Sharif Digital Repository

Separation of particles and cells is one of the most important and practical methods in fields such as biomedicine, medicine and industry. In microfluidics There are various methods for particles and cells separation According to the source of them, they can be categorised as active and passive techniques. Active techniques rely on an external force field. The most important advantage of this method is controlling the force on the particles during the experiment. However, the flow speed is always limited because particles must be exposed to the outer force field for sufficient duration to achieve effective functionality. passive techniques depend entirely on the channel geometry or intrinsic... 

In this work hydrometallurgical route for processing spent commercial catalysts (Co/Al2O3) are investigated for leaching the Cobalt component. The used catalysts were initially pre-oxidized at 500 °C and 5 h in order to eliminate coke and other volatile species present. Pre-oxidized catalysts were dissolved in solvents such as H2SO4, HNO3, HCl and H2O at 80-90 °C, and the remaining residues separated from the solution. These experiments were performed at different concentrations, presence and absence H2O2 solution. Also effect of reflux on leaching process investigated. The result show the yield of the pre-oxidized catalysts extracted with highly concentration of extractant is higher than... 

Nowadays internal combustion engines play an important role in the power generation as well as transportation fields all over the world. By using the turbocharger in internal combustion engine, more power is obtained in compare with aspirated engine having the same size, which is limited for gasoline engines. In this research, by a three-zone computer simulation code and experimental tests, the power boost limitations of the gasoline turbocharged engine are investigated. The results of single cylinder aspirated gasoline engine tests are used for validation the natural aspirated part of the code. For validating the turbocharged engine simulation, the results of a four cylinders gasoline... 

Electroosmosis is the predominant mechanism for flow generation in lab-on-a-chip devices. These microfluidic devices are microscale laboratories on a microchip that can perform clinical diagnoses. Since most biofluids encountered in these devices are considered to be non-Newtonian and the cross section of microchannels in these devices is close to a rectangular shape, In this study, the hydrodynamically and thermally fully developed combined electroosmotically and pressure driven flow of power-law fluids in rectangular microchannels is analyzed. The governing equations are first made dimensionless and then transformed into new ones based on the computational parameters which provide mesh... 

Gas pollutants are included volatile inorganic compositions and odorous materials, which are harmful and dangerous for environment and human health. There are several methods for removing gas pollutants such as physical, chemical and biological methods. In this work, we discuss about ethyl-mercaptan adsorption in LPG by ZSM-5 zeolite and in use of micro systems (micro channels). This work is also concerned about micro channel coating by ZSM-5 and NaY zeolites on glass and the method of coating with (3-Chloropropyl) trimethoxysilane linker. After selecting the appropriate method for zeolite coating, we proceed to micro channel coating. In this research, four different designs of micro channel... 

For designing a unit operation, knowledge about physical properties is essential. This is attained either by direct measurement, which needs spending time and cost or, using proposed correlations. This project is subjected to theoretical analysis of viscosity as the most important rheological property of dilute suspensions of microgels, or in other words colloidal suspensions of porous spheres. They are applied in drug delivery, enhanced oil recovery, synthesis of catalyst and adsorption of heavy metal ions from aqueous systems for water purification purposes. In dilute suspensions particles are faraway from each other and there is no interaction between them therefore, it is better to... 

The purpose of this study is to study heterogeneous nanocatalysts for the production of biofuels by the method of exchange of styrene using oil and methanol as a fossil fuel alternative. Preparation of nanocatalysts, performing characteristic tests and investigating the reaction in different operating conditions in the batch reactor has already been studied. Therefore, in this study, the production of biodiesel fuel using the trans-esterification of canola oil with nanocatalysts in the micro-reactor reactor will be discussed. Previously, a heterogeneous catalyst (lithium based on calcium-lanthanum) was constructed using a co-incineration method and a wet inoculum, and as active and stable... 

% of human blood makes up of plasma, that this plasma is a rich source of proteins that can be used as biomarkers for a variety of clinical diseases and laboratory research, therefore, it is necessary that the plasma be separate by a high purity percentage. Using a centrifuge It is a common method used to separate plasma from blood, but because it requires large equipment and a large volume of blood, as well as stress caused by centrifugal force, increases the probability of damage to the biomarkers, so it has been tried today that Use methods that are easy to transport and require a small amount of blood. The idea of using the microfluidic device has been put forward for the purpose of... 

Laufer and Hulstijn (2001) proposed the Task-Induced Involvement Load Hypothesis stating that in the retention of new words in an incidental context, tasks with higher involvement load will be more effective than tasks with lower involvement load. The present study aimed to examine whether the retention of vocabulary is enhanced with an increase in the amount of task-induced involvement load in an intentional learning environment. Moreover, it was investigated whether proficiency level of learners had a role in the effectiveness of the vocabulary tasks with different involvement loads. Four groups of university students, male and female, participated in the study. They were given a TOEFL... 

Self-regulated learning, though having swept educational psychology's literature like a tidal wave (Boekaerts, 1999), and also, compared to other constructs such as metacognition and learning strategies, has remained comparatively uncharted in L2 research. One preliminary step to chart this concept is to develop questionnaires for it. With these and other things in mind, the principal purpose of this study was to develop a questionnaire in English and Persian to measure self-regulated language learning capacity and behavior of Iranian EFL learners. The development of the questionnaire was guided by two pilots (412 participants), content validation through expert judgment, cognitive... 

