Sharif Digital Repository

Electrochemical water splitting which consists of two half-reactions, namely; the hydrogen evolution reaction (HER) and the oxygen evolution reaction (OER), is an important process in electrochemical energy storage and sustainable production of energy. Therefore, the development of cost-effective and efficient electrocatalysts for water splitting has attracted a lot of interest. In this work, a new nanocomposite was prepared from cobalt diselenide and cerium (IV) oxide derived from calcination of a cerium-based metal-organic framework (Ce-MOF), via hydrothermal and electrodeposition methods. The structure and morphology of synthesized materials were investigated by XRD, FE-SEM, EDX, and BET... 

In this research ,Al-20Si-5Fe-3Cu-1Mg-XMn alloys were produced by gas atomizing and melt spinning processes. Microstructure and growth morphology of powder and ribbons were investigated using optical microscopy , scanning electron microscopy. powders were hot pressed at 400ºC/250Mpa and microstractural variations, mechanical properties were evaluated after consolidation. Results show that relatively high cooling rate in gas-atomized powders lead to refinement of microstructure and formation of semi-equilibrium δ intermetallic phase . As the powder particle size decrease , the growth morphology changes from primary silicon + euthectic to euthectic + primary dendritic aluminum . Mn changed the... 

In the past few years, many research works on the controllable integration of metal nanoparticles and metal-organic frameworks were done, since the obtained composite material shows a synergism effect in catalysis and photocatalysis, drug delivery applications, gas, and energy storage, as well as sensing. For the first time, in this study, we employed template-assisted growth to synthesize Au-HKUST-1 Nanocomposite. XRD analysis entirely confirms that employing this strategy in synthesizing Au-HKUST-1 was wholly successful, and the plasmonic properties of this nanostructure were studied via UV-visible spectroscopy. In the course of synthesis, gold nanoparticles with 70nm diameter were... 

The primary purpose of acidizing operations in the oil and gas industry is to enhance hydrocarbon production. Acidizing has been a common and conventional method for years, especially when production engineers face issues like declining reservoir pressure leading to reduced production rates. Initially, the treatment solution is referred to as matrix acidizing. In acidizing operations, different additives are combined with the acid to control its behavior in the reservoir. These additives may include iron control agents, corrosion inhibitors, friction reducers, and more. Incompatibility among these additives, the acid, and reservoir fluids can lead to severe damage to the reservoir.... 

The goal of this research is the simulation of the annular combustion chamber of the turbine engine utilized by liquid fuel. The achievement to this goal will lead to create numerical tools for parametric study, analysis and combustion chamber designing.For this reason simple geometry has been considered. This simplicity of geometry causes to facilitate in parametric study and decrease in saving time for modeling and meshing. This combustion chamber is a simplified model of engine CF6. In recent study, the k – ε realizable model has been used for turbulence modeling. For non-adiabatic condition, chemical reaction is dissolved by utilizing probability density function along with laminar... 

In this work, the dynamic competition between firms providing internet services is studied. The framework is Markov equilibrium whereby structural parameters are obtained using two-step estimations, allowing for analyzing the situation in case of subsidies for service upgrade. The results show that such subsidy has little effect on the number of firms while increasing the number of fast firms  

During the last few years, the study of urban environment structures is considered as a research field of interest in remote sensing. In satellite observations of the earth's surface, continuous imaging in terms of time and space has caused the remote sensing technique to be proposed as a useful and efficient tool for the analysis of urban areas. Obtaining quantitative spatial information from the urban environment in fields such as determining the height of buildings plays an essential role in urban planning, monitoring damage to buildings, establishing communication bases and digital cities. During the last two decades, the use of Tomosar approach in order to reconstruct the structures of... 

Mobile edge computing (MEC) is a promising technology that aims to resolve cloud computing’s issues by deploying computation resources at the edge of mobile network and in the proximity of users. The advantages of MEC include reduced latency, energy consumption, and load on access and mobile core networks, to name but a few. Despite all the aforementioned advantages, the mobility of mobile network users causes the traditional MEC architecture to suffer from several issues, such as decreased efficiency and frequent service interruption. One of the methods to manage users’ mobility is virtual machine (VM) migration, where the VM containing the user’s task is migrated to somewhere closer to... 

