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    Designing a hierarchical model-predictive controller for tracking an unknown ground moving target using a 6-DOF quad-rotor

    , Article International Journal of Dynamics and Control ; September , 2020 Khankalantary, S ; Badri, P ; Mohammadkhani, H ; Sharif University of Technology
    Springer Science and Business Media Deutschland GmbH  2020
    Abstract
    In this paper, a hierarchical predictive controller is designed in order to solve the tracking problem of a moving ground target by a quad-rotor in an unknown and uneven environment. This controller has internal and external predictive controller levels. In the lower layer of the controller, a constrained predictive controller is designed that is capable of rejecting perturbations and quickly tracking the reference path, and in the outer loop, a model predictive controller is designed to optimally detect the moving ground target where, the sub-cost functions were defined so that the quad-rotor would be able to track the moving ground target even if it was temporarily out of sight of the... 

    Designing a hierarchical model-predictive controller for tracking an unknown ground moving target using a 6-DOF quad-rotor

    , Article International Journal of Dynamics and Control ; Volume 9, Issue 3 , 2021 , Pages 985-999 ; 2195268X (ISSN) Khankalantary, S ; Badri, P ; Mohammadkhani, H ; Sharif University of Technology
    Springer Science and Business Media Deutschland GmbH  2021
    Abstract
    In this paper, a hierarchical predictive controller is designed in order to solve the tracking problem of a moving ground target by a quad-rotor in an unknown and uneven environment. This controller has internal and external predictive controller levels. In the lower layer of the controller, a constrained predictive controller is designed that is capable of rejecting perturbations and quickly tracking the reference path, and in the outer loop, a model predictive controller is designed to optimally detect the moving ground target where, the sub-cost functions were defined so that the quad-rotor would be able to track the moving ground target even if it was temporarily out of sight of the... 

    Thermodynamic study of Cr+3 ions removal by "MnO2 /MWCNT" nanocomposite

    , Article Oriental Journal of Chemistry ; Volume 31, Issue 3 , 2015 , Pages 1429-1436 ; 0970020X (ISSN) Mohammadkhani, S ; Gholami, M. R ; Aghaie, M ; Sharif University of Technology
    Oriental Scientific Publishing Company  2015
    Abstract
    In this research "MnO2/MWCNT" nanocomposite was prepared firstly and then it was used as an adsorbent for Cr+3 ions removal from aqueous solutions. Our results showed that the prepared nanocomposite from modified multi-wall carbon nanotube and MnO2 has a good capacity for Cr+3 removal from aqueous solution. Morphology and Crystallinity of the modified MWCNT before and after deposition on MnO2 were examined by SEM and XRD. In turn, the experimental results were examined according to the Langmuir, Freundlich and Temkin Isotherms and Freundlich isotherm represented our experimental results  

    Thermodynamic study of Cr+3 ions removal by "MnO2/MWCNT" nanocomposite

    , Article Oriental Journal of Chemistry ; Volume 32, Issue 1 , 2016 , Pages 591-599 ; 0970020X (ISSN) Mohammadkhani, S ; Gholami, M. R ; Aghaie, M ; Sharif University of Technology
    Oriental Scientific Publishing Company  2016
    Abstract
    In this research "MnO2/MWCNT" nanocomposite was prepared firstly and then it was used as an adsorbent for Cr+3 ions removal from aqueous solutions. Our results showed that the prepared nanocomposite from modified multi-wall carbon nanotube and MnO2 has a good capacity for Cr+3 removal from aqueous solution. Morphology and Crystallinity of the modified MWCNT before and after deposition on MnO2 were examined by SEM and XRD. In turn, the experimental results were examined according to the Langmuir, Freundlich and Temkin Isotherms and Freundlich isotherm represented our experimental results  

    L1 Adaptive integrated guidance and control for flexible hypersonic flight vehicle in the presence of dynamic uncertainties

