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mirjalili--mohamad-reza
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Numerical Investigation of Nitrogen Condensation in a Two-phase Vortex Tube
, M.Sc. Thesis Sharif University of Technology ; Ghorbanian, Kaveh (Supervisor)
Abstract
The Ranque-Hilsch vortex tube (RHVT) has no moving parts through which a high-pressure fluid gains on rotational velocity by passing radially through the inlet nozzles and then enters the vortex chamber. Subsequently, the high-pressure fluid becomes divided into two relatively distinctive hot and cold axial flows. Today, while RHVT is of great industrial interest due to its simplicity in manufacturing and operation; however, the mechanism of energy dissociation, which is dominated by the complex coupled interaction of the viscous thermo-fluid characteristics and geometrical properties, is not fully understood and no clear theory has been proposed to explain the energy dissociation so far....
Modeling and Analysis of the Powder Deposition Mechanisms of Selective Laser Sintering Process
, M.Sc. Thesis Sharif University of Technology ; Movahedi, Mohamad Reza (Supervisor)
Abstract
Selective laser sintering is a technique which uses a laser as the power source to sintering some selected points at a bed of powder in order to create a solid structure. In this research the SLS mechanisms of powder deposition is simulated and surface smoothness and layer density created by each mechanism is computed. For this purpose roller, blade and hopper mechanisms are simulated. For this simulation, polyamide 12 (PA2200) which is a common material is used. In this simulation at first powder specifications are extracted according to the references and for particle shape instead of using the spherical particle shape we use a certain shape that is more close to reality which created by...
Theoretical And Experimental Investigation on The Effect of Sinker Tube Geometry on Hydrodynamic Behavior of The Floating Fish Cage in Waves and Current
, M.Sc. Thesis Sharif University of Technology ; Tabeshpour, Mohamad Reza (Supervisor)
Abstract
This study was conducted to investigate a theoretical and experimental two-dimensional model of a floating fish cage in regular waves and uniform current. Due to the inefficiency of computational fluid dynamics (CFD) in solving such problems, developing a simple model to predict the results is highly advantageous. In this study, a simple mass-spring model was developed to simulate the problem. After validating the results of this simple model through a series of model tests in a wave tank, it was further utilized to extract additional results. Experiments were conducted at six different wave heights and four current velocities. In all experiments, wave steepness was maintained at a ratio of...
Experimental Investigation of Using Phase Change Material as a Cooling Method for a Thermoelectric Generator
, M.Sc. Thesis Sharif University of Technology ; Morad, Mohamad Reza (Supervisor)
Abstract
Global energy consumption is on a trajectory to surge by 50% by 2050, primarily driven by prevailing energy consumption patterns. Consequently, the imperative to innovate and develop novel energy sources, such as the utilization of recycled waste heat, has become paramount for the foreseeable future. In light of this, this paper delves into the transformative potential of employing Phase Change Materials (PCMs) for cooling Thermoelectric Generators (TEGs) and harnessing waste heat for productive purposes. The research investigates three distinct configurations to evaluate the efficacy of PCMs in enhancing thermal management. Configuration 1 exclusively relies on an active cooling fan, while...
Modeling of the Mechanical Behavior of Rapid Prototyped Scaffolds Based on Their Pore Architecture and Introducing a Prototyping Method to Produce Ceramic Scaffolds
, Ph.D. Dissertation Sharif University of Technology ; Bagheri, Reza (Supervisor) ; Baghaban Eslaminejad, Mohamad Reza (Supervisor)
Abstract
Mechanical behavior of tissue engineering scaffolds plays a key role in their biological performance; however the effect of microstructural features on mechanical behavior of such scaffolds is still under investigation. The objective of this study was to investigate the influence of pore architecture and relative density on mechanical behavior of rapid prototyped scaffolds. In this regard, scaffolds with different cubic, hexagonal and trigonal unit cells were designed. These unit cells were repeated in different arrangements in 3D space to produce different nodal connectivities. The internal dimension of pores varied from 500 to 600 μm. Plastic models of scaffolds then fabricated by 3D...
