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Modification of carbohydrate polymers via grafting in air. 1. Ceric-Induced synthesis of starch-g-polyacrylonitrile in presence and absence of oxygen [electronic resource]
, Article Starch - Starke ; Volume 54, Issue 3-4, pages 140–147, April 2002 ; Zohurian Mehr, Mohammad J
Abstract
Monomer grafting, a unique technique for polysaccharide modification, is always performed under inert (e.g., N2) atmosphere. This work is the first report related to evaluating the possibility and efficiency of the grafting of acrylonitrile (AN) onto starch in presence of oxygen. Thus, corn starch (in both granular and gelatinized states) as well as soluble starch were grafted by AN using a ceric-carbohydrate redox initiating system. Graft copolymerizations were performed under nitrogen, air, and oxygen atmospheres at similar conditions. Grafting occurrence was verified using chemical and spectral proofs. The polymerization mechanism and kinetics were investigated by recording the...
Modification of carbohydrate polymers via grafting in Air. 2. Ceric-Initiated graft copolymerization of acrylonitrile onto natural and modified polysaccharides [electronic resource]
, Article Starch - Stärke ; Volume 54, Issue 10, pages 482–488, October 2002 ; Zohuriaan-Mehr, Mohammad J
Abstract
Acrylonitrile (AN) was grafted onto various natural and modified polysaccharides (i.e., gum arabic, gum tragacanth, xanthan gum, sodium alginate, chitosan, sodium carboxymethyl cellulose, hydroxyethyl cellulose, methyl cellulose) by using ceric-carbohydrate redox initiating system. After overcoming practical problems, mainly from the high viscosity of the aqueous solutions of the different substrates, the graft copolymerization reactions were run either in air or in N2 atmosphere under similar conditions. Grafting was confirmed using chemical and spectral (FTIR) proofs. The reactions were kinetically investigated using semi-empirical expressions and time-temperature profiles. An anomalous...
Temporal Congestion Games
, M.Sc. Thesis Sharif University of Technology ; Ghodsi, Mohammad (Supervisor)
Abstract
We consider a special class of Congestion Games enhanced with a notion of time.Network Routing problems, such as road traffic networks, computer neworks, and evacuation problems are some applications of this class of games. Two subclasses of these games, namely atomic and non-atomic is considered in this article, both of them introduced in 2009. Some of the existing results are Nash equilibria existence proof for “single-source single-sink” case, and a mechanism for improving price of anarchy in the non-atomic subclass. There are also some results in the atomic subclass of this game.We extend both models of atomic and non-atomic subclasses to “multi-source,multi-sink” configurations. We call...
Modified CMC: part 1- optimized synthesis of carboxymethylcellulose-g-polyacrylonitrile [electronic resource]
, Article Iranian Polymer Journal ; Vol. 14, No 2, 131-138, 2005 ; Pourjavadi, A ; Sadeghi, M
Abstract
As the first part of a continued research on conversion of carboxymethyl cellulosesodium salt (CMC) to useful biopolymer-based materials, large numbers of cyanide functional groups were introduced onto CMC by grafting with polyacrylonitrile (PAN). The graft copolymerization reactions were carried out under nitrogen atmosphere using ceric ammonium nitrate (CAN) as an initiator. Evidence of grafting was obtained by comparing FTIR spectra of CMC and the graft copolymer as well as solubility characteristics of the products. The synthetic conditions were systematically optimized through studying the effective factors including temperature and concentrations of initiator, acrylonitrile monomer,...
