Sharif Digital Repository

This paper summarizes the possibility of carbon dioxide gas Injection and compares the results with natural depletion in one of Iranian under saturated oil reservoir. At first with using PVTi software and Eclipse simulator, slim tube test has been simulated and Minimum Miscibility Pressure (MMP) of carbon dioxide gas with reservoir fluid determined then simulation of CO2 injection had done and at the end assessment of economic conditions for CO2 injection had been considered. Results had shown CO2 is an optimized choice for gas injection in this oil reservoir  

Interaction between rock-fluid and fluid-fluid can have a significant effect on oil recovery. Changing the wettability of reservoir rock toward more water-wet or less oil-wet state is one of the expected mechanisms during low salinity water injection (LSWI). pH and salinity are of the most eminent factors of injection water controlling the wettability state of a crude oil/brine/rock system during any waterflooding operation. A small change in pH can affect the surface charges at the rock/water and oil/water interfaces leading to wettability alteration in a porous medium. In this study, the synergic effect of salinity and pH on the wettability state of carbonate rocks is evaluated through... 

Calcite is among the most abundant minerals organizing the oil reservoir formation and therefore its surface properties play a central role in the increase of the oil recovery efficiency. The effect of low-salinity water in carbonate rocks reveals that brine composition and salinity can improve the oil recovery in carbonates through wettability alteration. However, the specific mechanism for wettability changes that leads to improved oil recovery in calcite is not well understood. To obtain deeper insights at atomic level into the understanding the characteristics of the calcite-water interface, we performed classical molecular dynamics simulations in the presence of different ions in brine... 

In recent years, controlling the salinity and composition of the injected water has become an emerging enhanced oil recovery (EOR) technique, often described as low salinity (LS) waterflooding. This work is done with the intention to contribute to the ongoing discussions about LS waterflooding mechanism(s). For this purpose, a series of different experiments were conducted. At first, the effect of salinity on the interfacial tension (IFT) and the contact angle was evaluated with a crude oil sample. Then to achieve more accurate results in observing oil/water interface, similar IFT experiments were also carried out on a synthetic oil containing asphaltenes. Thereafter, microscopic... 

Recently, the visibility graph has been introduced as a novel method for analyzing time series, which maps a time series to a complex network. In this paper we introduce a new algorithm of visibility, "cross-visibility", which reveals the conjugation of two coupled time series. The correspondence between the two time series is mapped to a network, "the cross-visibility graph", to demonstrate the correlation between them. We have applied the algorithm to several correlated and uncorrelated time series, generated by the linear stationary ARFIMA process, in order to better understand the results of the cross-visibility of empirical series. The comparison between the degree distribution of... 

In order to understand the potential role of divalent ions involved in smart water, fluid-fluid and rock-fluid interactions are studied through contact angle and interfacial tension (IFT) measurements. Then, the suitable brines in changing contact angle and IFT are brought into measurement with spontaneous imbibition experiments to evaluate the co-impact of fluid-fluid and rock-fluid interactions. The results show the importance of SO42− ions during smart water injection as removing them from the injection water leads to a sharp drop in ultimate oil recovery. Accordingly, when the concentration of SO42− within the injection water increases four times, 10% ultimate oil recovery is recovered.... 

Waterflooding has been regarded as an efficient method for pressure maintenance of oil reservoirs. x Improved techniques such as Smart Water flooding as a new EOR/IOR process has gained more momentum based on the recent research activities in this field and the reduction of oil price. Despite many efforts on achieving the governing mechanisms of Smart Water flooding in many individual fields, most of data are sparse and more possible mechanisms which explains all the interactions yet to be introduced. This experimental study used a systematic laboratory framework which is based on seawater treatments at fixed ionic strength to eliminate the ionic strength effects, NaCl considered as the... 

A highly efficient and simple procedure for the synthesis of quinazolin-4(3H)-ones from the condensation of 2-aminobenzamide with triethylorthoesters in presence of a catalytic amounts of heteropolyacids in various solvents is reported  

Introduction: Research evidence indicates that maladaptive reorganization of the brain plays a critical role in amplifying pain experiences and pain chronification; however, no clear evidence of change exists in brain wave activity among patients with chronic low back pain (CLBP). The objective of this study was to assess brain wave activity in patients with CLBP, compared to healthy controls. Methods: Twenty-five patients with CLBP and twenty-four healthy controls participated in the study. A quantitative electroencephalography device was used to assess brain wave activity in eyes-open and eyes-closed (EO and EC) conditions. The regional absolute and relative power of brain waves were... 

An accurate examination of deformability of rock samples in response to any change in stresses is deeply dependent on the reliable determination of properties of the rock as analysis inputs. Although Young’s modulus (E) can provide valuable characteristics of the rock material deformation, the direct determination of E is considered a time-consuming and complicated analysis. The present study is aimed to introduce a new hybrid intelligent model to predict the E of granitic rock samples. Hence, a series of granitic block samples were collected from the face of a water transfer tunnel excavated in Malaysia and transferred to laboratory to conduct rock index tests for E prediction. Rock index... 

