Sharif Digital Repository

We investigate the effect of wall roughness on water electrolyte transport characteristics at different temperatures through carbon nanotubes by using nonequilibrium molecular dynamics simulations. Our results reveal that shearing stress and the nominal viscosity increase with ion concentration in corrugated carbon nanotubes (CNTs), in contrast to cases in smooth CNTs. Also, the temperature increase leads to the reduction of shearing stress and the nominal viscosity at moderate degrees of wall roughness. At high degrees of wall roughness, the temperature increase will enhance radial movements and increases resistance against fluid motion. As the fluid velocity increases, the particles do not... 

We investigate the effect of wall roughness on water electrolyte transport characteristics at different temperatures through carbon nanotubes by using nonequilibrium molecular dynamics simulations. Our results reveal that shearing stress and the nominal viscosity increase with ion concentration in corrugated carbon nanotubes (CNTs), in contrast to cases in smooth CNTs. Also, the temperature increase leads to the reduction of shearing stress and the nominal viscosity at moderate degrees of wall roughness. At high degrees of wall roughness, the temperature increase will enhance radial movements and increases resistance against fluid motion. As the fluid velocity increases, the particles do not... 

A lubrication model is used to study dewetting of an evaporating thin film layer over a solid substrate with a nanometer-scale topography. The effects of the geometry of the topography, the contact angle, the film thickness, and the slippage on the dewetting have been studied. Our results reveal that the evaporation enhances the dewetting process and reduces the depinning time over the topography. Also it is shown that the depinning time is inversely proportional to the slippage and increasing the contact angle may considerably reduce the depinning time, while the film thickness increases the depinning time  

Using non-equilibrium molecular dynamics simulations, we investigate the effects of nanotube size, mean flow velocity, ion concentration and temperature of an electrolyte water solution on shearing stress and nominal viscosity. It is shown that the distributed electric field arising from the electrolyte water solution has significant influences on fluid properties. Also, the temperature of the solution, which causes thermal movement, affects nanofluidic transport in nanoenvironments. The nominal viscosity and shearing stress increases as the tube diameter increases. When the temperature of solution increases or ion concentration decreases, the shearing stress and nominal viscosity increase.... 

Environmental pollutions with heavy metals pose serious health and ecological risks. Sabzevar in the northeast of Iran has natural chromic mines and then chromium-polluted soils and groundwater. In the present work, the metal-tolerant bacterial strain KR2 was identified as Shewanella sp. following 16S rDNA gene sequence analysis. Bioremediation ability of isolated bacterial from agricultural soils that irrigated by groundwater, Shewanella sp., was evaluated for uptaking of chromium with varying Cr(VI) concentrations from 50 to 500 ppm in aerobic conditions (pH 7.0, 37 °C). The Shewanella sp. strain KR2 showed an obvious heavy metal tolerant in the wide range of heavy metals including: Cr6+,... 

We study the quantum nonlinear planar Hall effect in bilayer graphene under a steady in-plane magnetic field. When time-reversal symmetry is broken by the magnetic field, a charge current occurs in the second-order response to an external electric field as a result of the Berry curvature dipole in momentum space. We show that a nonlinear planar Hall effect originating from the anomalous velocity is caused by an orbital effect of an in-plane magnetic field on electrons in bilayer graphene in the complete absence of spin-orbit coupling. Taking into account the symmetry analysis, we derive the dominant dependence of the Berry curvature dipole moment on the magnetic field components. Moreover,... 

Despite various applications of hydrogels, they have poor gel strength and low resistance against crack propagation which lead to the limitation of their applications. For overcoming this inherent weakness, the current study has focused on the simultaneous utilization of interpenetrating polymer network (IPN) structure and nanocomposite hydrogels. It is known that IPN and nanocomposite gels can improve gel strength. The combination of IPN and nanocomposite structure was developed in hydrogels for improving gel strength. For this purpose, bentonite was successfully modified with a cationic surfactant, (3-methacrylamidopropyl) trimethyl ammonium chloride (MAPTAC), as intercalate, and... 

Despite the various uses of hydrogels, one of their weaknesses is the poor gel strength. To overcome this restriction, the current study has focused on simultaneously employing an interpenetrating polymer network (IPN) structure and nanocomposite hydrogels. Through this approach, the influence of nanofiller in the single network and IPN hydrogel properties was also studied in detail. For this purpose, a novel full interpenetrating polymer network (IPN) hydrogel nanocomposite based on 2-acrylamido-2-methylpropane sulfonic acid (AMPS)/acrylic acid (AA)–sodium acrylate (AANa) was synthesized in two steps through a facile solution polymerization with incorporation of modified bentonite (MBE) as... 

