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Development of Particulate Zinc-Iron/PTFE Composite and Nanocomposite Coatings Using Electrodeposition
, M.Sc. Thesis Sharif University of Technology ; Ghorbani, Mohammad (Supervisor)
Abstract
Electrodeposition is an old, well known and conventional science surface modification method to improve the surface characteristics, decorative and functional, of a wide variety of materials. This science is considered in nanotechnology as a bottom-up method for fabrication of one, two and three-dimensional nanomaterials. A great variety of secondary components can be added to plating baths resulting in metallic matrix composite and nanocomposite coatings production. Low amounts of iron addition for alloying zinc coatings, significantly increases the corrosion resistance of this generally used metal economically. Superhydrophobic coatings on metallic substrates have shown, during the past...
Copper recovery from reverberatory furnace flue dust
, Article International Journal of Mineral Processing ; Volume 157 , 2016 , Pages 205-209 ; 03017516 (ISSN) ; Askari, M ; Sharif University of Technology
Elsevier, B. V
2016
Abstract
In this study, leaching of reverberatory furnace dust at Sarcheshmeh was investigated in H2SO4-O3 medium. Response surface methodology based on central composite face-centered design (RSM-CCF) was applied to optimize the operating parameters. The optimal conditions to achieve the principle objectives of maximizing copper dissolution and minimizing iron dissolution from dust were identified to be a temperature of 30 °C, a leaching time of 3 h, an initial pH of 0.5, a pulp density of 20%, and an ozone flow rate of 1 g/h. Under the optimum conditions, the copper and iron concentrations in the leaching solution were found to be 27.11 and 0.90 g/L, respectively. The results showed that selective...
Thermodynamic optimization of design variables and heat exchangers layout in HRSGs for CCGT, using genetic algorithm
, Article Applied Thermal Engineering ; Volume 29, Issue 2-3 , 2009 , Pages 290-299 ; 13594311 (ISSN) ; Shayegan, J ; Sharif University of Technology
2009
Abstract
The heat recovery steam generator (HRSG) is one of the few equipments that are custom made for combined cycle power plants, and any change in its design affects all performance parameters of a steam cycle directly. Thus providing an optimization tool to optimize its design parameters and the layout of its heat exchangers is of great importance. A new method is introduced for modeling a steam cycle in advanced combined cycles by organizing non-linear equations and their simultaneous solutions by use of the hybrid Newton methods in this article. Thereafter, optimal thermodynamic performance conditions for HRSGs are calculated with the help of the genetic algorithm. In the conclusion, the...
Copper Selective Leaching from Sarcheshmeh Reverberatory Furnace Dusts
, M.Sc. Thesis Sharif University of Technology ; Askari, Masoud (Supervisor)
Abstract
In this study, leaching of Sarcheshmeh Reverberatory Furnace Dust was investigated in the H2SO4-O3 media. Response surface methodology based on central composite face-centered design (RSM-CCF), was applied to optimize the operating parameters. The optimum conditions to obtain the main goal of maximum copper and minimum iron dissolution from dust were identified to be temperature of 30˚C, leaching time of 3hr, initial pH of 0.5, pulp density of 20% and ozone flow rate of 1g/h. The copper and iron concentrations of leaching solution were found to be 27.11 and 0.89983 g/L under the optimum conditions, respectively. The results showed that selective copper extraction from the dust could be...
Study and optimization of amino acid extraction by emulsion liquid membrane
, Article Separation Science and Technology ; Volume 43, Issue 11-12 , 2008 , Pages 3075-3096 ; 01496395 (ISSN) ; Alemzadeh, I ; Vossoughi, M ; Sharif University of Technology
2008
Abstract
A batch extraction of an essential amino acid, phenylalanine, from an aqueous solution of different concentrations by an Emulsion Liquid Membrane (ELM) was developed using D2EHPA as a cationic carrier, Span 80 as the surfactant, paraffin, and kerosene as the diluents, and HCl as the internal electrolyte. All effective parameters such as the initial pH of the aqueous external phase, the electrolyte concentration in the aqueous internal phase, carrier, and surfactant concentration in the emulsion, the volume ratio of the organic to aqueous internal phase (Roi), the volume ratio of the W/O emulsion to the aqueous external phase (Rew) and time were examined and optimized using the Taguchi...