An accurate examination of deformability of rock samples in response to any change in stresses is deeply dependent on the reliable determination of properties of the rock as analysis inputs. Although Young’s modulus (E) can provide valuable characteristics of the rock material deformation, the direct determination of E is considered a time-consuming and complicated analysis. The present study is aimed to introduce a new hybrid intelligent model to predict the E of granitic rock samples. Hence, a series of granitic block samples were collected from the face of a water transfer tunnel excavated in Malaysia and transferred to laboratory to conduct rock index tests for E prediction. Rock index... 

The transfer of pyridinium ion across the water/nitrobenzene interface has been studied by the methods of cyclic voltammetry and ac-impedance measurements. The diffusion coefficients of these species in both media, Dw,pyH+ = 4.4 × 10-5 and DNB,pyH+ = 2.16 × 10-5 cm2 s-1, as well as the diffusion coefficient of pyridine in the organic phase, DNB,py, 3.05 × 10-7 cm2 s-1, have been calculated. The standard potential of pyridinium ion transfer, and the corresponding free energy change and its distribution coefficient between the two phases, have been reported by means of cyclic voltammetry. Impedance measurements resulted in an arc in Nyquist diagrams representing the transfer of pyridinium ion... 

Over recent years, frequent involvements in claims have been inevitable due to unpredictable economic changes and increasing complexities in construction industry. Therefore, even appropriately made contracts are not exempted from claims. On the other hand, construction contract claims are time-consuming, expense-involving and most likely leading to unsatisfactory results. However, there may be some positive outcomes, such as time extension or compensation of damages. To launch investigations, a list of important and frequent claims in oil and gas industry projects of Iran was extracted after a succinct documents review. Further, the most important claim causes were identified through... 

Signed graphs are graphs whose edges get signs ±1 and, as for unsigned graphs, they can be studied by means of graph matrices. Here we focus our attention to the largest eigenvalue, also known as the index of the adjacency matrix of signed graphs. Firstly we give some general results on the index variation when the corresponding signed graph is perturbed. Also, we determine signed graphs achieving the minimal or the maximal index in the class of unbalanced unicyclic graphs of order n≥3. © 2019  

Using a parallel mechanism in the wear test simulators of prosthetic knees provides an easy access to the femoral and tibial components during tests. Moreover, because of its higher accuracy and load capacity, in comparison with serial mechanisms, it allows simulation of heavier tasks, such as climbing stairs, to be performed. This paper describes a new 3 Degree of freedom (DoF) spatial 2T1R (T: Translational DoF; R: Rotational DoF) parallel mechanism, for reproducing the force and motion of the tibial component of the knee prostheses in a wear test simulator. Kinematics and dynamics analysis of the mechanism indicated that it can satisfy the required DoFs, workspace and load capacity... 

Fluxgate magnetometers with different design and core materials have been made. The sensors have been characterized and the frequency responses of the sensors have been measured. The fluxgate magnetometer based on orthogonal design and amorphous wire core working in fundamental mode reaches 30pT/Hz noise level and 40μV/nT sensitivity. Finally an active magnetic shield constructed based on the amorphous core fluxgate magnetometer reaches more than 60dB field attenuation for DC field and has a good response for frequencies below 100Hz  

Nickel-copper alloy modified glassy carbon electrodes (GC/NiCu) prepared by galvanostatic deposition were examined for their redox process and electrocatalytic activities towards the oxidation of methanol and glucose in alkaline solutions. The methods of cyclic voltammetery (CV), chronoamperometry (CA) and impedance spectroscopy (EIS) were employed. The cyclic voltammogram of NiCu alloy demonstrates the formation of β/β crystallographic forms of the nickel oxyhydroxide under prolonged repetitive potential cycling in alkaline solution. In CV studies, in the presence of methanol NiCu alloy modified electrode shows a significantly higher response in oxidation reaction. The peak current of the... 

The electro-oxidation of methanol on nickel and nickel-copper alloy modified glassy carbon electrodes (GC/Ni and GC/NiCu) in a 1 M NaOH solution at different concentrations of methanol was studied by the method of ac-impedance spectroscopy. Two semicircles in the first quadrant of a Nyquist diagram were observed for electro-oxidation of methanol on GC/Ni corresponding to charge transfer resistance and adsorption of intermediates. Electro-oxidation of methanol on GC/NiCu shows negative resistance in impedance plots as signified by semi-circles terminating in the second quadrant. The impedance behavior shows different patterns at different applied anodic potential. The influence of the... 

In the present study, the behavior of fin pile under lateral loading was investigated by ABAQUS software. First, the generated model was verified against an available experimental small-scale test in the literature. Having conducted verification, a study was carried out on the fin pile dimensions under lateral loading. Different parameters, such as pile diameter, fin’s length, and width, were studied. Moreover, a study on the fin’s aspect ratio by setting fin’s area constant was conducted, and then, optimum fin’s ratio was obtained. The results indicated that both fin’s length and width could improve pile efficiency under lateral loading, yet fin’s length had a more critical impact, and...