Sharif Digital Repository

A combination of silica chloride and wet SiO2 was used as an effective deacetalizating agent for the conversion of acetals to their corresponding carbonyl derivatives under mild and heterogeneous condition  

In this study, quick route-coating is practiced to substitute methyl ammonium (MA) cation with formamidinium (FA) at different ratios. Through optimizing the MA:FA ratio, a maximum power conversion efficiency (PCE) of 8.31% is achieved for holes transporting material-free MA0.8FA0.2PbI3 mixed PSCs with the JSC of 19.02 mA/cm2, VOC of 0.859 V and FF of 50.88%. Then, to improve the performance, stability and carrier transport dynamic, various additives (PVA, PVP, PEG and EC) are incorporated into the perovskite layer. The treatment of perovskites with additives has proved to cause significant changes in the surface roughness, charge accumulation, charge transport, charge transport resistance,... 

A modified carbon paste electrode was prepared by incorporating TiO2 nanoparticles with bis[bis(salicylidene-1,4-phenylenediamine)molybdenum(VI)]. A mixture of fine graphite powder with 4 wt% of TiO2 nanoparticles was applied for the preparation of the carbon paste (by dispersing in paraffin) and finally modified with a molybdenum (VI) complex. The electrocatalytic oxidation of guanine (G) was investigated on the surface of the molybdenum (VI) complex-TiO2 nanoparticle modified carbon paste electrode (MCTNMCPE) using cyclic voltammetry (CV), differential pulse voltammetry (DPV), chronoamperometry (CHA) and chronocoloumetry (CHC). Using the modified electrode, the kinetics of G... 

A modified dynamic-based pushover (MDP) analysis is proposed to properly consider the effects of higher modes and the nonlinear behavior of the structural systems. For this purpose, first, a dynamic-based story force distribution (DSFD) load pattern is constructed using a linear dynamic analysis, either time history (THA) or response spectrum (RSA). Performing an initial pushover analysis with the DSFD load pattern, a nonlinearity modification factor (NMF) is calculated to modify the DSFD load pattern. The envelope of the peak responses of the structure obtained from 2 pushover analyses with the modified DSFD load pattern as well as the code suggested first mode load pattern are considered... 

Enolizable ketones have been reacted in a one-pot method with aromatic aldehydes, acetyl chloride and acetonitrile at room temperature in the presence of SnCl4/SiO2 to furnish the corresponding β-acetamidoketones in improved yields. Acetylation of an aromatic hydroxyl group was observed while using 4-hydroxybenzaldehyde or vanillin and the corresponding β-acetamidoketones were isolated in an excellent yield  

Synthesis of 14-aryl or alkyl-14H-dibenzo[a,j]xanthenes using nano-TiO 2 as eco-friendly and efficient catalyst is reported. Short reaction times, high yields, a clean process, simple methodology, easy work-up and green conditions are advantages of this protocol  

A combination of silica chloride and wet SiO2 was used as an effective deacetalizating agent for the conversion of acetals to their corresponding carbonyl derivatives under mild and heterogeneous condition  

In this paper, two online path planning methods are presented for SURENA III humanoid robot by using model predictive control scheme. The methods are general control schemes which can generate the online motions for walking of a humanoid robot. For lowering computational costs a three dimensional linear inverted pendulum model is used instead of the full dynamical model of the robot. The generated trajectories are then used for computing the zero-moment point (ZMP) of the robot and the joint torques. The resulted joint torques of the two methods are compared to torques obtained from Genetic Algorithm (GA) path planning method presented for SURENA III humanoid robot in previous studies. The... 

Aromatic aldehydes and ketones are readily acetalized or ketalized under microwave irradiation in the presence of water as a solvent  

A four-step synthetic strategy was applied to achieve novel methacrylic monomers. 5-Norbornene-2,2-dimethanol was prepared from a Diels–Alder reaction of cyclopentadiene and acrolein, followed by the treatment of the adduct with an HCHO/KOH/MeOH solution. The resulting 1,3-diol (1) was then acetalized with different aromatic aldehydes having OH groups on the ring to produce four spiroacetal derivatives. The reaction of methacryloyl chloride with the phenolic derivatives led to four new methacrylic monomers that were identified spectrochemically (mass, FTIR, 1H-NMR, and 13C-NMR spectroscopy). Free radical solution polymerization was used to prepare novel spiroacetal–norbornene containing... 

An eight-step synthetic strategy was followed to prepare a series of novel azobenzene-containing methacrylate monomers bearing spiroacetal-norbornene moiety and methylene spacers. Thus, the adduct 2, obtained from cyclopentadiene and acrolein, was converted to 1,3-diol 3. The diol was acetalized with nitrobenzaldehyde 4 under microwave irradiation to obtain nitro compound 5 that was then reduced to amino compound 6. Diazonium salt of 6 was coupled with phenol to produce phenolic compound 7 which was then reacted with n-dibromoalkanes (n = 2, 4, 6, 8, 10) to yield bromo compounds 9a-e. Nucleophilic substitution reaction of the bromo compounds with lithium methacrylate produced the methacrylic... 

A 2D numerical investigation is performed to better understand the transient thermo-fluid processes in a vortex tube for a cold mass fraction equal to0.44. The results along the Ranque-Hilsch vortex tube reveal a close agreement with past numerical and experimental data. The distribution of axial, radial, and tangential velocities as well as the stagnation pressure and temperature are examined at different positions for different time steps. The results indicate that the tangential velocity is the most significant velocity component and dominates the heat transfer and energy conversion processes. In addition, it is evident that the core of the cold end experiences the highest pressure... 

Based on special properties of metal dampers such as high energy dissipation, stable hysteric cycles, simple application, low cost, insensitivity to changes of temperature and the ability to substitute after the occurrence of earthquakes, they are being used for structural control. One of these metal dampers which has been of special interest is the tapered steel slit damper (TSS). When shear forces are applied, this damper yields and enters the plastic zone. The TSS damper is made of pieces of standard wide flanges where slits have been extracted from their web. These dampers are connected to the top of the chevron braces and under the middle of the beams. In the endurance time (ET) method... 

We use a direct simulation Monte Carlo (DSMC) method to simulate gas heating/cooling and choked subsonic flows in micro/nanoscale channels subject to either constant wall temperature or constant/variable heat flux boundary conditions. We show the effects of applying various boundary conditions on the mass flow rate and the flow parameters. We also show that it is necessary to add a buffer zone at the end of the channel if we wish to simulate more realistic conditions at the channel outlet. We also discuss why applying equilibrium-based Maxwellian distribution on molecules coming from the channel outlet, where the flow is nonequilibrium, will not disturb the DSMC solution. The current... 

Microstructural changes in friction-stir welding (FSW) of artificially aged AA2017 were investigated. First, FSW was performed with rotational and linear speeds of 800 rpm and 40 mm/min, respectively. Then, microstructural studies by means of optical metallography and electron microscopy were conducted in different regions of the welded plates. Hardness testing was also employed to determine local strength and subsequent natural aging progress after welding. The results indicate that the considerable hardness degradation occurs in the thermo-mechanically affected zone owing to coarsening of semi-coherent precipitates. Grain refinement also takes place in the weld nugget as a result of...