The left-hand side of the auroral hiss emission observed by Galileo has a frequency time profile shaped very similar to the funnel shape observed in the Earth's auroral region. This close similarity indicates that we can use the theory of whistler-mode propagation near the resonance cone to locate the emission source. The general characteristics of the whistler mode are discussed. Then the position of the emission source is investigated using a geometrical method that takes into account the trajectory of Galileo. Initially a point source is assumed. Then the possibility of a sheet source aligned along the magnetic field lines which are tangent to the surface of Io is investigated. Both types... 

The present article deals with super-swelling behavior of crosslinked homopolymer of 2-acrylamido-2-methylpropane sulfonic acid, poly(AMPS), in binary mixtures of dimethyl sulfoxide (DMSO) and various polar solvents including water, mono-, and polyhydric alcohols, and amide solvents such as N-methyl pyrrolidone. Extraordinary phase transition sequences including a new unusual swelling phenomenon, referred to as "overentrant" swelling, was observed for this polymeric organogel in the solvent/DMSO mixtures. The swelling behaviors were preliminarily explained based on the major interactions involved in the solvation process and dielectric constant of the swelling media. It was established that... 

Alcohol-specific superabsorbing gels (superalcogels) based on non-neutralized acrylic acid (AA, 60-94 mol%) and 2-acrylamido-2-methylpropane sulfonic acid (AMPS) were prepared via solution polymerization in water. Polyethylene glycol dimethacrylate and potassium persulfate were used as crosslinker and initiator, respectively. Characterization of samples was performed using FTIR, 1H-NMR and thermomechanical analyses. Glass transition temperature and modulus of dried samples were found to be directly changed with their AA content. The gels exhibited enormous ability for absorbing and retaining a variety of mono- and poly-hydric alcohols. For example, in lieu of one gram of a typical sample... 

Homopolymer hydrogel of 2-acrylamido-2-methylpropane sulfonic acid (AMPS) and its nanocomposite counterpart were prepared to study their swelling properties. The hydrogels showed ability to absorb and retain electrolytes as well as binary mixtures of water and organic solvents (i.e., methanol, ethanol, acetone, ethylene glycol (EG), polyethylene glycol, N-methyl-2-pyrrolidone (NMP), and dimethylsulfoxide (DMSO). The nanocomposite gel exhibited lower swelling in all solvent compositions in comparison with non-composite gel. Unlike conventional acrylic acid-based hydrogels, the poly(AMPS) gels showed superabsorbing capacity in pure ethanol, methanol, EG, DMSO and NMP. Meanwhile, swelling... 

We have investigated the "weak chaos" exponent to see if it can be considered as a classification parameter of different sandpile models. Our simulation results show that the (Abelian) BTW sandpile model, the (non-Abelian) Zhang model, and the ("Abelian") Manna model possesses different "weak chaos" exponents, so they may belong to different universality classes. Finally, we show that getting off the critical point destroys this behavior in these models  

In this paper we investigate the effect of the number of dissipative sites in an Abelian sandpile model. The dissipative sites are considered to be in the bulk rather than in the boundary. In such systems, statistics of avalanches smaller than a certain size obey a power law. We have seen that the exponents associated with these power law behaviors change slightly as the number of dissipative sites is decreased. We have found that the zero dissipation limits of these exponents are independent of size. Therefore we suggest that the previously-seen dependence of the exponent on the system size is because of the number of dissipative sites rather than the system size. Also it is observed that... 

In this paper we consider the Bak, Tang, and Wiesenfeld (BTW) sand-pile model with local violation of conservation through annealed and quenched disorder. We have observed that the probability distribution functions of avalanches have two distinct exponents, one of which is associated with the usual BTW model and another one which we propose to belong to a new fixed point; that is, a crossover from the original BTW fixed point to a new fixed point is observed. Through field theoretic calculations, we show that such a perturbation is relevant and takes the system to a new fixed point  

In this study, influences of intermolecular forces on the dynamic pull-in instability of electrostatically actuated beams are investigated. The effects of midplane stretching, electrostatic actuation, fringing fields, and intermolecular forces are considered. The boundary conditions of the beams are clamped-free and clamped-clamped. A finite-element model is developed to discretize the governing equations, and Newmark time discretization is then employed to solve the discretized equations. The static pull-in instability is investigated to validate the model. Finally, dynamic pull-in instability of cantilevers and double-clamped beams are studied considering the Casimir and van der Waals...