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Investigation Properties of Polyethylene/ Carbon Nanotube Nanocomposites Prepared Via in Situ Polymerization
, M.Sc. Thesis Sharif University of Technology ; Ramazani Saadatabadi, Ahmad (Supervisor)
Abstract
In this research UHMWPE/MWCNT nanocomposites with different concentrations of nanotubes (0.5, 1.5, 2.5, 3.5 wt %) were prepared via in situ polymerization using a novel Bi-supported Ziegler-Natta catalytic systems. Magnesium etoxide and Multi wall carbon nanotubes functionalized by hydroxyl groups were used as supports of catalyst. TiCl4 accompanied by triethylaluminum constituted Ziegler-Natta catalytic system. Preparation of catalyst and polymerization were done in slurry phase under the argon atmosphere. Support of catalyst on MWCNT was investigated using Fourier Transform Infrared Spectroscopy (FTIR). The results confirmed interaction between catalyst and hydroxyl groups on the surface...
Examination of a solar desalination system equipped with an air bubble column humidifier, evacuated tube collectors and thermosyphon heat pipes
, Article Desalination ; Volume 397 , 2016 , Pages 30-37 ; 00119164 (ISSN) ; Behshad Shafii, M ; Sharif University of Technology
Elsevier
2016
Abstract
In this paper, the performance of a novel HDH solar desalination system equipped with a combination of heat pipe (HP), evacuated tube collector (ETC) and air bubble column humidifier is experimentally investigated. This novel HDH system uses advantages of ETC-HP as a highly efficient thermal absorption and conductor device, and at the same time employs the advantages of an air bubble column humidifier, i.e. high interface area and effective mixing in order to heat the water and humidify the air, respectively. The effects of various parameters including incoming air flow rate into the humidifier, initial depth of water in the humidifier, and adding fluids such as oil and water in the space...
2PLoc: Preserving privacy in location-based services
, Article Proceedings - SocialCom 2010: 2nd IEEE International Conference on Social Computing, PASSAT 2010: 2nd IEEE International Conference on Privacy, Security, Risk and Trust, 20 August 2010 through 22 August 2010 ; August , 2010 , Pages 707-712 ; 9780769542119 (ISBN) ; Kharrazi, M ; Jalili, R ; Sharif University of Technology
2010
Abstract
Location-based services are becoming popular for mobile users. The mobile users' location plays a key role to provide the service from one side, but it can be considered as a dimension of their privacy and so necessary to keep it anonymous to the other parties. Since one important issue is to achieve an accurate service, it is important to use the mobile's accurate location. Using the location accurately raises some concerns on behalf of the user's privacy. One solution for meeting this requirement is using tickets by the means of a third party. The tickets should have some properties for not letting a mobile user to cheat and use the ticket more than one time. This paper proposes a protocol...
Dispersive micro-solid phase extraction using magnetic nanoparticle modified multi-walled carbon nanotubes coupled with surfactant-enhanced spectrofluorimetry for sensitive determination of lomefloxacin and ofloxacin from biological samples
, Article Materials Science and Engineering C ; Volume 60 , 2016 , Pages 30-36 ; 09284931 (ISSN) ; Pourghazi, K ; Hajjaran, S ; Sharif University of Technology
Elsevier Ltd
2016
Abstract
A dispersive micro-solid-phase extraction (D-μ-SPE) procedure coupled with surfactant-enhanced spectrofluorimetric detection was developed for determination of ofloxacin and lomefloxacin from biological and environmental samples. The D-μ-SPE procedure was performed using magnetic Fe3O4 nanoparticle grafted multi-walled carbon nanotube as an efficient adsorbent. The main factors affecting the signal enhancement (including surfactant concentration and pH) and extraction efficiency (including pH, extraction time, sample volume, amount of magnetic adsorbent, and desorption conditions) were investigated in detail. Under the optimized conditions, the calibration curves were linear (R2 0.9995) over...
Photocatalytic filtration reactors equipped with bi-plasmonic nanocomposite/poly acrylic acid-modified polyamide membranes for industrial wastewater treatment
, Article Separation and Purification Technology ; Volume 236 , 2020 ; Irani, E ; Pourghazi, K ; Sharif University of Technology
Elsevier B.V
2020
Abstract
In this study, two new composite membranes with antifouling and anti-biofouling properties were prepared through the modification of commercial polyamide (PA) discs using combination of in-situ polymerization of polyacrylic acid (PAA) and grafting of two synthesized bi-plasmonic Au-Ag and Ag-Au photocatalysts. The synthesis and characterization of the photocatalysts in batch mode were discussed in details as primary studies. Two intense 405-nm and 532-nm lasers for Ag-Au and Au-Ag photocatalysts, respectively and a solar-simulated xenon lamp for both photocatalysts were applied for photodegradation studies and the results were compared. In addition, the effect of other parameters such as...
