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mehdipour-zareh--saber
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Experimental Investigation of Effective Parameters on Lead Ion Removal by Nanofiltration
,
M.Sc. Thesis
Sharif University of Technology
;
Kariminia, Hamidreza
(Supervisor)
;
Vatanpoor, Vahid
($item.subfieldsMap.e)
Abstract
In this study, the effects of parameters such as operation pressure, concentration of Pb2+ ion, nature of associated anion, pH of initial feed and composition of feed was investigated by commercial polyamide nanofilter membrane. One-salt solution nanofiltration experiments was performed by using Pb(NO3)2, PbCl2 and PbSO4 and the binary-salt solution experiments was conducted by using Cu(NO3)2, Cd(NO3)2, Zn(NO3)2, NaNO3 and NH4NO3 together with Pb(NO3)2. The binary-salt experiments in presence of monovalent and divalent cations (together with Pb2+) were performed successively. At first the surface charge of membrane in contact with 1mM KCl solution at pH range of 3-7 was measured. The pH of...
Single-hydrogen dissociation paths for upright and flat acetophenone adsorbates on the Si(001) surface
, Article Journal of Physical Chemistry C ; Volume 118, Issue 41 , 16 October , 2014 , Pages 23682-23689 ; ISSN: 19327447 ; Sharif University of Technology
2014
Abstract
Using cluster-based density functional theory we investigate adsorption configurations of an acetophenone molecule on a Si(001) surface and their follow-up proton transfer processes. We examine two possible types of dative-adsorption configurations, up-right standing and flat, as well as compute their follow-up kinetically preferable on-dimer, interdimer, and inter-row proton transfers. Energetics of possible conversions between the achieved adsorption configurations are computed as well. Using all the data obtained, we theoretically illustrate reaction pathways leading to detached hydrogen positions captured in STM imaging of a Si(001) surface exposed to acetophenone vapor at room...
A study of the electrophoretic deposition of bioactive glass-chitosan composite coating
, Article Ceramics International ; Volume 38, Issue 1 , January , 2012 , Pages 471-476 ; 02728842 (ISSN) ; Afshar, A ; Sharif University of Technology
2012
Abstract
Bioactive glass is coated on implant's surface to improve corrosion resistance and osseointegration, when placed in the body. Bioactive glass particles were synthesized through a sol-gel process and deposited along with chitosan to form a composite coating on a stainless steel substrate using electrophoretic deposition technique. Stable suspensions of chitosan-bioactive glass were prepared using bioactive glass particles (<1 μm) and 0.5 g/l chitosan solution. The influence of ethanol-water ratio on deposition yield was investigated. For all process conditions, best results were achieved with suspension of 30 vol% water in ethanol-water containing 2 g/l bioactive glass. FTIR studies showed...
Chitosan–Bioactive Glass Composite Coating on Nd-Fe-B Magnetic Alloy Substrate by Electrophoretic Deposition
, M.Sc. Thesis Sharif University of Technology ; Afshar, Abdollah (Supervisor)
Abstract
This research work deals with application of poly-saccharide to improve coating process of bioactive ceramic composite on aNd-Fe-B magnetic alloy substrate. Bioactive glass particles were synthesized through a sol-gel process and coated in the form of composite with poly-saccharide onto a magnetic substrate by electrophoretic deposition technique. Stable suspensions of 0.5 gr/lit polysaccharide polymer-ceramic were prepared using bioactive glass particles (<1µm), acetic acid 1%. The influence of added water to ethanol, pH and tri-ethanol-amine (TEA) additive on suspension stability, deposition rate and coating’s structure was investigated. It was shown that by increasing the water to ethanol...
Development of Procedures, Forms and Tools for Post-Earthquake Reconnaissance
, M.Sc. Thesis Sharif University of Technology ; Mahsuli, Mojtaba (Supervisor)
Abstract
This study aims to design and develop procedures, forms, and tools for post-earthquake reconnaissance. The current procedure for data collection is based on the sending of groups to identify the dimensions of the evidence and its consequences by the executive and responsible institutions. Studying and reviewing the reports that have been produced by this method shows that there is not any systematic mechanism for collecting data on a wide scale and from all aspects of the evidence. The limited data collected by the executive and responsible institutions are scattered in the reports and are less documented in the database. Therefore, it is necessary to collect big data on the severity and...
