Sharif Digital Repository

Aromatic aldehydes and ketones are readily acetalized or ketalized under microwave irradiation in the presence of water as a solvent  

A four-step synthetic strategy was applied to achieve novel methacrylic monomers. 5-Norbornene-2,2-dimethanol was prepared from a Diels–Alder reaction of cyclopentadiene and acrolein, followed by the treatment of the adduct with an HCHO/KOH/MeOH solution. The resulting 1,3-diol (1) was then acetalized with different aromatic aldehydes having OH groups on the ring to produce four spiroacetal derivatives. The reaction of methacryloyl chloride with the phenolic derivatives led to four new methacrylic monomers that were identified spectrochemically (mass, FTIR, 1H-NMR, and 13C-NMR spectroscopy). Free radical solution polymerization was used to prepare novel spiroacetal–norbornene containing... 

A 2D numerical investigation is performed to better understand the transient thermo-fluid processes in a vortex tube for a cold mass fraction equal to0.44. The results along the Ranque-Hilsch vortex tube reveal a close agreement with past numerical and experimental data. The distribution of axial, radial, and tangential velocities as well as the stagnation pressure and temperature are examined at different positions for different time steps. The results indicate that the tangential velocity is the most significant velocity component and dominates the heat transfer and energy conversion processes. In addition, it is evident that the core of the cold end experiences the highest pressure... 

Based on special properties of metal dampers such as high energy dissipation, stable hysteric cycles, simple application, low cost, insensitivity to changes of temperature and the ability to substitute after the occurrence of earthquakes, they are being used for structural control. One of these metal dampers which has been of special interest is the tapered steel slit damper (TSS). When shear forces are applied, this damper yields and enters the plastic zone. The TSS damper is made of pieces of standard wide flanges where slits have been extracted from their web. These dampers are connected to the top of the chevron braces and under the middle of the beams. In the endurance time (ET) method... 

We use a direct simulation Monte Carlo (DSMC) method to simulate gas heating/cooling and choked subsonic flows in micro/nanoscale channels subject to either constant wall temperature or constant/variable heat flux boundary conditions. We show the effects of applying various boundary conditions on the mass flow rate and the flow parameters. We also show that it is necessary to add a buffer zone at the end of the channel if we wish to simulate more realistic conditions at the channel outlet. We also discuss why applying equilibrium-based Maxwellian distribution on molecules coming from the channel outlet, where the flow is nonequilibrium, will not disturb the DSMC solution. The current... 

A modified dynamic-based pushover (MDP) analysis is proposed to properly consider the effects of higher modes and the nonlinear behavior of the structural systems. For this purpose, first, a dynamic-based story force distribution (DSFD) load pattern is constructed using a linear dynamic analysis, either time history (THA) or response spectrum (RSA). Performing an initial pushover analysis with the DSFD load pattern, a nonlinearity modification factor (NMF) is calculated to modify the DSFD load pattern. The envelope of the peak responses of the structure obtained from 2 pushover analyses with the modified DSFD load pattern as well as the code suggested first mode load pattern are considered... 

A combination of silica chloride and wet SiO2 was used as an effective deacetalizating agent for the conversion of acetals to their corresponding carbonyl derivatives under mild and heterogeneous condition  

Microstructural changes in friction-stir welding (FSW) of artificially aged AA2017 were investigated. First, FSW was performed with rotational and linear speeds of 800 rpm and 40 mm/min, respectively. Then, microstructural studies by means of optical metallography and electron microscopy were conducted in different regions of the welded plates. Hardness testing was also employed to determine local strength and subsequent natural aging progress after welding. The results indicate that the considerable hardness degradation occurs in the thermo-mechanically affected zone owing to coarsening of semi-coherent precipitates. Grain refinement also takes place in the weld nugget as a result of... 

The current research uses an unstructured direct simulation Monte Carlo (DSMC) method to numerically investigate supersonic and subsonic flow behavior in micro convergent-divergent nozzle over a wide range of rarefied regimes. The current unstructured DSMC solver has been suitably modified via using uniform distribution of particles, employing proper subcell geometry, and benefiting from an advanced molecular tracking algorithm. Using this solver, we study the effects of back pressure, gas/surface interactions (diffuse/specular reflections), and Knudsen number, on the flow field in micronozzles. We show that high viscous force manifesting in boundary layers prevents supersonic flow formation... 

In this study, the supersonic and choked subsonic flows through micro/nano channels are investigated using direct simulation Monte Carlo (DSMC) method. The supersonic case is simulated at different Knudsen numbers covering slip to transition flow regimes, while the effects of inlet Mach and back pressure are studied in details. The inlet/outlet pressure boundary conditions are suitably implemented benefiting from the basics of characteristics theory. A behavior similar to the one predicted by the Fanno theory is observed here; i.e., the supersonic flow velocity decelerates up to a choking condition where any further increase in Knudsen number is impossible unless strong normal/oblique shocks... 

Synthesis of 14-aryl or alkyl-14H-dibenzo[a,j]xanthenes using nano-TiO 2 as eco-friendly and efficient catalyst is reported. Short reaction times, high yields, a clean process, simple methodology, easy work-up and green conditions are advantages of this protocol  

Rarefied gas flow in micro/nano electro mechanical systems (MEMS/NEMS) does not perform exactly as that in macro-scale devices. The main goal in this study is to investigate mixed subsonic-supersonic flows in micro/nano channels and nozzles and to provide physical descriptions on their behaviors. We use DSMC method as a reliable numerical tool to extend our simulation. It is because the DSMC provides accurate solution for the Boltzmann equations over the entire range of rarefied flow regime or Knudsen numbers. As is known, the appearance of oblique/normal shocks at the inlet of a channel or a nozzle adds to the complexity of internal flow field analyses. We found some very unique physical...