    , Article Proceedings of the Institution of Mechanical Engineers. Part I: Journal of Systems and Control Engineering ; Volume 235, Issue 8 , 2021 , Pages 1521-1531 ; 09596518 (ISSN) Khankalantary, S ; Rezaee Ahvanouee, H ; Mohammadkhani, H ; Sharif University of Technology
    SAGE Publications Ltd  2021
    Abstract
    In this article, an integrated guidance and control design method for general nonlinear flexible hypersonic flight vehicles in the presence of dynamic uncertainties based on the (Formula presented.) adaptive state feedback control approach is presented. Initially, the 6-degree-of-freedom integrated guidance and autopilot dynamic model is organized using the combination of flexible uncertain hypersonic flight vehicle dynamic model and hypersonic flight vehicle-target relative motion model whereas aerodynamic and model uncertainties, cross-coupling effects, and disturbances are considered. The proposed integrated guidance and control method based on (Formula presented.) adaptive control scheme... 

    Investigation of Vibration and Stability of Graphene NanoRibbone under Magnetic field Effect

    , Ph.D. Dissertation Sharif University of Technology Mohammadkhani, Hasan (Author) ; Dehghani Firouzabadi, Rouhollah (Supervisor)
    Abstract
    This study aims at investigating the vibration analysis and stability of Graphene Nano-Ribbon (GNR) under a magnetic field using continuum mechanics approach and an efficient hybrid modal-molecular dynamics method. The force distribution on the GNR due to the magnetic field is determined by Maxwell's equations, Biot-savart law, magnetic dipoles and Lorentz force law.
    Using the continuum mechanics model, the vibration of the GNR in a magnetic field is investigated by some problems and the resonance frequencies, stability boundaries and critical load are studied.
    Furthermore, in this present study, an efficient hybrid modal-molecular dynamics method is developed for the vibration... 

    Deep vision for navigation of autonomous motorcycle in urban and semi-urban environments

    , Article 5th Iranian Conference on Signal Processing and Intelligent Systems, ICSPIS 2019, 18 December 2019 through 19 December 2019 ; 2019 ; 9781728153506 (ISBN) Mohammadkhani, M. A ; Majidi, B ; Manzuri, M. T ; Sharif University of Technology
    Institute of Electrical and Electronics Engineers Inc  2019
    Abstract
    Deep neural networks are currently the best solution for road and traffic scene interpretation for autonomous and self-driving vehicles. Compared to the autonomous cars, motorcycles have significant flexibility and advantages in crowded traffic situations and especially in non-urban and off-road areas. Many off-road tracks especially for agriculture and environment management tasks are only traversable with motorcycles. In this paper, a deep neural network is used for design and implementation of the vision system for navigation of an autonomous motorcycle. The proposed framework is evaluated using real world scenarios captured by a real motorcycle in various complex situations. The... 

    Designing a dual-functional epoxy composite system with self-healing/barrier anti-corrosion performance using graphene oxide nano-scale platforms decorated with zinc doped-conductive polypyrrole nanoparticles with great environmental stability and non-toxicity

    , Article Chemical Engineering Journal ; Volume 382 , 15 February , 2020 Mohammadkhani, R ; Ramezanzadeh, M ; Saadatmandi, S ; Ramezanzadeh, B ; Sharif University of Technology
    Elsevier B.V  2020
    Abstract
    Designing a novel epoxy composite system with dual self-healing/barrier anti-corrosion functions using graphene oxide (GO) nano-platforms decorated by polypyrrole (PPy) nanoparticles doped with zinc metal ions is the major objective of this research attempt. GO-PPy-Zn nanoplatform was fabricated via one-pot polymerization of pyrrole monomers on GO and two direct/indirect methods of zinc doping. In order to verify the PPy nanoparticles synthesis on GO sheets several analyses such as UV–visible, XPS, HR-TEM and FE-SEM were performed. The epoxy nanocomposite coatings containing GO-PPy and GO-PPy-Zn nanoplatforms were fabricated and applied on carbon steel. The nanocomposite coatings... 