MRI-PET image fusion based on NSCT transform using local energy and local variance fusion rules
, Article Journal of Medical Engineering and Technology ; Vol. 38, issue. 4 , 2014 , p. 211-219 ; Fatemizadeh, E ; Behnam, H ; Sharif University of Technology
2014
Abstract
Image fusion means to integrate information from one image to another image. Medical images according to the nature of the images are divided into structural (such as CT and MRI) and functional (such as SPECT, PET). This article fused MRI and PET images and the purpose is adding structural information from MRI to functional information of PET images. The images decomposed with Nonsubsampled Contourlet Transform and then two images were fused with applying fusion rules. The coefficients of the low frequency band are combined by a maximal energy rule and coefficients of the high frequency bands are combined by a maximal variance rule. Finally, visual and quantitative criteria were used to...
A robust dual source level set method for three-dimensional echocardiography image segmentation
, Article Journal of Theoretical and Applied Information Technology ; Volume 95, Issue 21 , 2017 , Pages 5701-5710 ; 19928645 (ISSN) ; Fatemizadeh, E ; Behnam, H ; Sharif University of Technology
2017
Abstract
Echocardiography as a common place device has been widely used for diagnosis. Segmentation of left ventricle just using the standard level set formulation based on the magnitude of intensity cannot restrict the contour evolution completely due to the lack of sharp edges. This paper aims to introduce a robust method for segmentation of three-dimensional echocardiography images based on two boundary maps namely distance map and probabilistic map as stopping criteria of contour evolution which are extracted using two different approaches. The distance map is extracted by applying Free Form Deformation (FFD) method on manually determined landmarks of initial spherical volume to register the...
An optimized probabilistic edge based level set method for left ventricle segmentation in echocardiography images
, Article Biomedical Research (India) ; Volume 28, Issue 8 , 2017 , Pages 3788-3793 ; 0970938X (ISSN) ; Fatemizadeh, E ; Behnam, H ; Sharif University of Technology
Scientific Publishers of India
2017
Abstract
In this paper, an efficient approach for ultrasonic object segmentation with special application for left ventricle segmentation in echocardiography images is proposed. At first, an efficient hybrid trend for ultrasonic image edge detection is suggested. Then, a modified level set approach is introduced based on the extracted edges and the computed probabilistic map as the stopping criteria for the contour evolution. Both synthetic and clinical images are utilized as validation measures with respect to the prior techniques which indicate outperform results quantitatively and qualitatively. Left ventricle segmentation using proposed method illustrates expert-approved performance, providing a...
A review on state-of-the-art applications of data-driven methods in desalination systems
, Article Desalination ; Volume 532 , 2022 ; 00119164 (ISSN) ; Faegh, M ; Khiadani, M ; Sharif University of Technology
Elsevier B.V
2022
Abstract
The substitution of conventional mathematical models with fast and accurate modeling tools can result in the further development of desalination technologies and tackling the need for freshwater. Due to the great capability of data-driven methods in analyzing complex systems, several attempts have been made to study various desalination systems using data-driven approaches. In this state-of-the-art review, the application of various artificial intelligence and design of experiment data-driven methods for analyzing different desalination technologies have been thoroughly investigated. According to the applications of data-driven methods in the field of desalination, the reviewed...
Laser-assisted triggered-drug release from silver nanoparticles-grafted dual-responsive polymer
, Article Materials Science and Engineering C ; Volume 76 , 2017 , Pages 536-542 ; 09284931 (ISSN) ; Sadighi Bonabi, R ; Pourghazi, K ; Sharif University of Technology
Elsevier Ltd
2017
Abstract
Laser assisted drug release from a synthesized plain polymer composed of poly (butyl methacrylate-co-acrylamide-co-methacrylic acid) [P(BMA-co-AAm-co-MAA)] and a metallo-polymer composed of silver nanoparticles (Ag NPs) grafted plain polymer (the nanocomposite) were studied to investigate their capability to serve as drug carriers. Positive temperature dependent swelling changes were observed for both carriers and their thermal sensitivity and thermal and optical switching properties were investigated in two buffered solutions. An acidic solution with pH = 1.2 to simulate stomach body condition and a neutral solution with pH = 7.4 to simulate intestine condition. Reversible phase transition...