Electrophoretic deposition of bioactive glass coating on 316L stainless steel and electrochemical behavior study
, Article Applied Surface Science ; Volume 258, Issue 24 , 2012 , Pages 9832-9839 ; 01694332 (ISSN) ; Afshar, A ; Mohebali, M ; Sharif University of Technology
Elsevier
2012
Abstract
In this research, submicron bioactive glass (BG) particles were synthesized by a sol-gel process and were then coated on a 316L stainless steel substrate using an electrophoretic deposition (EPD) technique. Stable suspension of bioactive glass powders in ethanol solvent was prepared by addition of triethanol amine (TEA), which increased zeta potential from 16.5 ± 1.6 to 20.3 ± 1.4 (mv). Thickness, structure and electrochemical behavior of the coating were characterized. SEM studies showed that increasing EPD voltage leads to a coating with more agglomerated particles, augmented porosity and micro cracks. The results of Fourier transformed infrared (FTIR) spectroscopy revealed the adsorption...
Urchin-like hierarchical ruthenium cobalt oxide nanosheets on Ti3C2T: XMXene as a binder-free bifunctional electrode for overall water splitting and supercapacitors
, Article Nanoscale ; Volume 14, Issue 4 , 2022 , Pages 1347-1362 ; 20403364 (ISSN) ; Esfandiar, A ; Mehdipour, H ; Sharif University of Technology
Royal Society of Chemistry
2022
Abstract
Synthesizing efficient electrode materials for water splitting and supercapacitors is essential for developing clean electrochemical energy conversion/storage devices. In the present work, we report the construction of a ruthenium cobalt oxide (RuCo2O4)/Ti3C2Tx MXene hybrid by electrophoretic deposition of Ti3C2Tx MXene on nickel foam (NF) followed by RuCo2O4 nanostructure growth through an electrodeposition process. Owing to the strong interactions between RuCo2O4 and Ti3C2Tx sheets, which are verified by density functional theory (DFT)-based simulations, RuCo2O4/Ti3C2Tx MXene@NF can serve as a bifunctional electrode for both water splitting and supercapacitor applications. This electrode...
An experimental investigation of the effect of fracture dip angle on oil recovery and drainage rate in free fall gravity drainage in fractured reservoirs using a glass micromodel (A pore level investigation)
, Article Petroleum Science and Technology ; Volume 31, Issue 4 , 2013 , Pages 355-367 ; 10916466 (ISSN) ; Kharrat, R ; Ghazanfari, M ; Sharif University of Technology
2013
Abstract
Gravity drainage is the main production mechanism in the gas invaded zone in naturally fractured reservoirs. However, there are large ambiguities and complexities, resulting from the dynamic of oil depletion from matrix blocks toward the fracture network. Visualization of drained oil at pore scale using glass micromodels provides the opportunity to better understand the effects of different parameters which might affect oil recovery from fractured reservoirs. In this work a micromodel apparatus generated by laser etching is used to perform some gravity drainage tests on the network patterns. The experiments were performed on double block systems using crude oil. The block to block...
Kinematic and Dynamic Analysis and Workspace Optimization of a 3DoF Cable-Based Parallel Robot
, M.Sc. Thesis Sharif University of Technology ; Zohoor, Hassan (Supervisor)
Abstract
Cable-driven robots are referred to as parallel robots actuated with cables. In fact,in such robots rigid links are replaced by cables, which may be extended to desired lengths without making mechanism much heavy. This robot possesses a number of unique properties that makes it suitable for many industrial applications. The main factor which makes cable robots analysis different from other parallel robots is the incapability of cables to push objects. Hence, obtaining the workspace of a cable robot is one of the most important subjects associated with this type of robot.The goal of this thesis is to design a spatial translational cable driven robot, which may be used for object handling. For...