New polysaccharide-g-polyacrylonitrile copolymers: synthesis and thermal characterization [electronic resource]
, Article Polymers for Advanced Technologies ; Volume 14, Issue 7, pages 508–516, July 2003 ; Pourjavadi, Ali ; Sharif University of Technology
Abstract
Various natural and modified polysaccharides (i.e. arabic gum, tragacanth gum, xanthan gum, sodium alginate, chitosan, sodium carboxymethyl cellulose, hydroxyethyl cellulose, methyl cellulose) were modified using ceric-initiated graft polymerization of acrylonitrile under inert atmosphere. Grafting was confirmed using spectral (FT-IR) proofs. The grafting parameters were determined by conventional methods. Thermal characteristics of the homopolymer-free copolymers were studied using differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA) under nitrogen atmosphere. The major thermal transitions as well as the activation energy of the major decomposition stages were...
Modified Chitosan. 2. H-chitoPAN, a novel pH-responsive superabsorbent hydrogel [electronic resource]
, Article Journal of Applied Polymer Science ; Volume 90, Issue 11, pages 3115–3121, 9 December 2003 ; Mahdavinia, G. R ; Zohuriaan-Mehr, M. J
Abstract
Chitosan was modified with polyacrylonitrile (PAN) through ceric-initiated graft copolymerization. The chitosan-g-PAN product was saponified using sodium hydroxide aqueous solution to prepare a novel superabsorbent hydrogel, H-chitoPAN. Duration of completing the saponification reaction as well as the water absorbency capacity of the hydrogel was decreased with increasing the alkaline concentration. Either chitosan-g-PAN or H-chitoPAN was characterized by FTIR spectroscopy and DSC, TGA, and DTG thermal methods. According to FTIR, all the nitrile groups were converted to carboxylate and carboxamide groups. Both modified chitosans exhibited enhanced thermal stability over chitosan. The...
The effects of annular electromagnetic stirring parameters on microstructure evolution of rheocast AZ91 magnesium alloy
, Article Journal of Materials Research and Technology ; Volume 8, Issue 2 , 2019 , Pages 2300-2308 ; 22387854 (ISSN) ; Aashuri, H ; Sharif University of Technology
Elsevier Editora Ltda
2019
Abstract
In the present study, an annular electromagnetic stirrer was used to fabricate the semi-solid slurry of AZ91 magnesium alloy under various conditions of electromagnetic intensities and times. The fabricated semi-solid slurry was injected into a step-die cavity, using a hydraulic jack with ram speed of 1 m/s. The effects of electromagnetic intensity, stirring time and step thicknesses on the microstructure evolution, shape factor, globules equivalent diameter, solid fraction and microhardness of samples were investigated. The experimental results showed that obtained optimal parameters of electromagnetic stirring were 55 (A) stirring current and 30 (s) stirring time. In this conditions, the...
Modeling Propagation of Cardiac Action Potential at Cellular Level
, M.Sc. Thesis Sharif University of Technology ; Jahed, Mehran (Supervisor)
Abstract
Heartbeat is the result of contractions of over 10 billion cardiac cells. These cells’ cytoplasms are connected to each other by gap junctions which are arrays of intercellular protein channels. Thus action potential can propagate from one cell to another and cause its contraction. In core-conductor model, one-dimensional microscopic representation of cardiac tissue, cells are attached to each other to form a ladder network. The parallel elements are connected to each other by series resistors which represent gap junctions. These resistors are nearly always considered as static elements. In this thesis I have investigated the effects of incorporating the dynamicity of gap junction resistors...
Distributed Cardiovascular System Modeling
, M.Sc. Thesis Sharif University of Technology ; Jahed, Mehran (Supervisor)
Abstract
Simulation of cardiovascular system functionality during various physiological conditions is essential at different diagnostic and clinical levels. A first step in studying the roots of cardiovascular diseases and abnormal activity is to study a practical yet complete model of the cardiovascular system. In this thesis we introduced a new approach for defining the distributed model of the cardiovascular system. Initially, we chose an appropriate subsystem, namely Arch of Aorta, and proposed a distributed model for it. The elements of the proposed model were nonlinear RLC elements that simulate resistance, blood viscosity and vessel elasticity respectively. To minimize the system complexity,...