Estimating the price elasticity of gas demand involves complexities depending on the gas market structure and pricing mechanisms in different countries. Distinguishing between supply and demand shocks and block pricing are among the main challenges that can cause endogeneity in elasticity estimates. Iran's domestic gas network, one of the largest and most extensive household gas markets, is divided into five climatic zones based on weather conditions. The pricing steps for these five climates during the five cold months are such that a customer in a warmer climate pays higher prices. Conversely, the pricing steps for the seven warm months are the same for all climates. This policy creates a... 

In this study steady state and dynamic simulation of an NFM extractive distillation unit for seperation of aromatics and non-aromatic components has been carried out. Column output composition obtained with experimental binary coefficients is compared with those obtainded by UNIFAC equation. The results indicate that using UNIFAC for all binrary coefficients results in an unacceptable error in concentration of benzene. If the experimental binary coefficents of benzene with NFM are used and the rest are calculated by UNIFAC equation, the simulation results will be very close to those obtained via experimental binary coefficients. Also it is shown that considering a constant efficiency for all... 

During the brewing process, beer alternately goes through different chemical and biochemical reactions and solid–liquid separation stages. The clarification at the final step of brewing is a highly critical stage when it comes to producing a clear and bright beer. Recently, membrane technology has been successfully used in beer clarification, wherein Kieselguhr (diatomaceous earth) filtration is replaced by cross-flow microfiltration. The most important disadvantages of using microfiltration in clarification of beer is the fouling and flux decline during the process. The phenomenology of fouling mechanisms is still undefined and selection of an appropriate technique for flux enhancement in... 

Different methods can be used to produce reduction gas. One example is using coal. But today there’s a tendency to use natural gas. One way of transforming natural gas to reduction gas is to burn it with gases produced by combustion, such as or vapor; usually a catalyst is used in this method. Another method is burning natural gas directly with oxygen or air. The recent method is of benefit especially in Iran, because of available natural gas resources and avoiding catalyst problems. Designing a burner for this purpose is an important step in reaching this goal. In this project such a burner is designed and manufactured. The burner manufactured in this project burns natural gas with... 

Nowadays, with population growth and vehicle traffic increase, only providing transportation supply couldn’t answer the transportation demand. One of the most important solutions to reduce traffic is transportation demand management (TDM). In this research, the effects of parking pricing and improving public transportation services on private car demand reduction in city center are examined. The data are collected from private cars users in the city center of Isfahan through interviews. By stated preference method, the impacts of parking price and public transit travel time and other related factors were investigated. For this purpose, binary logit, multinomial logit and nested logit models... 

In this study TiO2/SiO2 thin films were prepared by sol-gel method from Tetra isopropylortho Titanate(TIPT) as the principle of TiO2 material with Tera ethoxysilane(TEOS) as the principle of SiO2 material to achieve high scratch-resistant , antibacterial and self-cleaning surface area under the effect of various percentage of SiO2 . Film deposition was carried out using a dip-coating technique and heat-treatment was used at 700ºC to achieve crystalline of films with excellent adherence the of substrate.
The surface morphology of the films has been observed by Scanning Electron Microscope (SEM) and the tribological properties of the surface were investigated by Atomic Force Microscope... 

Industrialization has brought about air pollution which is one of the most important factors threatening human health. The most efficient method to improve air quality include preventing the emission of pollutants by making laws and regulations. In order to set appropriate regulations, there needs to be a correct understanding of the problem. The purpose of this research is to identify such factors and create a correct understnding of the problem in Iran by constructing a Model of Iranian air qulity. The model used in this research, CMAQ is one of the most comprehensive and state of the art models in transport of pollutnts and chemical reactions in the atmosphere. The inputs into CMAQ... 

As mobile multimedia services become popular, it is expected that mobile devices provide more multimedia functions such as real-time video playback, TV watching, and video games. However, real-time video applications running on mobile devices are heavily constrained by their limited computing power, compared to high-end consumer devices. In order to playback a high resolution video on mobile devices, a typical approach would be to fully decode video bitstream into the pixel-domain, and then spatially downscale the decoded frames at a desired resolution. However, due to large computation and memory required for decoding followed by downscaling, this approach is unsuitable for real-time video... 

Free and Open-Source Software (FOSS) is grown rapidly and many researches are conducted to study FOSS developments. The studies aim to help FOSS development by finding bugs, analyzing developers, modeling evolution of software and categorizing them. Finding proper developers or key developers of each group is essential in developing software, recommend developers and assigning bugs to proper developers. Community detection detects groups of nodes having dense connections. The groups represent developers which cooperate closely on developing FOSS. The thesis proposes a method based on evolutionary algorithms and topological analysis to detect communities in open-source software development...