Reactive compensation techniques for increasing loadability of long primary distribution lines
, Article 37th Annual North American Power Symposium, 2005, Ames, IA, 23 October 2005 through 25 October 2005 ; Volume 2005 , 2005 , Pages 233-237 ; 0780392558 (ISBN); 9780780392557 (ISBN) ; Stefopoulos, G. K ; Parniani, M ; Sharif University of Technology
2005
Abstract
Electric networks often consist of remote cities or villages with low population densities, which consume a considerably small amount of energy. This can be in the order of a few megawatts for places that are up to 100 km away from the source. Typical uncompensated primary distribution lines are not an effective option for these situations, since line loadability drastically decreases as the line length is increased. Increasing the voltage level, on the other hand, is not cost effective. This paper investigates different reactive compensation techniques for increasing the loadability of these lines. Effect of series capacitors, shunt capacitors and voltage regulating transformers in such...
Analyzing and modeling of a new resonance inverter for low power vehicular application
, Article PECon 2012 - 2012 IEEE International Conference on Power and Energy ; 2012 , Pages 576-581 ; 9781467350198 (ISBN) ; Keipour, A ; Sudi, Z ; Moallemi, M ; Hajihosseinlu, A ; Sharif University of Technology
2012
Abstract
In this paper we proposed a novel inverter to convert a DC voltage to a desired AC voltage. This inverter is designed for variable inductive loads and low output power applications. We proposed a novel simple PWM method which enables the inverter to keep the output current at six times more than the rated output current, without reducing output voltage value. In addition, based on a simple use of resonance in the circuit, the new inverter can raise the output voltage to extremely high amplitude for a relatively short time. These characteristics make the proposed inverter is useful for some industrial applications such as electrical vehicle. The new configuration of the circuit consists of a...
Effect of material properties on the mechanical performance of nitinol esophageal stent: finite element analysis [electronic resource]
, Article Materials Science Forum ; Volumes 773 - 774, 2014, 9-17 ; Sadrnezhaad, K ; Kokabi, H. A ; Razani, M ; Mohagheghi, A. H ; Sharif University of Technology
Abstract
Stent placement has been a main approach to treat gastrointestinal diseases during past decade. Nitinol superelastic stents have been considered as a solution to such difficulties as restenosis after implantation, low twisting ability, inadequate radial mechanical strength and inappropriate dynamic behaviors associated with the ducts. In this paper, effects of Af temperatures on mechanical performance of z-shaped Nitinol wire stent under crimping test for clinical applications are investigated by finite element simulation. Having 60% crimping and high radial resistive strength, favorable superelastic behaviors are attained at Af temperature of 22°C. The performance of the stent is seen to be...
A novel control technique for Power Factor Correction in SEPIC converter utilizing input/output voltage waveforms sampling
, Article PECon 2012 - 2012 IEEE International Conference on Power and Energy ; 2012 , Pages 268-273 ; 9781467350198 (ISBN) ; Sudi, Z ; Mohagheghi, E ; Lakmehsari, A. H ; Hajihosseinlu, A ; Sharif University of Technology
2012
Abstract
In this study, a simple and novel control technique for Power Factor Correction (PFC) is introduced, which is a SEPIC-based (Single-ended Primary-inductor Converter based) rectifier with high input power factor. Operation of the proposed method is based on sampling of input and output voltages in SEPIC rectifier. Using samples of input and output voltage, this control system makes the input current to follow a sinusoidal path. As a result, the line current?'s Total Harmonic Distortion (THD) is reduced and the input power factor is improved. This paper also compares the new method with the conventional control method for the power factor correction. In order to examine the proposed control...
Synthesize of Graphene Nanoribbons with a Non-Zero Energy Band Gap for Inactivation of Alive Cells Using Infrared Irradiation
, M.Sc. Thesis Sharif University of Technology ; Akhavan, Omid (Supervisor)
Abstract
Graphene is a one layer atom thickness and zero energy gap so for using it in nano electronic and transistors baised on graphene it's energy gap should be opened.one of the methods for opening graphene band gap is creating nano scale boundaries or synthesize graphene nanoribbons. One of the new methods for graphene nanoribbon synthesize is longitudinal opening of carbon nanotube. In this thesis graphene nanoribbons synthesize with this method and analyze with AFM and Raman spectroscopy. Carbon nanotubes also have energy gap and IR absorption recently they used for living cell destruction. In this thesis we synthesize graphene nanoribbons and analyzing their optical absorption and use it for...