Risk Breakdown Structure (RBS) Identification and Designing for projects
, M.Sc. Thesis Sharif University of Technology ; Sepehri, Mehran (Supervisor)
Abstract
To actualize and making the outputs of a project effectual, it is necessary to conduct an effective management during a project. This case may not be possible without accurately planning for activities, management and controlling all phases of a project ignoring the risk management of that project. If risks of a project cannot be detected before conducting a project, it is possible to challenge the performance and even effectiveness of the project. In current conditions, the most important problem of managers and executives of construction projects through the country is risk management of projects, not acknowledging with definitions of risk, models of risk management and lack of a model for...
Introducing a suitable Controller for Rowing Activity in Patients with Spinal CordInjuries using FES
, M.Sc. Thesis Sharif University of Technology ; Jahed, Mehran (Supervisor)
Abstract
Disconnections in neural paths from the central nervous system to the muscles or vice versa cause different neuropathies, thus paralysis in different limbs may occur. As a result of the lack of muscular activity and the decrease in blood perfusion in paralyzed limbs, problems like osteoporosis, increase in the risk of breaking, decline in muscle size, cardiovascular diseases, renal dysfunction, bedsores, etc may happen. In order to induce movement in paralyzed limbs, thus preventingmentioned problems, rowing exercise through Functional Electrical Stimulation (FES) may be utilized. In FES, electrical Stimulation using current stimulating pulses is applied to contracting and relaxing muscles,...
Performance Management of HSE Management System based on BSC Framework-the Case Study of Mapna Corporation
, M.Sc. Thesis Sharif University of Technology ; Sepehri, Mehran (Supervisor)
Abstract
A Balanced Scorecard (BSC) model is proposed to evaluate performance of Health, Safety and Environment (HSE) management systems. This model includes key performance indicators at three integrated levels. It has been tested and verified in a project-based organization in Iran, active in the area of power and energy. Results show that the company has done well in implementing HSE management processes, but no so well in growth and learning. This model may be used as a basis for comparing different companies and various proposed programs in the field of HSE management systems. The model includes indicators and sub-indicators in each category particularly related to stakeholders, processes, and...
Functional Modeling of Normal and CHF Heart and Control of Total Artificial Heart- An Optimizing Approach
, Ph.D. Dissertation Sharif University of Technology ; Jahed, Mehran (Supervisor)
Abstract
World-wide, Congestive Heart Failure (CHF) takes hundreds of thousands of lives each year. This chronic heart disease causes poor performance of the heart and insufficient blood pumping to the organs. A significant percentage of patients with CHF require heart transplants for their survival. The high cost of heart transplant, shortage of donor hearts and possibility of its rejection by recipients are serious problems of this type of treatment. Therefore a large number of heart patients are potential beneficiaries of artificial blood pumps such as Ventricular Assist Device (VAD) and Total Artificial Heart (TAH). Performance of these systems must be compliant and complementary to the existing...
Identifying Affecting HR Factors on Unsuccessful Reengineering Projects
, M.Sc. Thesis Sharif University of Technology ; Sepehri, Mehran (Supervisor)
Abstract
In this study, factors which lead in failures in reengineering processes in project based companies have been investigated. The research used qualitative methods, and finally using theme analysis to identify the main factors.Consequently, the main causes of failure of re-engineering projects have been identified and classified in six basic categories including: organizational leadership, planning, human resources management, mental models causing resistance, culture and organizational climate and communication. That each of these themes includes some subset of the agents it represents. In this study, a suitable pattern for organizations which intend to perform reengineering has been...
Applying Tandem CONWIP Policy to Assembly Supply Chain
, M.Sc. Thesis Sharif University of Technology ; Sepehri, Mehran (Supervisor)
Abstract
Supply chain management has been developed extensively in second half of last century and the development has been continued up to present century. Nowadays Development and conformity of production and inventory control methods with JIT philosophy in production line level is one of the topics that received much attention from researchers. An increasing interest in the scope of JIT philosophy is on the extension and adaptation of Pull policies such as Kanban and CONWIP for materials and production control. In a real-life environment, companies are subjected to various types of uncertainties such as stochastic processing times and variable demand. This uncertain environment could cause lots...
