Sharif Digital Repository

Recent investigations on construction engineering have determined that repairing of Reinforced Concrete (RC) by means of fiber reinforced polymer (FRP) composites is an effective method of retrofitting existing columns. The main research in this thesis focuses on the repair of concrete specimens which are damaged and their initial strength has been reduced. To achieve this purpose, through experimental procedures, the effect of confining damaged concrete cylinders by FRP, has been investigated. The experimental program included three parameters: type of fibers (glass or carbon), type of confining (full or partial), and the number of layers. First concrete cylinders were made and loaded to... 

Today, the importance of scientific collaborations is due to the fact that researchers who jointly publish an article, research connections are formed between them, and as a result, professional learning is obtained. Each of these researchers brings a feature and advantage to the research team, such as mastering a particular topic and its subdivisions, team thinking, and division of labor between them. The importance of these collaborations is doubled when researchers collaborate with each other at the international level, because the networking of researchers through collaboration with colleagues from different countries, especially central and developed countries in science, in addition to... 

Perovskite solar cells are the new generation of solar cells, and are mainly introduced in two types of structures.1) planer and 2) mesoscopic structure. The difference between these two structures derives from the absence of mesoporous layer in the planer structures. The mesoporous layer acts as an electron transporting layer, and is mainly a titanium dioxide semiconductor. To apply the mesoporous layer, the preparation of the TiO2 paste is needed.The synthesis of titanium dioxide nanopowder for the preparation of TiO2 paste requires high temperature heat treatment and is not desirable in terms of energy consumption.Another weakness of this layer is the presence of surface defects, which... 

In this thesis, a coarse-grained multi-scale method for 2D crystallyn solids based-on finite element consepts has presented. In this method, both scales are atomic scale and similar to what we see in non-local QC method, the entire atomic structure will be intact. Accordingly, calculations of potential functions and forces in the domain will have the atomic accuracy. In the presented method to reduce the domain’s degrees of freedom, the classical finite-element meshing concept to mesh the elastic linear areas in the domain is used and the MD calculations will done on the mesh nodes. Therefore, degrees of freedom in the system will reduce and consequently, the computational cost will reduce.... 

Peak Floor Acceleration (PFA) is a necessary requirement in Industrial Buildings for the design of equipment, piping, cable tray and ventilation duct supports. The seismic analysis of equipments needs the determination of PFA at the points where the equipments are fixed on the supporting structure. The classical spectral methods (SRSS, CQC) do not allow this determination which can be done in using the time integration method. This last approach needs to perform numerous calculations with various realizations of the seismic excitation. This thesis aims to present a method allowing calculating the response properties of a linear elastic shear building structure loaded by a transient... 

Dye-sensitized solar cells (DSSCs) are Photoelectrochemical cells using wide band gap nanoporous oxide semiconductors sensitized by dye molecules. For achieving high efficiency DSSCs preparation of photoanode electrode with high surface aea which leads to adequate dye absorption is necessary. In order to achieve proper morphology, thickness, particles size and porosity, producing a TiO2 nano-structured paste is required. TiO2 powder was prepared using sol-gel method. following a calcination process at 300 degrees, XRD patterns showed presence of anatase and brookite structures with average crystallite size of 9 nm. Additives such as diethylene glycol, acetylacetone and Triton X-100 were used... 

With development of nanotechnology in medicine, nanoparticles are used for detection of tumor and cancer biomarkers. Magnetic nanoparticles are widely used for therapeutic and diagnostic objectives, because of their biocompatibility, ease of preparation and strong magnetic properties. Genistein (C15H10O5) is a soy isoflavone which is used for its anti-cancer activities. It is used for inhibition of cell proliferation, cell growth, and tumor invasion. The aim of this study is to assess the impact of nano-conjugation of geinstein as chemotherapeutic agent against cancer. For preparation of typical iron oxide Nanoparticles, Magnetite nanoparticles were synthesized by coprecipitating iron (II)... 

The Mesoporous Titanium Dioxide film using Sol-Gel method and Evaporation-Induced Self-Assembly technique (EISA) was prepared. In this study, in order to employ the best coatings in anode electrode of dye-sensitized solar cell, different conditions of making this film, the effective parameters in final structure, and various methods of coating were analyzed. After optimizing the conditions of film creating, images of field emission scanning electron microscope (FESEM) proved the formation of a layer of mesoporous structure which thickness after three times of coating is about 1.5 micrometers. In order to increase the energy conversion efficiency of solar cells, a new formulation for... 

In this thesis, pure –known as T- and chromium doped titanium dioxide nanoparticles –known as -CTx- with different dopant atomic ratio (0.1 to 5 %at.) were synthesized using a facile, fast and efficient method. FESEM and XRD studies showed no morphologic and structural change via Cr doping of nanoparticles (size in the range of 20-30 nm). However, according to DRS analysis, Cr intrusion in TiO2 crystal structure, drastically reduced band gap energy of pure TiO2 from 3.14 eV to 1.81 eV for CT3 powder and improved absorption range of UV-Vis spectrum. Mott-Schottky plots indicated that, Cr doping, caused reduction in donor density of TiO2 and an upward shift in the conduction band edge.... 

Structure and morphology of titanium dioxide have an excessive effect on the photovoltaic properties of dye-sensitized solar cells (DSCs). Different approaches have been used to improve the efficiency of these cells. One is using a scattering layer. Studies have been shown that properties of scattering layer such as composition and morphology have great effect on photovoltaic properties of solar cell. In this project, the effect of cubic morphology of TiO2 as a scattering agent in photoanode of DSCs is studied. Titanium dioxide with various morphologies including nanoparticles, solid and hollow cubic structures have been synthesized by solvothermal and hydrothermal methods, respectively. The... 