Oxidative Addition of Amines to Aldehydes Catalyzed by Supported Cobalt Nanoparticles on SBA-15
, M.Sc. Thesis Sharif University of Technology ; Saidi, Mohamad Reza (Supervisor) ; Rajabi, Fatemeh (Co-Advisor)
Abstract
Considering the widespread applications of amides, synthesis of these compounds is of great importance. The one pot oxidative addition of amines to aldehydes is one of the most simple and appealing approaches to synthesis amides. With the aim of developing a mild and convenient approach towards preparation of amides, numerous methods have been reported for this important process over the past few decades. These improvements have been mostly related to the optimization of reaction conditions and the use of more challenging substrates including diverse derivatives of aldehydes, and also design a novel and effective catalytic systems. Due to the various advantages of supported heterogeneous...
Colloidal Stability Investigation of Physisorbed and Chemisorbed Poly(ethylene glycol)-Coated Iron Oxide Nanoparticles
, M.Sc. Thesis Sharif University of Technology ; Madaah Hosseini, Hamid Reza (Supervisor)
Abstract
In the current research, colloidal stability of two different types of coating on the surface of Superparamagnetic Iron Oxide nanoparticles (SPIONs) was studied. In the first triumph, a dual-layer coating was achieved by utilizing optimum amount of Dextran and different PEG (Poly(ethylene glycol)) concentrations which the weight ratios of iron oxide/PEG were 1/1, 2/1, 4/1, 8/1, and 16/1. Then, the presence of the coating was characterized by XRD, FT-IR, DLS and FE-SEM methods. These results together with the TGA ones revealed that as the concentration of PEG surfactant increases, the thickness of coating increases. Moreover, VSM test was performed to specify the effect of coating on the...
Electrochemical Hydrogen Generation Using Metal Organic Frameworks Derived Catalysts
, M.Sc. Thesis Sharif University of Technology ; Gholami, Mohamad Reza (Supervisor)
Abstract
In recent years, the widespread investigation on multi-transition metal oxides that with two or more transition metal oxides, have been increased rapidly for electrochemical application due to low cost, high conductivity and good electrochemical performance other than single metal oxides. In this project, CuCo2O4 nanoparticles were firstly fabricated by decomposing of CuCo-MOF as the template. The as prepared samples were used to synthesis a new nanocomposite of MoS2 and CuCo2O4. The best ratio of the two component were optimized to prepare the best electrocatalyst for Hydrogen evolution reaction (HER). The structure of prepared nanocomposite were investigated by various techniques such as...
A Model to Determine the Inventory Policy to Allow the Transshipment of Goods between Retailers Warehouses in Vendor-Managed Inventory System
, M.Sc. Thesis Sharif University of Technology ; Akbari Jokar, Mohamad Reza (Supervisor)
Abstract
The integrative supply chain management is one of the main business processes between final consumer and supplier and it is formed by responsibilities such as production, services and information those have added value for customers and beneficiaries. Therefore and as the goal of a chain is maximization of gained value for the factors involved in chain, so, this goal can be more accessible by decreasing transportation (transportation method, tracking, …) and stock costs (conservation, ordering, …). As its purpose, this thesis intends to introduce and increase the options of goods transportation possibilities between retailers’ warehouses and evaluation of its effect on transportation and...
Developing a Simulator for Concurrent Execution of Multiple Workflows in Fog Computing Environment
, M.Sc. Thesis Sharif University of Technology ; Izadi, Mohamad (Supervisor)
Abstract
Fog computing environment consists of several devices which distribute across an arbitrary topology. Each of these devices is capable of carrying out a designated computation simultaneously with other devices. One of the common ways of describing a computation is through the usage of workflows. Workflow is a flexible and formal way of modeling tasks and their requirements for execution. A workflow is essentially a DAG. Therefore, it can model the data dependency between tasks quite accurately. The complex structure of a workflow in conjunction with the homogenous nature of devices in a fog environment makes it difficult to find a resource management algorithm to minimize execution time, used...