Synthesis of magneto-plasmonic Au-Ag NPs-decorated TiO2-modified Fe3O4 nanocomposite with enhanced laser/solar-driven photocatalytic activity for degradation of dye pollutant in textile wastewater
, Article Ceramics International ; Volume 45, Issue 14 , 2019 , Pages 17837-17846 ; 02728842 (ISSN) ; Anvari, A ; Sadighi Bonabi, R ; Sharif University of Technology
Elsevier Ltd
2019
Abstract
The synergistic effect of plasmonic Au-Ag nanoparticles (NPs) on the increase of absorption band of nano-sized TiO2 and magnetic property of Fe3O4 NPs on the separation-ability of this semiconductor was applied for preparation of eight magneto-plasmonic photocatalysts for degradation of rhodamine-6G (Rh6G) in textile wastewater. The size, structure, morphology, crystallinity and optical and magnetic properties of prepared photocatalysts have been evaluated by various characterization techniques. Their photocatalytic activities were assessed under irradiation of an intense linear 405-nm laser and a continuous solar-simulated xenon lamp. The results were demonstrated that in comparison to the...
Switchable on/off drug release from gold nanoparticles-grafted dual light- and temperature-responsive hydrogel for controlled drug delivery
, Article Materials Science and Engineering C ; Volume 76 , 2017 , Pages 242-248 ; 09284931 (ISSN) ; Sadighi Bonabi, R ; Pourghazi, K ; Sharif University of Technology
Elsevier Ltd
2017
Abstract
A switchable dual light- and temperature-responsive drug carrier using gold nanoparticles (Au NPs)-grafted poly(dimethylacrylamide-co-acrylamide)/poly acrylic acid [P(DMA-co-AAm)/PAAc] hydrogel was prepared by free radical polymerization procedure using N,N-methylenebisacrylamide as cross-linker and ammonium persulfate as initiator. Initial P(DMA-co-AAm) hydrogel and uniformly-distributed stable Au NPs, prepared by reduction of hydrogen tetrachloroaureate (III) hydrate in the presence of trisodium citrate, were synthesized separately. Then, the prepared P(DMA-co-AAm) and Au NPs were added to an acrylic acid solution along with the cross-linker and initiator to prepare PAAc hydrogel within...
Laser and solar light-induced degradation of pollutant dyes using bi-plasmonic ag-au nanoparticles-decorated magnetic tio2 for textile wastewater treatment
, Article Journal of Nanostructures ; Volume 12, Issue 1 , 2022 , Pages 45-61 ; 22517871 (ISSN) ; Shapouri, M. R ; Amoli-Diva, M ; Sharif University of Technology
University of Kashan
2022
Abstract
Eight eco-friendly, and magnetically-separable heterogeneous photocatalysts including five Au nanoparticles (NPs) modified magnetic TiO2@Fe3O4 NPs and three Ag-Au bi-plasmonic NPs-decorated TiO2@Fe3O4 NPs with enhanced photocatalytic performance under visible light were synthesized and used for photodegradation of methyl orange (MO) as a model pollutant in textile wastewater samples. The photocatalytic activity was assessed using two radiation sources namely, an intense linear 532-nm laser and a continuous solar-simulated xenon lamp. Compared to the TiO2 alone, the prepared photocatalysts revealed efficient photocatalytic activity in visible region due to the presence of two localized...
Automatic segmentation of brain MRI in high-dimensional local and non-local feature space based on sparse representation
, Article Magnetic Resonance Imaging ; Volume 31, Issue 5 , 2013 , Pages 733-741 ; 0730725X (ISSN) ; Fatemizadeh, E ; Behnam, H ; Sharif University of Technology
2013
Abstract
Automatic extraction of the varying regions of magnetic resonance images is required as a prior step in a diagnostic intelligent system. The sparsest representation and high-dimensional feature are provided based on learned dictionary. The classification is done by employing the technique that computes the reconstruction error locally and non-locally of each pixel. The acquired results from the real and simulated images are superior to the best MRI segmentation method with regard to the stability advantages. In addition, it is segmented exactly through a formula taken from the distance and sparse factors. Also, it is done automatically taking sparse factor in unsupervised clustering methods...
Adaptive sparse representation for MRI noise removal
, Article Biomedical Engineering - Applications, Basis and Communications ; Volume 24, Issue 5 , October , 2012 , Pages 383-394 ; 10162372 (ISSN) ; Fatemizadeh, E ; Behnam, H ; Sharif University of Technology
World Scientific
2012
Abstract
Sparse representation is a powerful tool for image processing, including noise removal. It is an effective method for Gaussian noise removal by taking advantage of a fixed and learned dictionary. In this study, the variable distribution of Rician noise is reduced in magnetic resonance (MR) images by sparse representation based on reconstruction error sets. Standard deviation of Gaussian noise is used to find these errors locally. The proposed method represents two formulas for local error calculation using standard deviation of noise. The acquired results from the real and simulated images are comparable, and in some cases, better than the best Rician noise removal method due to the...