Fabrication of Graphene/TiO2 Nanowalls as Visible Lights Photocatalysts
, M.Sc. Thesis Sharif University of Technology ; Akhavan, Omid (Supervisor)
Abstract
TiO2 is known as a photocatalyst in near UV-Visible light region with better efficiency compared to other semiconductor photocatalysts. Many attempts have been done to increase the efficiency of this photocatalyst. also, application of 2D carbon nanostructures namely graphene for increasing the photocatalytic activity of TiO2 has shown positive results.
In this research, we first synthesized Graphene Oxide (GO) suspension by exfolation of graphite oxide suspension. then we fabricated TiO2 thin films on glass substrates by so-called sol-gel method. finally we fabricate Graphene Oxide/TiO2 nanowalls composite films as a photocatalyst in visible light. X-ray photoelectron spectroscopy...
In this research, we first synthesized Graphene Oxide (GO) suspension by exfolation of graphite oxide suspension. then we fabricated TiO2 thin films on glass substrates by so-called sol-gel method. finally we fabricate Graphene Oxide/TiO2 nanowalls composite films as a photocatalyst in visible light. X-ray photoelectron spectroscopy...
Fabrication of Graphene-WO3 Nanocomposites as Photocatalyst in the Visible Light Region
, M.Sc. Thesis Sharif University of Technology ; Akhavan, Omid (Supervisor)
Abstract
WO3 is known as a photocatalyst in the visible light region, but with lower efficiency compared to more interesting semiconductor photocatalysts such as TiO2 and ZnO. Many attempts have been done to increase the efficiency of this photocatalyst by incorporating metal and metal oxide nanoparticles or recently carbon nanotubes.On the other hand, application of graphene, as an unrolled carbon nanotube, for increasing the photocatalytic activity of TiO2 and ZnO has shown positive results. Furthermore, it was reported that such semiconductor photocatalysts (and very recently WO3) can photocatalytically reduce the chemically exfoliated graphene oxide sheets under UV-vis irradiation.
In this...
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Synthesis of Graphene Nanosheets for Stem Cells Applications
, M.Sc. Thesis Sharif University of Technology ; Akhavan, Omid (Supervisor)
Abstract
Graphene nanogrids fabricated by graphene nanoribbons obtained through oxidative unzipping of multi-walled carbon nanotubes, used as two-dimensional selective templates for accelerated differentiation of human mesenchymal stem cells (hMSCs), isolated from umbilical cord blood, into osteogenic lineage. The biocompatible and hydrophilic graphene nanogrids showed high actin cytoskeleton proliferations that coinciding with patterns of the nanogrids. The amounts of proliferations found are slightly better than proliferation on hydrophilic graphene oxide (GO) sheets, and significantly higher than non-uniform proliferations on hydrophobic reduced graphene oxide (rGO) sheets and polydimethylsiloxane...
Identifying the risks of Iranian Knowledge BasedFirms Using Fault Tree Analysis (FTA)
, M.Sc. Thesis Sharif University of Technology ; Fattahi, Omid (Supervisor)
Abstract
Knowledge Based Firms are considered to be important for the economic development of a country in regards to both employment growth and innovative activity. The latter is believed to contribute significantly to the increase in productivity and therefore the competitiveness of Iran’s economy. This study contributes to the above literature by investigating the factors that are believed to treat the growth of such firms in Iran. The purpose of this study is to identify functional risks of vital signs monitors via Fault Tree Analysis (FTA) method to use as a guide for manufacturers to identify and control hazards. Therefore, 30 knowledge based firms were selected as sample. Then, based on a...
