Sharif Digital Repository

Kinetics of oxidation of MgO-C refractories was investigated by shrinking core modeling of the gas-solid reactions taking place during heating the porous materials to the high temperatures. Samples containing 4.5-17 wt pct graphite were isothermally oxidized at 1000-1350°C. Weight loss data was compared with predictions of the model. A mixed 2-stage mechanism comprised of pore diffusion plus boundary layer gas transfer was shown to generally control the oxidation rate. Pore diffusion was however more effective, especially at graphite contents lower than 10 wt pct under forced convection blowing of the air. Model calculations showed that effective gas diffusion coefficients were in the range... 

We investigate the effect of wall roughness on water electrolyte transport characteristics at different temperatures through carbon nanotubes by using nonequilibrium molecular dynamics simulations. Our results reveal that shearing stress and the nominal viscosity increase with ion concentration in corrugated carbon nanotubes (CNTs), in contrast to cases in smooth CNTs. Also, the temperature increase leads to the reduction of shearing stress and the nominal viscosity at moderate degrees of wall roughness. At high degrees of wall roughness, the temperature increase will enhance radial movements and increases resistance against fluid motion. As the fluid velocity increases, the particles do not... 

In this report the important factors affecting the levitation melting of nickel are discussed. The relationship between the temperature of a levitated sample to factors such as coil design, gas flow rate, power input, and sample weight are studied. Different coil designs were investigated and compared. It was found that for satisfactory sustained levitation melting, the sample weight, depending on the material, must be within a particular range. Furthermore, increasing the power input would result in a decrease in the droplet temperature; and increasing the weight of the sample results in an increase in the temperature. The flow rate of a cooling gas has a reverse relationship to the... 

Magnetic nanofiber cellulose (NFC) was selected as a biopolymer surface for the reaction with ferric metformin and a novel nanocatalyst was prepared. This green heterogeneous organometallic catalyst was analyzed by physiochemical techniques. The new metformin drug complex supported on magnetic NFC was used as a powerful and efficient catalyst for the synthesis of functionalized 4H-pyrans derivatives. The antimicrobial activity of the products showed excellent activity against all the bacterial and fungal strains (especially compounds 7q and 6r). © 2022 Taylor & Francis Group, LLC  

Bread scraps with transition metal oxide spinels were utilized to synthesize core–shell magnetic nanocatalyst. The prepared heterogeneous catalyst was characterized using Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), scanning electron microscopy (SEM), Brunauer–Emmett–Teller (BET), thermogravimetric analysis (TGA), and transmission electron microscopy (TEM). This magnetic nanocatalyst opens up a new avenue to introduce a very useful and efficient catalytic system for the one-pot synthesis of tetraketone derivatives via Knoevenagel-Micheal reaction of 1,3 cyclohexanedione and benzaldehyde in ethanol as a green solvent at 50 °C, and one-pot four-component reaction of... 

A lubrication model is used to study dewetting of an evaporating thin film layer over a solid substrate with a nanometer-scale topography. The effects of the geometry of the topography, the contact angle, the film thickness, and the slippage on the dewetting have been studied. Our results reveal that the evaporation enhances the dewetting process and reduces the depinning time over the topography. Also it is shown that the depinning time is inversely proportional to the slippage and increasing the contact angle may considerably reduce the depinning time, while the film thickness increases the depinning time  

We investigate the effect of wall roughness on water electrolyte transport characteristics at different temperatures through carbon nanotubes by using nonequilibrium molecular dynamics simulations. Our results reveal that shearing stress and the nominal viscosity increase with ion concentration in corrugated carbon nanotubes (CNTs), in contrast to cases in smooth CNTs. Also, the temperature increase leads to the reduction of shearing stress and the nominal viscosity at moderate degrees of wall roughness. At high degrees of wall roughness, the temperature increase will enhance radial movements and increases resistance against fluid motion. As the fluid velocity increases, the particles do not... 

We have investigated the "weak chaos" exponent to see if it can be considered as a classification parameter of different sandpile models. Our simulation results show that the (Abelian) BTW sandpile model, the (non-Abelian) Zhang model, and the ("Abelian") Manna model possesses different "weak chaos" exponents, so they may belong to different universality classes. Finally, we show that getting off the critical point destroys this behavior in these models  

The Abelian sandpile model (ASM) is a paradigm of self-organized criticality (SOC) which is related to c ≤ -2 conformal field theory. The conformal fields corresponding to some height clusters have been suggested before. Here we derive the first corrections to such fields, in a field theoretical approach, when the lattice parameter is non-vanishing, and consider them in the presence of a boundary. © 2007 IOP Publishing Ltd  

Using non-equilibrium molecular dynamics simulations, we investigate the effects of nanotube size, mean flow velocity, ion concentration and temperature of an electrolyte water solution on shearing stress and nominal viscosity. It is shown that the distributed electric field arising from the electrolyte water solution has significant influences on fluid properties. Also, the temperature of the solution, which causes thermal movement, affects nanofluidic transport in nanoenvironments. The nominal viscosity and shearing stress increases as the tube diameter increases. When the temperature of solution increases or ion concentration decreases, the shearing stress and nominal viscosity increase.... 