In present work, hydroxyapatite nano-rods are synthesized using a simple sol-gel method with calcium nitrate and potassium dihydrogenphosphate as calcium and phosphorus precursors respectively and ammonia was used for adjusting the pH=9. To obtain rod shape hydroxyapaite powder, multi wall carbon nanotubes were added to the solution, nHA powder was calcinated at 60 and 450 ℃. In second step, chitosan-gelatin/nanoHA solution were prepared by blending chitosan and gelatin in different concentrations with nanoHA powder, then the solution was freeze dried to maintain a composite scaffold. The prepared HA powder and bio-composite scaffold were characterized by X-ray diffraction (XRD), field... 

Dye-sensitized solar cell (DSSCS) is the third-generation of solar cells based on semiconductors formed between a photo sensitized anode and counter cathode which make a photo electrochemical system. They haven’t been commercially marketed due to their lower efficiency than the previous generations. In order to achieve the higher efficiency, the electron injection and light absorption must be increased. One way to increase electron injection is doping the semiconductor with an external ion to reduce lattice band gap. In this work, we made powder and Nano-structured film of titanium dioxide doped with various molar ratios of Mg by the sol-gel process. The effect of Mg:Ti molar ratio on... 

In this study, application of a Magnetic Nanofluid consisting of Magnetite as Nanoparticle and Water as base fluid in DASC systems is investigated. The DASC system is modeled theoretically and behavior of such system is predicted.In this study a comparison between magnetite Nanofluid and some other common Nanofluids is conducted. The study shows that Magnetite Nanofluid has a better performance and efficiency than Water, Al2O3 Nanofluid and SiO2 Nanofluid. Also magnetite Nanofluid and TiO2 Nanofluid function are almost similar.Also effect of external magnetic field on the performance of magnetite Nanofluid is investigated. It is showed that when the magnetic Nanofluid is subjected to an... 

The goal of crowd labeling is to find labels of given samples using humans’ mind power.Since crowds are not necessarily experts, their provided labels are rather noisy and erroneous.This challenge is usually resolved by collecting multiple labels for each sample and aggregating them to estimate its true label. Although this mechanism leads to high-quality labels, it is not actually cost effective. Adaptive methods consider that only some samples are challenging and require more labels. They spend the budget more wisely, and iteratively collect the required labels. Using adaptive methods approach, we utilize statistical latent models to model and analyze the collected labels and low-rank... 

In the present work, one dimensional ZnO nanostructures were grown by seed-assisted hydrothermal method. Hydrothermal processing parameters were controlled to obtain ZnO nanorods with diameter lower than 120 nm. The products were characterized by FE-SEM, EDAX, XRD, PL, and ATR-FTIR analyses. ZnO nanoparticles were also synthesized via a simple solvothermal method and their photo peropeties were compared with onedimensional nanostructures. Thereafter dye-sensitized solar cells based on TiO2-ZnO double layer nanostructured film were fabricated. It was observed that DSSC efficiency increased with decreasing the thickness of the film. The highest efficiency of 2.41% was obtained  

Investigation about Hydraulic Fracturing phenomenon in fractured porous medium which was occurred by in-situ fracture pressure upon the crack wings, owes the fact that creating enormous damages. However, it might include advantages such as increasing the rate of crude oil production from deep and high pressure/ high temperature reservoirs. On account of the fact that, existence of cracks and natural discontinuities and heat sources such as boundary of geo thermal reservoirs in porous mediums it is undeniable fact. Also, cross sectioning hydraulic fracturing cracks with natural cracks it is an obvious impact. Actually, investigation and analyzing the break throw of HF crack with natural... 

A new strategy for enhancing the efficiency of TiO2 dye sensitized solar cells (DSSCs) doped with Ni ions with different molar percentages (i.e., 0, 0.5, 1, 5 and 10 mol%) was reported. The samples were prepared by sol-gel route and characterized by means of XRD, DRS, UV-visible, FESEM and photovoltaic measurment techniques. It was found that Ni-doped TiO2 nanoparticles had a mixture of anatase, rutile and brookite crystal structures. Moreover, the band gap energy was decreased with increasing Ni molar ratio, The highest cell efficiency of 5.4% was achieved for 1mol% Ni-doped TiO2, being 42% greater than that of pure TiO2 nanoparticles  

Chatter in machining systems is a limiting factor of workpiece surface, tool and machine life and material removal rate. Because of this, studying and modeling of vibrations is very important in the machining. This study is much importer in the boring operation because boring bar's length to diameter ratio is very high and so it is very sensitive to vibrations. As we know, vibration characteristics of a machine change between its operating condition and its resting mode. Because of this it's better to study machine's vibrations when it's working. This study requires some methods that can find operating parameters of machine. The aim of this work is to find these parameters. For finding these... 

The unsteady phenomena occur in rotors of helicopters, wind turbines and compressors. Investigation of the unsteady flow is a very important test, since it can affect and restrict the performance of rotors of helicopters and wind turbine's blades when operating at high angles of attack. Dynamic tests, such as pitching and plunging oscillations are one of the best methods for studying these phenomena due to the complexity of the unsteady flows. In analyzing the results of dynamic tests one must consider the interference effects of wind tunnel walls. Different investigations show that in dynamic tests, the interference effects of flow field around the model, wind tunnel walls and support of...