Synthesis of Graphene from Waste by Chemical Exfoliation and Study of It’s Physical Characteristics
, M.Sc. Thesis Sharif University of Technology ; Akhavan, Omid (Supervisor)
Abstract
One atom thick layer of pure carbon in bonded and hexagonal lattice is named graphene. graphene has unique mechanical, optical, thermal and electrical properties and because of these properties has grabbed attention. graphene has been made from high pure graphite by different methods such as CVD(chemical vapor deposition) , chemical exfoliation , micromechanical cleavage and colloidal suspension. through these methods, green methods for synthesis of graphene, using eco-friendly reductants during synthesis of graphene instead of hydrazine and recently using waste(not graphite) are attractive for synthesis of graphene. Following this idea , a group has produced graphene from wastes such as...
The Use of Hydrogen Rich Water for Synthesis of Hydrogenized Graphene and Investigation of Its Properties
, M.Sc. Thesis Sharif University of Technology ; Akhavan, Omid (Supervisor)
Abstract
Graphene is a two dimensional lattice which is created from carbon atoms. Having special feature, it has such various medical usage, for example in diagnosing and treating cancer. Adding a particular factor to graphene could improve their efficiency. In comparis on with graphene itself, graphene oxide and reduced graphene oxide are much more successful in diagnosing and treating than others because of their higher hygroscopic. Recent studies state that hydrogenized combinations including hydrogenized graphene show desired results. Due to its higher hygroscopic and the possibility of adherence to the cells, hydrogenized graphene could be very effective in diagnosing and treating the sarcomas....
A Meta Heuristic Approach for Design of a Network System in Mass Customization
, M.Sc. Thesis Sharif University of Technology ; Fattahi, Omid (Supervisor)
Abstract
This study discusses about mass customization and optimization of supply network in which both goal considering to set the flow of raw material and final product to satisfy the customer demand. The mass customization is more important concept in this study, so that this goal is placed to the first objective. In this research, the model which contained both goal is presented. The model focus on mass customization and try to satisfy various products demand, which constitute 3 kind of speed demands. Each product can satisfy in 3 way: fast, normal, slow.In the first model the new approach present in which the speed affects all of supplying, manufacturing and distributing system. The system try...
Synthesis of Graphene Oxide and Study of its Fluorescence Properties
, M.Sc. Thesis Sharif University of Technology ; Akhavan, Omid (Supervisor)
Abstract
Graphene oxide is a single sheet of Carbon atoms which has been arranged on a two-dimensional honeycomb lattice. Functional groups such as epoxy, carboxyl and carbonyl are located on basal plane and at the edges of graphene oxide and they localize electrons on the surface of graphene oxide and open band gap in its band structure. Pure graphene has zero band gap, so existence of fluorescence properties is unlikely; but graphene oxide has fluorescence properties due to band gap in its band structure. Fluorescence properties of graphene have been used in live cell imaging and drug delivery, so study and increasing of fluorescence properties is significantly important. The purpose of this...
A Novel Reliability Model for Information Technology Web services
, M.Sc. Thesis Sharif University of Technology ; Fatahi Valilai, Omid (Supervisor)
Abstract
The Internet is often used for communication-based applications such as online banking, stock trading, and shopping where service interruption is unacceptable. Thus, analysis of the impact of the failures of hardware, software, and related services’ performance quality of the service provided to users is of importance to designers and managers in these functions. In this study, we developed a strategy to the design of a dynamic combination of file servers with the aim of providing reliability and SLA. At first, we examine the reasons for the violation of service level in file host services and datacenters, and then we introduce the criteria to measure the violation of service level on the...
Development of a novel solution to enable integration and interoperability for cloud manufacturing
, Article 6th International Conference on Changeable, September 2016 through 6 September 2016 ; Volume 52 , 2016 , Pages 6-11 ; 22128271 (ISSN) ; Fatahi Valilai, Omid ; Sharif University of Technology
Elsevier B. V
2016
Abstract
Nowadays, manufacturing enterprises have been faced with a globalized competitive environment. In this fierce condition, Cloud Manufacturing paradigm emerged as a promising concept for competition. It provides effective solutions and tools for manufacturing enterprises to collaborate in globalized market. The revolution that Cloud Manufacturing has created is based on the redefinition of the classic methods to those which are appropriate for todays' modern and globalized manufacturing environments. In parallel with cloud-based revolution, the expansion of internet-based technologies has been started. These technologies previously have been applied in many fields and resulted in...