 (ISSN) Naseri, A ; Samadi, M ; Mahmoodi, N. M ; Pourjavadi, A ; Mehdipour, H ; Moshfegh, A. Z ; Sharif University of Technology
    American Chemical Society  2017
    Abstract
    ZnO/CuO nanofibers, with different CuO concentrations, were fabricated by one-step electrospinning of the polymer precursor and annealing in air. Scanning electron microscopy (SEM) showed smooth and beadless morphology for the synthesized nanofibers, while X-ray diffraction (XRD) analysis revealed formation of hexagonal and monoclinic crystalline structure phases for ZnO and CuO nanofibers, respectively. X-ray photoelectron spectroscopy (XPS) analysis confirmed the presence of CuO on the surface of ZnO nanofibers. For further confirming the formation of chemical bonds, Fourier transform infrared (FT-IR) spectroscopy was employed. The effect of Cu contents in the overall electronic band... 

    Experimental Investigation of Effective Parameters on Lead Ion Removal by Nanofiltration

    , M.Sc. Thesis Sharif University of Technology Mehdipour Zareh, Saber (Author) ; Kariminia, Hamidreza (Supervisor) ; Vatanpoor, Vahid ($item.subfieldsMap.e)
    Abstract
    In this study, the effects of parameters such as operation pressure, concentration of Pb2+ ion, nature of associated anion, pH of initial feed and composition of feed was investigated by commercial polyamide nanofilter membrane. One-salt solution nanofiltration experiments was performed by using Pb(NO3)2, PbCl2 and PbSO4 and the binary-salt solution experiments was conducted by using Cu(NO3)2, Cd(NO3)2, Zn(NO3)2, NaNO3 and NH4NO3 together with Pb(NO3)2. The binary-salt experiments in presence of monovalent and divalent cations (together with Pb2+) were performed successively. At first the surface charge of membrane in contact with 1mM KCl solution at pH range of 3-7 was measured. The pH of... 

    Optimizing Transmisson from Distant Wind Farms

    , M.Sc. Thesis Sharif University of Technology Abdollahi Mansourkhani, Hamid Reza (Author) ; Hosseini, Hamid (Supervisor)
    Abstract
    Wind power is site dependent and is by nature partially dispatchable. Furthermore, good wind sites are far from grid. Due to these problems, and along with the existing limitations in the transmission networks, a comprehensive analysis over an extended time is needed to properly explore all potential wind sites for wind capacity allocation. This problem is computationally expensive and decomposition methods are required to break down this problem. Here Benders decomposition approach is used, which is a popular technique for solving large-scale problems, to decompose the original problem into a master and a subproblem. The master problem is a linear problem, which allocates wind capacity to... 

    Identification of the Set of Single Nucleotide Variants in Genome Responsible for the Differentiation of Expression of Genes

    , M.Sc. Thesis Sharif University of Technology Khatami, Mahshid (Author) ; Rabiee, Hamid Reza (Supervisor) ; Beigi, Hamid (Supervisor)
    Abstract
    Single nucleotide polymorphs, There are changes caused by a mutation in a nucleotide in the Dena sequence. Mononucleotide polymorphisms are the most common type of genetic variation. Some of these changes have little or no effect on cells, while others cause significant changes in the expression of cell genes that can lead to disease or resistance to certain diseases. Because of the importance of these changes and their effect on cell function, the relationships between these changes are also important. Over the past decade, thousands of single disease-related mononucleotide polymorphisms have been identified in genome-related studies. Studies in this field have shown that the expression of... 

    Synthesis & Characterization of Au-HKUST-1 Nanocomposite and Evaluation of Plasmonic Properties of Gold Nanoparticles in this Nanocomposite

    , M.Sc. Thesis Sharif University of Technology Moazzeni, Hamid Reza (Author) ; Madaah Hosseini, Hamid Reza (Supervisor)
    Abstract
    In the past few years, many research works on the controllable integration of metal nanoparticles and metal-organic frameworks were done, since the obtained composite material shows a synergism effect in catalysis and photocatalysis, drug delivery applications, gas, and energy storage, as well as sensing. For the first time, in this study, we employed template-assisted growth to synthesize Au-HKUST-1 Nanocomposite. XRD analysis entirely confirms that employing this strategy in synthesizing Au-HKUST-1 was wholly successful, and the plasmonic properties of this nanostructure were studied via UV-visible spectroscopy. In the course of synthesis, gold nanoparticles with 70nm diameter were... 

    Intrinsically Ru-doped suboxide TiO2nanotubes for enhanced photoelectrocatalytic H2generation

    , Article Journal of Physical Chemistry C ; Volume 125, Issue 11 , 2021 , Pages 6116-6127 ; 19327447 (ISSN) Khorashadizade, E ; Mohajernia, S ; Hejazi, S ; Mehdipour, H ; Naseri, N ; Moradlou, O ; Moshfegh, A. Z ; Schmuki, P ; Sharif University of Technology
    American Chemical Society  2021
    Abstract
    In the present research, we investigate the synergistic effects of Ru-doping and Ar/H2 reduction treatment on the photoelectrochemical water splitting performance and hydrogen evolution rate of TiO2 nanotube array photoelectrodes. The Ti-Ru alloy with 0.2 at. % Ru was used to grow anodic self-organized Ru-doped TiO2 nanotube layers. An ideal synergy between Ar/H2 reduction treatment and Ru-doping results in the extended absorption toward the visible light region and improved photoelectrocatalytic activity. The black Ru-doped TiO2-x photoanode's water splitting rate improves remarkably (∼ninefold) compared to the black TiO2-x sample (∼twofold). Moreover, the black Ru-doped TiO2-x photoanode...