Regardless of the extensive research on different aspects of vocabulary and the great emphasis that leading scholars (Meara, 1996; Nation, 990; Read, 1988) placed on the significance of the number of words a learner knows as a substantial component in language learning and vocabulary learning, few investigations have been conducted regarding the size of the vocabulary each language learner knows (Nation, 2012). In addition, Nation (2012) debates the need to combine modern technology and language testing. Therefore, it is necessary to provide innovative methods of testing this knowledge. The present study developed the Computerized Adaptive Test (CAT) of Nation and Beglar’s (2007) Vocabulary... 

A power transmission system includes transmission lines that are interconnected for economic and security reasons. Power systems are often prone to faults at the transmission level, since transmission lines are spread over vast geographical areas. Being the most serious events in power systems, blackouts are often initiated by a fault and a sequence of events afterward leads to partial or complete power outage. In this condition, fault diagnosis is the first step for power system restoration. In this research work, a new approach utilizing impedance-based fault location is introduced for fault diagnosis. By developing wide-area measurements in the context of smart grids, accurate... 

Internet of Things (IoT) is one of the most emerging fields in the computer science context. It is predicted that more than 9 billion devices will be connected to IoT networks by 2025. Considering the specifications of IoT devices such as low battery capacity and small memory, these networks face major challenges in energy consumption and reliability. One of the most important elements which have an indisputable effect on network efficiency is routing protocol. In this manner, IETF presented RPL in 2012. It is designed to create a robust network among IoT devices.Although RPL performs well in static networks, it is not designed originally for mobile networks and it has serious flaws in that... 

In conventional method of modeling and design of structures it is assumed that structures are fixedly supported, however, this assumption is generally far from reality; because, not only the majority of buildings’ bases are not stiff enough to suppose them rigid, but also if their foundations are shallow there exist no piles underneath them, they may separate from their bases – the event which is called foundation uplift. Although according to past studies permission of foundation uplift as well as incorporation of base flexibility may markedly affect any structure’s dynamic response, is spite of about half a century which has elapsed since the beginning of these studies, it seems that still... 

First studies in internal combustion engines have focused on increasing engine power and efficiency, reducing engine volume and improving fuel quality. However, nowadays most studies are concentrated on decreasing exhaust emissions and usage of regenerative fuels while maintaining engine size, efficiency and power. Surveying fuel type in direct injection engines, requires investigation of microscopic and macroscopic spray characteristics including spray tip penetration, spray cone angle, spray area and sauter mean diameter, since these parameters determine air-fuel mixture quality. In this study, spray of ethanol as a regenerative fuel that reduces emissions such as NOx and CO is... 

Recent stringent HC and CO emission regulations are because of increasing consciousness of the perilous influences of exhaust emissions. The chief attempt to pass the standards is to decrease the emissions during cold-start, due to catalytic converters are not efficient until they arrive a light-off temperature. It has been discovered that 50% to 80% of the controlled HC and CO emissions are sent out from tailpipe of automotive during the cold-start. Therefore, in order to minimize the cold-start emissions and fast light-off of catalytic converters, it is important to understand the catalytic converter characteristics and techniques for rapid warm-up catalyst. This thesis describes a... 

The number of operating vehicles has increased in recent years and as a result global pollutants have widely spread. Therefore, the regulations on the vehicle exhaust emissions have become much stricter. For an automobile to pass the emission tests successfully an accurate calibration of the ECU tables is needed, especially the tables which have direct impact on the amount of pollutant emissions. To achieve the optimum performance of the catalyst existing in the exhaust system of the engine, the fuel/air ratio must have nearly stoichiometric value. The present research studies the ECU strategies for implementing this objective by appropriate management and control of catalyst and oxygen... 

A 3-D CFD model was developed to study effects of early/late intake valves opening/closing on flow field characteristics in the Intake Manifold (IM) of a spark-ignited gasoline 1.5 Litre, 4-cylinder engine. The main task of IM is to prepare essential air for combustion process into cylinder which should distribute air to total runners of IM properly. In this modeling, combustion process and valve behaviors and how to pass fluid flows through intake valves are simulated separately and they are added to it.HyperMesh, Fluent, GT-Power, and MATLAB were used to create a mathematical model on the geometries of IM in TIBA engine, one National Engine of Iran, obtained from MEGA motor Company. The... 

The aqueous phase reforming (APR) of glycerol is an attractive yet challenging pathway to convert abundant biomass into value added hydrogen. Pt catalysts have received attention due to their ability to produce hydrogen-rich gas under APR conditions. In this work, the conversion of glycerol into hydrogen is demonstrated using Pt0.05CexZr0.95-xO2 (x=0, 0.29, 0.475, 0.66 and 0.95) solid solution catalysts and a series of M-doped Pt-MgO (M = Pd, Ir, Re, Ru, Rh and Cr) sheet-shaped nano-catalysts. Both characteristic (XRD, BET, H2-TPR, CO-chemisorption, TEM and XPS) and reactivity measurements were used to investigate the activity of the catalysts. Results indicated that reactivity depended on... 

Many of industrial processes include suspension in their middle section of production, final product or residue. Majority of these two-phase mixtures are unstable due to their large particle size (larger than one micrometer). Therefore, Study of particle distribution in suspensions for generation of stabilized suspension becomes significant. In this study a new mechanism in stabilization of microparticle suspension known as nanoparticle halo mechanism has been assessed. Experiments have been conducted in dilute suspension and two-way coupling range. The effect of the presence of silica nanoparticle on zirconia microparticle suspension has been investigated. The effect of zeta potential of...