    Synthesis and Characterization of Anticorrosive Hybrid Epoxy Coating based on Polyaniline/Nanodiamond Nanostructures

    , M.Sc. Thesis Sharif University of Technology Mohammadkhani, Rahman (Author) ; Shojaei, Akbar (Supervisor) ; Pirhady, Nahid (Co-Advisor)
    Abstract
    One of the ways that corrosion control is presented is the use of coatings that have good properties such as high adhesion, impact resistance, ultraviolet radiation, and so on. They also have other unique properties like anti-corrosion property. To achieve coatings with these advanced properties, they use special properties of nanocomposites. Nanocomposites can add or improve one or more properties to coating properties.In the present study, we tried to first synthesize NanoDiamond/Polyaniline hybrid nanoparticles in different percentages and then use this hybrid in epoxy ester coating. To characterize this hybrid, various analyzes such as FE-SEM, TEM, FT-IR, UV-Visible, TGA and XRD were... 

    High-throughput micro-solid phase extraction on 96-well plate using dodecyl methacrylate-ethylen glycol dimethacrylate monolithic copolymer

    , Article Analytica Chimica Acta ; Volume 792 , August , 2013 , Pages 59-65 ; 00032670 (ISSN) Bagheri, H ; Es'haghi, A ; Es-haghi, A ; Mohammadkhani, E ; Sharif University of Technology
    2013
    Abstract
    A novel high-throughput device based on 96-micro-solid phase extraction (96-μ-SPE) system was constructed for multiresidue determination of nine pesticides in aquatic samples. The extraction procedure was performed on a commercially available 96-well plate system. The extraction module consisted of 96 pieces of 1cm×3cm of cylindrically shaped stainless steel meshes. The prepared meshes were fixed in a home-made polytetrafluoroethylene-based constructed ninety-six holes block for possible simultaneous immersion of meshes into the center of individual wells. Dodecyl methacrylate and ethylene glycol dimethacrylate was copolymerized as a monolithic polymer and placed in the cylindrically shaped... 

    Layer-by-layer self assembly deposition and characterization of TiO 2 nanoparticles by using a short chain polycation

    , Article EPJ Applied Physics ; Volume 48, Issue 1 , 2009 , Pages 10602p1-10602p7 ; 12860042 (ISSN) Rahman, M ; Taghavinia, N ; Sharif University of Technology
    2009
    Abstract
    Using low molecular weight polyethylenimine (PEI), transparent thin films of TiO2 nanoparticles were prepared by layer-by-layer self assembly method. UV-visible spectrophotometry was employed in a quantitative manner to monitor the adsorbed mass of TiO2 and PEI after each dip cycle. The adsorption of both TiO2 and PEI showed a saturation dip time of 10 min. The effect of dip time on the growth mode and surface morphology was investigated by scanning electron microscopy (SEM) and non-contact atomic force microscopy (AFM). It was found that growth proceeds in the form of laterally broad islands in case of short dip times, and taller but laterally smaller islands in case of longer dip times. A... 

    Graphene oxide nanoplatforms reduction by green plant-sourced organic compounds for construction of an active anti-corrosion coating; experimental/electronic-scale DFT-D modeling studies

    , Article Chemical Engineering Journal ; Volume 397 , 1 October , 2020 Mohammadkhani, R ; Ramezanzadeh, M ; Akbarzadeh, S ; Bahlakeh, G ; Ramezanzadeh, B ; Sharif University of Technology
    Elsevier B.V  2020
    Abstract
    In this study, the Peganum harmala seed extract (PHSE) was used as a green reducing agent of graphene oxide with high deoxygenation capability. PHSE not only acts as a reducing agent of GO due to the high amount of nitrogen-rich compounds but also plays an essential role in the particles' active anti-corrosion performance improvement. In order to add more active inhibition property, the zinc cations were doped successfully on the chemical structure of GO nanosheets, and eventually, the RGO-PHSE-Zn nanocomposite was obtained. The FT-IR results and UV–visible achievements declared that the epoxide (-C-O-C-) functional groups attached to the surface of the GO nanosheets had been successfully... 