Workspace analysis of a cable-suspended robot with active/passive cables
, Article Proceedings of the ASME Design Engineering Technical Conference ; Volume 6 A , August , 2013 ; 9780791855935 (ISBN) ; Zohoor, H ; Sharif University of Technology
American Society of Mechanical Engineers
2013
Abstract
Cable-driven parallel robots have several outstanding characteristics that make them unique in many robotic applications. Since cables can only pull, one of the most important issues associated with these robots is obtaining their workspace. In this paper a spatial translational cable-driven robot with active/passive cables is considered and its workspace is investigated from several points of views. First the moment resisting capability of the robot is discussed and the effects of some robot's parameters on the workspace are studied. Then, both force-feasibility and moment-resisting capability of the robot are considered to find the region where the end-effector may exert the required...
Planning of Energy Storage Systems with the Main Goal of Managing the Output Power of Wind Farms
, M.Sc. Thesis Sharif University of Technology ; Ehsan , Mehdi (Supervisor)
Abstract
Uncertain fuel prices and also global climate changes are accompanied by some state initiatives such as renewable portfolio standards (RPS). This has caused a fast growth in the amount of renewable energy installed worldwide especially wind energy over last decades. However, the intrinsic characteristics of wind farms output power, i.e. intermittency and volatility of wind speed along with being non-dispatchable in output generation of wind turbine raises many new technical and financial challenges for power system operators and planners. Up to these issues, large level of wind power penetration causes a growing concern in wind energy curtailment issue which the wind farm’s operator may be...
Influence of ion interaction on lead removal by a polyamide nanofiltration membrane
, Article Desalination ; Volume 362 , April , 2015 , Pages 84-92 ; 00119164 (ISSN) ; Vatanpour, V ; Kariminia, H. R ; Sharif University of Technology
Elsevier
2015
Abstract
Retention of lead(II) ions on a polyamide nanofiltration membrane was investigated. Effects of different factors including operating pressure, lead ion concentration, anion nature, pH and composition of feed on the lead ion rejection were studied. The solutions used consisted of Pb(NO3)2, PbCl2 and PbSO4 in the single-salt solution system and Pb(NO3)2, Cu(NO3)2, Zn(NO3)2, Cd(NO3)2, NaNO3 and NH4NO3 in the binary-salt solution system. The influence of divalent and monovalent cations including cadmium, copper, zinc, sodium and ammonium on the rejection of lead ion was examined. The transmembrane pressure and lead ion concentration varied between 10 and 40bar and 20 and 400mg Pb2+/L,...
Three Phase Modeling of Fluid Flow in the Well Tubing to predict Asphaltene Deposition
, M.Sc. Thesis Sharif University of Technology ; Ayatollahi, Shahaboddin (Supervisor)
Abstract
In this thesis, by focusing on the hydraulics of three phase flow in vertical tubing to investigate asphaltene deposition problem, the solid particles behaviors in a turbulent flow is fully studied. Reasonable size distribution for particles (based on previous works and researches) was assumed and a model for 2 sections of a Marrat oil field well to evaluate their asphaltene deposition problem was developed. Three phase liquid-gas-solid flow in the well tubing was simulated. Asphaltene deposition profile on the well tubing, mean and maximum of the deposition rate and particle concentrations in the flow regime were calculated and compared with real field data. Better agreement with field data...
Innovations in non-linear oscillations of a pendent drop from a capillary tip during formation and detachment - an LBM simulation
, Article Journal of Applied Fluid Mechanics ; Volume 14, Issue 1 , 2020 , Pages 331-344 ; Taeibi Rahni, M ; Zareh, M ; Sharif University of Technology
Isfahan University of Technology
2020
Abstract
Individual drops are suitable tools to study the liquid-fluid interfacial properties. In this work, force-displacement equation and non-linear oscillations of a pendent drop are numerically investigated. The presented novel force-displacement function allows following the dynamics of a pendent drop and realizing its elastic behavior. The growth and detachment of drop, which is pending due to gravity from a capillary tip, is considered (assuming high density and high viscosity ratios and immiscible two-phase flows). Two-dimensional multi-relaxation time lattice Boltzmann method (MRT-LBM) was used to simulate growth, detachment, and oscillations of the drop using a conservative model for...