ChemInform abstract: microwave-assisted rapid ketalization/acetalization of aromatic aldehydes and ketones in aqueous media [electronic resource]
, Article Journal of Chemical Research ; September 1999, Volume -, Number 9; Page(s) 562 to 563 ; Mirjalili, Bibi Fatemeh ; Sharif University of Technology
Abstract
Aromatic aldehydes and ketones are readily acetalized or ketalized under microwave irradiation in the presence of water as a solvent
Synthesis and characterization of poly(methacrylates) containing spiroacetal and norbornene moieties in side chain [electronic resource]
, Article Journal of Applied Polymer Science ; Volume 77, Issue 1, pages 30–38, 5 July 2000 ; Mirjalili, Bibi Fatemeh ; Sharif University of Technology
Abstract
A four-step synthetic strategy was applied to achieve novel methacrylic monomers. 5-Norbornene-2,2-dimethanol was prepared from a Diels–Alder reaction of cyclopentadiene and acrolein, followed by the treatment of the adduct with an HCHO/KOH/MeOH solution. The resulting 1,3-diol (1) was then acetalized with different aromatic aldehydes having OH groups on the ring to produce four spiroacetal derivatives. The reaction of methacryloyl chloride with the phenolic derivatives led to four new methacrylic monomers that were identified spectrochemically (mass, FTIR, 1H-NMR, and 13C-NMR spectroscopy). Free radical solution polymerization was used to prepare novel spiroacetal–norbornene containing...
The effect of multiwalled carbon nanotubes and activated carbon on the morphology and photocatalytic activity of TiO2/C hybrid materials
, Article Catalysis Science & Technology ; 1 , Jan , 2011 , pp. 279-284 ; Ghasemia, S. (Shahnaz) ; Gholami, M. R. (Mohamad Reza) ; Sharif University of Technology
2011
Abstract
TiO2 nanoparticles supported on activated carbon (AC) and multiwalled carbon nanotubes (MWCNTs) were prepared by the sol–gel method using ultrasonic irradiation. All the prepared samples were calcined at different temperatures and characterized by X-ray diffraction, nitrogen adsorption/desorption isotherms, scanning electron microscopy, transmission electron microscopy and diffuse reflectance spectroscopy. The effects of size and type of carbon on the morphology and photocatalytic activity of the resulting hybrid materials were investigated. The results showed that a decrease in the size of the carbon led to a decrease in size of TiO2 nanoparticles. Both AC and MWCNTs retarded the...
Unsteady Aerodynamic Simulation of Horizontal Axis Wind Turbine (HAWT)
, M.Sc. Thesis Sharif University of Technology ; Abbaspour, Madjid (Supervisor) ; Soltani, Mohamad Reza (Co-Advisor)
Abstract
The ultimate aim of this research is optimizing high- performance Horizontal Axis Wind Turbine (HAWT) associated with using Computational fluid dynamics (CFD) to predict the flow behavior over wind turbine blades. Computational prediction of the flow over wind turbines is a challenging numerical problem because of the complicated aerodynamics and large variation in length scales. Phenomena such as; the unsteady flow, vortex shedding of the blade tips, flow separation, complicated blade geometry due to variable twist and chord and changes in angle of attack, and highly turbulent flow over blade sections makes CFD prediction challenging, as well as interesting. The goal is to gain an in depth...
Investigation of the Drop Tank Influence on Range and Optimization of Its Geometry
, M.Sc. Thesis Sharif University of Technology ; Durali, Mohamad (Supervisor)
Abstract
This project focuses on the design of fuel drop tanks for airplanes that add minimal drag and positive lift to the flying object. This will obviously effect the stability and dynamic performance of the airplane. To reduce adverse dynamic effects the tank was divided to several segment with a special emptying sequence. The add-on tank has to have no interference with the object existing systems and require minimum structural changes in the object. Several designs were proposed and the one gaining highest marks was selected. The flow field and the dynamic behavior of combined vehicle and drop tanks were studied using FE simulations. The result shows that adding a drop tank with optimized...