    PO43--Loaded zif-8-type metal-organic framework-decorated multiwalled carbon nanotube synthesis and application in silane coatings for achieving a smart corrosion protection performance

    , Article Industrial and Engineering Chemistry Research ; Volume 61, Issue 32 , 2022 , Pages 11747-11765 ; 08885885 (ISSN) Mohammadkhani, R ; Ramezanzadeh, M ; Fedel, M ; Ramezanzadeh, B ; Mahdavian, M ; Sharif University of Technology
    American Chemical Society  2022
    Abstract
    In this research study, interfacial assembled nanoporous zeolitic imidazolate framework (ZIF-8) multiwalled oxidized carbon nanotubes (MW-OCNTs) were developed and introduced into a silane coating. To analyze the destructive behavior of the nanoparticles exposed to salty solutions with three distinctive pHs of 2, 7.5, and 12, various types of tests such as X-ray diffraction (XRD), field emission scanning electron microscopy (FESEM), and inductively coupled plasma (ICP) were accomplished. The XRD test revealed that the main characteristic peaks of ZIF-8 were eliminated and/or their intensity decreased. In accordance with the obtained data from the XRD test, nanoparticles at pH = 2 had been... 

    A modified molecular structural mechanics model for the buckling analysis of single layer graphene sheet

    , Article Solid State Communications ; Volume 225 , 2016 , Pages 12-16 ; 00381098 (ISSN) Firouz Abadi, R. D ; Moshrefzadeh Sany, H ; Mohammadkhani, H ; Sarmadi, M ; Sharif University of Technology
    Elsevier Ltd  2016
    Abstract
    In this paper the classical molecular structural mechanics model of graphene is modified to improve its accuracy for the analysis of transverse deformations. To this aim, a sample graphene sheet under a uniform pressure is modeled by both molecular dynamics and molecular structural mechanics methods. The sectional properties of the beam element, by which the covalent bonds are modeled, are modified such that the difference between the results of the molecular mechanics model and molecular dynamics simulation is minimized. Using this modified model, the buckling behavior of graphene under a uniform edge pressure is investigated subjected to different boundary conditions for both zigzag and... 

    Synthesis and characterization of polyaniline/nanodiamond hybrid nanostructures with various morphologies to enhance the corrosion protection performance of epoxy coating

    , Article Diamond and Related Materials ; Volume 120 , 2021 ; 09259635 (ISSN) Mohammadkhani, R ; Shojaei, A ; Rahmani, P ; Pirhady Tavandashti, N ; Amouzegar, M ; Sharif University of Technology
    Elsevier Ltd  2021
    Abstract
    In this study, nano-sized diamond particles (ND) were functionalized in two consecutive stages. First, dry thermal oxidation was employed to obtain carboxylated ND. In the next step, carboxylated ND was properly surface modified through wet chemistry to acquire aminated-ND (ND-NH2). Then, polyaniline (PANI) was synthesized in the presence of aminated-ND particles at a broad concentration from 1 wt% to 70 wt% to obtain PANI/ND hybrid nanostructures. The chemical structure, morphology, and thermal stability of nanoparticles were comprehensively characterized by different techniques such as FT-IR, UV–visible, TGA, XRD, FESEM, and TEM. It was observed that the morphology of PANI/ND... 

    Prediction of Density, Surface Tension and Viscosity of Ionic Liquids using Artificial Intelligence

    , M.Sc. Thesis Sharif University of Technology Torrik, Abdolhalim (Author) ; Rahman Setayesh, Shahrbanoo (Supervisor)
    Abstract
    Ionic liquids due to their unique physical and chemical properties are widely used in various fields of chemistry and chemical engineering. Determining properties of ionic liquids can be difficult, time consuming or even impossible. In first step of this study the IL thermo database was chosen as source of experimental data of ionic liquids. Viscosity, density, surface tension and melting temperature of ionic liquids based on bis(trifluoromethylsulfonyl)imide anion with cations imidazolium, pyridinium, pyrrolidinium, piperidinium and ammonium were modeled using QSPR approach. Linear and nonlinear models were built by means of multiple linear regression (MLR), multilayer perceptron neural... 