Strengthening RC Slabs under Various Loads and Boundary Conditions Using FRP Composites
, M.Sc. Thesis Sharif University of Technology ; Khaloo, Ali Reza (Supervisor)
Abstract
In recent decades the use of FRP materials for strengthening structures has been developed extensively, thanks to their high strength, sufficient stiffness, high durablity, and ease of use. A great deal of research has been conducted on strengthening reinforced concrete beams and columns with FRP composites. By contrast, not many researches are performed on slabs, especially two-way slabs. In these few researches, the loading and boundary conditions are limited to simplest ones. Therefore, in this thesis, the focus of attention is on strengthening reinforced concrete slabs under various loads and boundary conditions using FRP composites.
In this thesis, first, FRP composites and their...
In this thesis, first, FRP composites and their...
Numerical Evaluation for Optimal Design of Number and Positions of Controllers In 2d Frames under Earthquake and Wind Loadings Using Different Active Control Algorithms
, M.Sc. Thesis Sharif University of Technology ; Bakhshi, Amin (Supervisor)
Abstract
Structures which are designed in accordance with previously used design codes are usually weak to sustain dynamic loading and therefore they shall be rehabilitated. One approach for rehabilitation is to use active control. In this study, active tendon is used as a structural device control. Various arrangements of controllers can be used to limit the response of the structure but it is desired to find an arrangement at which the cost of the placement will be minimized. The aim of this thesis is to find the best placement of active tendons on a frame such that the placement satisfies two general restrictions; namely structural response and control forces. Genetic algorithm is applied to the...
The design of PIP controller for a thermal system with large time delay
, Article World Academy of Science, Engineering and Technology ; Volume 32 , 2009 , Pages 890-894 ; 2010376X (ISSN) ; Sarrafan, A ; Ghaemi Osgouie, K ; Sharif University of Technology
2009
Abstract
This paper will first describe predictor controllers when the proportional-integral-derivative (PID) controllers are inactive for procedures that have large delay time (LDT) in transfer stage. Therefore in those states, the predictor controllers are better than the PID controllers, then compares three types of predictor controllers. The value of these controller's parameters are obtained by trial and error method, so here an effort has been made to obtain these parameters by Ziegler-Nichols method. Eventually in this paper Ziegler-Nichols method has been described and finally, a PIP controller has been designed for a thermal system, which circulates hot air to keep the temperature of a...
Data Sharing Aware Scheduling for Reducing Memory Accesses in GPGPUs
, M.Sc. Thesis Sharif University of Technology ; Hesabi, Shahin (Supervisor)
Abstract
Access to global memory is one of the bottlenecks in performance and energy in GPUs. Graphical processors uses multi-thread in streaming multiprocessors to reduce memory access latency. However, due to the high number of concurrent memory requests, the memory bandwidth of low level memorties and the interconnection network are quickly saturated. Recent research suggests that adjacent thread blocks share a significant amount of data blocks. If the adjacent thread blocks are assigned to specific streaming multiprocessor, shared data block can be rused by these thread blocks. However the thread block scheduler assigns adjacent thread blocks to different streaming multiprocessors that increase...
Combinatorial Optimization with Reinforcement Learning
, M.Sc. Thesis Sharif University of Technology ; Saleh Kaleybar, Saber (Supervisor)
Abstract
One of the key subjects in the area of mathematical optimization is a class of problems known as combinatorial optimization. We can find the optimal solution of continuous optimization problems feasible in time. But, in combinatorial optimization, we aim to obtain the optimal solution of the problem over a finite set. These problems are NP-hard and no polynomial-time solution has been proposed for this class of problems so far. Thus, in practical scenarios, we often use heuristic methods for solving NP-hard problems. There are lots of heuristic methods and choosing the best one in different situations might be challenging. In recent years, with the advances in deep neural networks,...
Semi Active Vibration Control of an Eleven Degree of Freedom Passenger Car Using Magnetorheological Shock Absorbers
, M.Sc. Thesis Sharif University of Technology ; Khayyat, Amir Ali Akbar (Supervisor)
Abstract
This thesis is presented to introduce a semi-active control of the suspension systems. The currently available semi-active damper technologies can be divided into two main groups. The first uses controllable electromagnetic valves and the second uses Magnetorheological (MR) fluid to control the damping characteristics of the system. A mass-spring model with eleven degrees of freedom, considering constant velocity for the car, is developed to model the suspension system. A semi-active vibration control system is presented to reduce the amplitude of automotive vibrations caused by the alteration of the road profile. The gravel road profile with Gaussian white noise as the road irregularity...