In this paper, we consider several known growth processes with height-dependent noise. This type of noise is interesting from a theoretical standpoint, for example, it paves the way to the derivation of the exact height distribution of the KPZ equation through the Hopf–Cole transformation. In addition, it may have implications for experimental growth processes. Using numerical methods, we observe that adding such a noise to different growth processes, can change their universality class or ruin the scaling laws. In the case of Mullins–Herring equation, a two-fold cross-over is observed. © 2020 Elsevier B.V  

We consider the Coulomb gas model on the upper half-plane with different boundary conditions, namely, Dirichlet, Neumann and mixed. We relate this model to SLE(κ, ρ) theories. We derive a set of conditions connecting the total charge of the Coulomb gas, the boundary charges, the parameters κ and ρ. Also we study a free fermion theory in presence of a boundary and show with the same methods that it would lead to logarithmic boundary changing operators. © Elsevier B.V. All rights reserved  

In this paper we derive the scaling fields in c = -2 conformal field theory associated with weakly allowed clusters in Abelian sandpile model and show a direct relation between the two models. © 2005 Elsevier B.V. All rights reserved  

Formal Loewner evolution is connected to conformal field theory. In this Letter we introduce an extension of Loewner evolution, which consists of two coupled equations and connect the martingales of these equations to the null vectors of logarithmic conformal field theory. © 2004 Elsevier B.V. All rights reserved  

In this study, the homotopy analysis method (HAM) is used to study dynamic pull-in instability in microbeams considering different sources of nonlinearity. Electrostatic actuation, fringing field effect and midplane stretching causes strong nonlinearity in microbeams. In order to investigate dynamic pull-in behavior, using Galerkin's decomposition method, the nonlinear partial differential equation of motion is reduced to a single nonlinear ordinary differential equation. The obtained equation is solved analytically in time domain using HAM. The problem is studied by two separate manners: direct use of HAM and indirect use of HAM in conjunction with He's Modified Lindstedt- Poincaré Method.... 

The present study dealt with the mechanism of competitive adsorption of Sb(III) and Fe(II) ions from a copper-containing aqueous solution on Purolite S957, a commercially available cationic ion-exchange adsorbent. Experiments were conducted using aqueous copper sulfate solutions containing either single or conjoint ions, using both sedentary and batch adsorption techniques to ascertain the sensitivity of the adsorption process to variation in pH, mass of resin, contact time, and temperature as well as establishing the optimal range of variables for maximum ion removal. The data from single ion adsorption tests were fitted by non-linear regression techniques to Henry, Langmuir, Freundlich,... 

The Persian Gulf is one of the aquatic ecosystems which has recently been faced with different pollutions. Cooling water discharges due to various industries such as power plants can cause important disorders on the present ecosystem balance and on aquatic creatures because of their high temperature. Thermal pollution leads to their migration, creates a potential for new coming species which in turn can thoroughly change the marine ecosystem feature. In this research, thermal pollution due to the Bandar Abbas Thermal Power Plant (BATP) development plan was modeled using MIKE21 software. In order to avoid a decrease in the power plant efficiency in the development plan, the distance between... 

The Persian Gulf is one of the aquatic ecosystems which has recently faced with different pollutions. Cooling water discharges due to various industries such as power plants can cause important disorders on present ecosystem balance because of its high temperature. Obviously, due to thermal pollution, a great number of aquatic creatures face with a new situation that they can not tolerate. Thermal pollution leads to their migration, creates a potential for new coming species which in turn can thoroughly change the marine ecosystem feature. The other impacts of this phenomenon are: disorders in reproduction, nourishment and other biological habits. In this research, thermal pollution due to... 

The left-hand side of the auroral hiss emission observed by Galileo has a frequency time profile shaped very similar to the funnel shape observed in the Earth's auroral region. This close similarity indicates that we can use the theory of whistler-mode propagation near the resonance cone to locate the emission source. The general characteristics of the whistler mode are discussed. Then the position of the emission source is investigated using a geometrical method that takes into account the trajectory of Galileo. Initially a point source is assumed. Then the possibility of a sheet source aligned along the magnetic field lines which are tangent to the surface of Io is investigated. Both types... 

Correlations between electrical and thermal conduction in polymer composites are blurred due to the complex contribution of charge and heat carriers at the nanoscale junctions of filler particles. Conflicting reports on the lack or existence of thermal percolation in polymer composites have made it the subject of great controversy for decades. Here, we develop a generalized percolation framework that describes both electrical and thermal conductivity within a remarkably wide range of filler-to-matrix conductivity ratios (Y f / Y m), covering 20 orders of magnitude. Our unified theory provides a genuine classification of electrical conductivity with typical Y f / Y m ≥ 10 10 as...