    Preparation, Characterization and Catalytic Application of Some Polyoxometalates for Esterification Reaction

    , M.Sc. Thesis Sharif University of Technology Nazari, Pegah (Author) ; Rahman Setayesh, Shahrbanoo (Supervisor)
    Abstract
    Catalytic esterification of acetic acid with 1-hexanol was investigated over polyoxometalates. H3PW12O40 and H3PMo6W6O40 polyoxometalates with keggin structures were synthesized. Catalytic activity and recyclability of them were improved by loading on the γ-Al2O3 with impregnation method and Cs, K and NH4 salts preparing.Catalysts were characterized by XRD, SEM, FT-IR, BET, DRS and NMR techniques. According to XRD's results, catalysts have ace-centered cubic crystal systems. Loading on supports and preparing the salts do not destroy the structures of polyoxometalates. SEM images show the uniformity of catalysts' surface and catalysts' fixing on the support. It was seen that the keggin... 

    Electrochemical Degradation of Organic Pollutants in the Presence of Spinel Cobalt Ferrite Nanoparticles: Investigation of the Effective Parameters and Evaluation of Degradation Kinetics

    , M.Sc. Thesis Sharif University of Technology Mousavi, Sadegh (Author) ; Rahman Setayesh, Shahrbanoo (Supervisor)
    Abstract
    In this study, CoFe2O4/CuO nanocomposite was synthesized by hydrothermal method and utilized for removal of metronidazole in electro-Fenton process. Nanocomposite was characterized by FT-IR, XRD, FE-SEM, VSM and BET methods. The Results of XRD patterns confirmed the monoclinic structure formation for copper(Ⅱ) oxide and the spinel structure for CoFe2O4. The FE-SEM images displayed the formation of CuO nanosheets for copper(Ⅱ) oxide and the decoration of cobalt ferrite nanoparticles on the surface of CuO nanosheets. Measurement of the surface area of nanocatalysts using BET isotherm represented the high surface area for CuO nanosheets and the increase of surface area of nanocomposite in... 

    Theoretical Study of Adsorption of Organic Pollutants on Polypyrrole with Density Functional Theory (DFT)

    , M.Sc. Thesis Sharif University of Technology Rezaee, Mozafar (Author) ; Rahman Setayesh, Shahrbanoo (Supervisor)
    Abstract
    Phenolic compounds, which are one of the most dangerous compounds for the environment, are present in many effluents of various industries such as petrochemicals and pharmaceuticals, and the need to eliminate these compounds is increasingly felt. In this study, adsorption of three compounds of para-chlorophenol, para-nitrophenol and hydroquinone on polypyrrole adsorbent in the form of neutral, charged, copolymer with polyaniline and phosphorus-doped have been investigated using density functional theory (DFT). Calculations are performed at two levels of b3lyp/6-31+G(d,p) and wb97xd/631+G(d,p) for two different orientations of adsorbate molecules that the correlation-exchange function wb97xd... 

    Synthesis of Solar Light Responsive Nanocatalysts and Investigation of their Performance in Water Splitting Reaction

    , M.Sc. Thesis Sharif University of Technology Mokhtari, Negin (Author) ; Rahman Setayesh, Shahrbanoo (Supervisor)
    Abstract
    Today, fossil fuels cause countless environmental pollutants, so replacing fossil fuels with clean energy sources is very important. Water splitting using light and a semiconductor is one of the new methods of producing oxygen and hydrogen, which due to its simplicity and cheapness, has attracted a lot of attention today. In this study, ZnMn2O4 photocatalyst nanoparticles were first loaded on a graphitic carbon nitride support in different ratios of ZnMn2O4 and carbon support by hydrothermal method. Then the photocatalysts were evaluated for evolution of oxygen and hydrogen photocatalysts through water splitting under visible light. In ZnMn2O4 / g-C3N4 (80:20) nanocomposite, the highest...