Joint Segmentation and Motion Estimation of Cardiac Cine MR Image Sequences
, Ph.D. Dissertation Sharif University of Technology ; Jahed, Mehran (Supervisor)
Abstract
In this study a variational framework for joint segmentation and motion estimation is provided for inspecting heart in Cine MRI sequences. In the first work, a functional including Mumford-Shah segmentation and optical flow based dense motion estimation is proposed. However, the motion estimation technique is replaced with warping estimation in the second work to reach in more regular and smooth motion field based on tracking of cardiac boundaries. Both of these functionals are then approximated by using the phase-field method to make them suitable for extracting Euler-Lagrange equations. Numerical solution to the optimization problem, when the time and image spaces are discretized by finite...
Dynamics and Control of Needle Movement in Percutaneous Interaction with Prostate Tissue
, Ph.D. Dissertation Sharif University of Technology ; Jahed, Mehran (Supervisor)
Abstract
In many modern medical procedures, needle insertion is an inevitable part of the diagnosis or treatment protocols. The accuracy of the needle insertion is adversely affected by a number of factors. A needle, frequently assumed to be flexible, is inserted into a soft tissue and induces complex mechanical interactions that may result in considerable uncertainties. Tissue intrinsic characteristics as well as its deformation and rotation may cause dramatic complexities. This work considers the needle movement inside the tissue from the dynamics and control point of view. The proposed approach can be regarded as an initial step towards automation of needle insertion procedures; it can also be...
Needle Steering in Soft Tissue
, M.Sc. Thesis Sharif University of Technology ; Jahed, Mehran (Supervisor)
Abstract
Medical needle interventions are a common technique for accessing tissue structures.In these procedures, needles are used, for example, to extract biopsy samples, brachytherapy, and to insert drugs. In TRUS guided prostate brachytherapy application, Physicians used ulterasound imaging to steer the needle and insert radioactive seeds into cancerous tumors to irradiate surrounding tissue over several months. Prostate rotation, deformation, and unavailability of imaging data during part of the insertion path result in misplaced seeds. To overcome these problems, in this research, we modeled the prostate, its membrane and the surrounding fatty tissue as linearly elastic homogenous material, and...
Considering Lessons Learned and Ascertaining Their Roadmap in Project Management (Case Study: Sepanir Company)
, M.Sc. Thesis Sharif University of Technology ; Sepehri, Mehran (Supervisor)
Abstract
Evolutions in the economy, society and politics has raised knowledge as a key element in the development and competitiveness and knowledge management is considered one of the essential elements in this field. By taking temporary nature of the project into account, dynamics and competition in the project-oriented organizations business world makes the preservation and management of knowledge in project-based organizations more important. Lesson learned system is one of the knowledge management tools that can propose strategic solutions which avoid wasting of time and money and make perfect use of knowledge management accomplishments.In this study, by using literature review, interview and...
Pathology Analysis and Multi-Class Discrimination for Laryngeal Disorders
, M.Sc. Thesis Sharif University of Technology ; Jahed, Mehran (Supervisor)
Abstract
Ability to speak lucidly plays a key role in social relations. Consequently the role of larynx is quite important and timely diagnosis of laryngeal diseases has proved to be crucial. Since conventional diagnostic methods of the larynx are usually expensive or bothersome, the aim of this project is to analyze and classify diseases of the larynx with the aid of signal processing which tend to be faster and easier to implement and quite economical. This study utilizes the vowel sound /a/ and a well referenced database, namely MEEI (Massachusetts Eye and Ear Infirmary) which includes 53 normal and 213 abnormal voices in 7 classified diseases. In this work, using existing signal modeling and...