Thermodynamic analysis of a novel combined power and refrigeration cycle comprising of EKalina and ejector refrigeration cycles
, Article International Journal of Refrigeration ; Volume 104 , 2019 , Pages 291-301 ; 01407007 (ISSN) ; Faegh, M ; Shafii, M. B ; Sharif University of Technology
Elsevier Ltd
2019
Abstract
A novel combined power and refrigeration cycle is introduced and analyzed from the thermodynamic standpoint. The proposed cycle is an integration of a Kalina cycle equipped with an ejector (EKalina) and an ejector refrigeration cycle (ERC). In order to enhance the overall cycle performance, the possibility of employing two-phase ejectors in combined power and refrigeration cycles is studied. A parametric analysis is conducted to investigate the effects of the key thermodynamic parameters namely turbine inlet pressure, split ratio, basic ammonia concentration, heat source and evaporator temperatures on the cycle performance. The developed model is also verified with available data and it is...
Preparation of ultrahigh-molecular-weight polyethylene/carbon nanotube nanocomposites with a Ziegler-Natta catalytic system and investigation of their thermal and mechanical properties
, Article Journal of Applied Polymer Science ; Volume 125, Issue SUPPL. 1 , 2012 , Pages E453-E461 ; 00218995 (ISSN) ; Ramazani, S. A. A ; Izadi, H ; Sharif University of Technology
Wiley
2012
Abstract
In this research, ultrahigh-molecular-weight polyethylene (UHMWPE)/multiwalled carbon nanotube (MWCNT) nanocomposites with different nanotube concentrations (0.5, 1.5, 2.5, and 3.5 wt %) were prepared via in situ polymerization with a novel, bisupported Ziegler-Natta catalytic system. Magnesium ethoxide [Mg(OEt) 2] and surface-functionalized MWCNTs were used as the support of the catalyst. Titanium tetrachloride (TiCl 4) accompanied by triethylaluminum constituted the Ziegler-Natta catalytic system. Preparation of the catalyst and the polymerization were carried out in the slurry phase under an argon atmosphere. Support of the catalyst on the MWCNTs was investigated with Fourier transform...
Method development for simultaneous determination of active ingredients in cough and cold pharmaceuticals by high performance liquid chromatography
, Article Heliyon ; Volume 5, Issue 12 , 2019 ; 24058440 (ISSN) ; Shapouri, M. R ; Amoli Diva, M ; Hooshangi, A. H ; Khodayari, F
Elsevier Ltd
2019
Abstract
A rapid, simple and efficient liquid chromatographic method was developed for simultaneous determination of three active ingredients namely, chlorpheniramine maleate, phenylephrine hydrochloride and guaifenesin along with sodium benzoate preservative common cold medications (syrups) and the method was validated based on the International Conference on Harmonization (ICH) and United State Pharmacopeia (USP) guidelines. Separation of the analytes was achieved within 15 min on a nucleosil gravity phenyl column in a single run with a mobile phase consisting of methanol: buffer mixture (15:85 v/v) at room temperature, in isocratic mode with flow rate of 0.8 mL min−1. A comprehensive study on...
Effect of DL-methionine concentration, moisture content and bulk density of animal feed on the light-induced fluorescence as a process analytical tool
, Article Pertanika Journal of Science and Technology ; Volume 28, Issue 1 , 2020 , Pages 33-48 ; Ghasemzadeh, H ; Ablollahpour, S ; Amoli Diva, M ; Sharif University of Technology
Universiti Putra Malaysia Press
2020
Abstract
Mix uniformity is a critical quality control point in food manufacturing. Process analytical technology (PAT) provides new technological opportunities for fulfilling and perhaps replacing conventional sampling methods by proposing spectroscopic analyzers for measuring blend homogeneity. Many spectroscopic analyzers have been used in powder blending processes. Light-induced fluorescence (LIF) is the most rapid and consistent underutilized PAT. An experiment was conducted to evaluate the effects of DL-methionine concentration, moisture content (MC) and bulk density (BD) on LIF responses. Fluorescent responses to powder mixtures comprising 0.05–0.50% w/w fluorescent active pharmaceutical...
Effect of cooling rate on microstructure and mechanical properties of gray cast iron
, Article Materials Science and Engineering A ; Volume 528, Issue 2 , 2010 , Pages 583-588 ; 09215093 (ISSN) ; Davami, P ; Varahram, N ; Sharif University of Technology
2010
Abstract
This paper presents the results obtained and the deductions made from a series of microstructural studies and mechanical tests involving gray cast iron which was sand cast using a variety of modules. The effect of cooling rate on the primary dendrite arm spacing (DAS), secondary dendrite arm spacing (SDAS), thickness of ferrite-cementite layer (λe) and the hardness (HB) were evaluated. Results show that the both DAS and SDAS and also λe are highly dependent on the cooling rate, and they decreases as the cooling rate increases. More attempts were also done to correlate the HB with DAS, SDAS and λe. It was found that HB increases as DAS, SDAS and λe decreases