Developing a Parallel DSMC Algorithm for Simulating Flow in Micro-Nano Propulsion Systems
, M.Sc. Thesis Sharif University of Technology ; Darbandi, Masoud (Supervisor)
Abstract
With the rapid development of mico-nano propulsion systems in micro-spacecrafts and micro-sattelites, precise investigation of flow field in these devices has become necessary. Micro propulsion systems usually have a thrust in order of mili Newton, and they can be used for maneuvers of spacecrafts with mass of less than 10 kg. Micro propulsion systems are usually classified according to their thrust generation mechanism to different classes like cold gas, and chemical propulsion systems. Cold gas micro propulsion systems obtain their energy from thermodynamic expansion of gas and not by combustion. If the flow fiel dimensionare comparable to mean free path, rarefaction effects are observed...
Estimating Time and Cost Completion using Resource Performance
, M.Sc. Thesis Sharif University of Technology ; Shadrokh, Sharam (Supervisor)
Abstract
Deciding for the future is one of the key tasks that project managers must carry out. Accurate Estimate at Completion helps them make the right decision. Numeruse novel methods have been proposed for calculation of estimate at completion which most of them are based on Earned Value Management. The question is whether considering the resources, as the essential elements of activities and therefoe the project, would result in a more accurate Estimation. In this Thesis, we propose a method that uses resource performance and activity structure to calculate the Estimate at Completion. The method also forecasts future resource usage. To evaluate the proposed method, we generated fictitious...
Numerical investigation of transient thermo-fluid processes in a Ranque-Hilsch vortex tube
, Article International Journal of Refrigeration ; Volume 131 , 2021 , Pages 746-755 ; 01407007 (ISSN) ; Ghorbanian, K ; Sharif University of Technology
Elsevier Ltd
2021
Abstract
A 2D numerical investigation is performed to better understand the transient thermo-fluid processes in a vortex tube for a cold mass fraction equal to0.44. The results along the Ranque-Hilsch vortex tube reveal a close agreement with past numerical and experimental data. The distribution of axial, radial, and tangential velocities as well as the stagnation pressure and temperature are examined at different positions for different time steps. The results indicate that the tangential velocity is the most significant velocity component and dominates the heat transfer and energy conversion processes. In addition, it is evident that the core of the cold end experiences the highest pressure...
Incredible antibacterial activity of noble metal functionalized magnetic core-zeolitic shell nanostructures
, Article Materials Science and Engineering C ; Volume 35, Issue 1 , Feb , 2014 , Pages 115-121 ; Janatrostami, S ; Karanji, A. K ; Gholami, M. R. (Mohamad Reza) ; Sharif University of Technology
2014
Abstract
Functionalized magnetic core-zeolitic shell nanostructures were prepared by hydrothermal and coprecipitation methods. The products were characterized by Vibrating Sample Magnetometer (VSM), X-ray powder diffraction (XRD), Fourier Transform Infrared (FTIR) spectra, nitrogen adsorption-desorption isotherms, and Transmission Electron Microscopy (TEM). The growth of mordenite nanoparticles on the surface of silica coated nickel ferrite nanoparticles in the presence of organic templates was also confirmed. Antibacterial activity of the prepared nanostructures was investigated by the inactivation of Escherichia coli as a gram negative bacterium. A new mechanism was proposed for inactivation of E....
Solvent effects on the reaction rate and selectivity of synchronous heterogeneous hydrogenation of cyclohexene and acetone in ionic liquid/alcohols mixtures
, Article Journal of Molecular Catalysis A: Chemical ; Volume 306, Issues 1–2 , July , 2009 , Pages 11–16 ; Habibi-Yangjeh, A. (Aziz) ; Gholamia, M. R. (Mohamad Reza) ; Sharif University of Tecnology
2009
Abstract
Synchronous heterogeneous catalytic hydrogenation of cyclohexene and acetone, catalyzed by Pt/Al2O3, was carried out in solutions of 2-hydroxy ethylammonium formate (a room temperature ionic liquid, RTIL) with ethanol and propan-1-ol at 25 °C. Rate constants and selectivity of the reaction (relative to cyclohexene hydrogenation) increase with mole fraction of the ionic liquid (IL). The reactants tendency to the catalyst surface increases by addition of the ionic liquid and thus the reaction rate increases, especially for cyclohexene hydrogenation. Consequently the selectivity to cyclohexene hydrogenation was increased. Single-parameter correlations of log kvs.π* (dipolarity/polarizibility)...