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mohammadkhani--rahman
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Designing a hierarchical model-predictive controller for tracking an unknown ground moving target using a 6-DOF quad-rotor
, Article International Journal of Dynamics and Control ; September , 2020 ; Badri, P ; Mohammadkhani, H ; Sharif University of Technology
Springer Science and Business Media Deutschland GmbH
2020
Abstract
In this paper, a hierarchical predictive controller is designed in order to solve the tracking problem of a moving ground target by a quad-rotor in an unknown and uneven environment. This controller has internal and external predictive controller levels. In the lower layer of the controller, a constrained predictive controller is designed that is capable of rejecting perturbations and quickly tracking the reference path, and in the outer loop, a model predictive controller is designed to optimally detect the moving ground target where, the sub-cost functions were defined so that the quad-rotor would be able to track the moving ground target even if it was temporarily out of sight of the...
Designing a hierarchical model-predictive controller for tracking an unknown ground moving target using a 6-DOF quad-rotor
, Article International Journal of Dynamics and Control ; Volume 9, Issue 3 , 2021 , Pages 985-999 ; 2195268X (ISSN) ; Badri, P ; Mohammadkhani, H ; Sharif University of Technology
Springer Science and Business Media Deutschland GmbH
2021
Abstract
In this paper, a hierarchical predictive controller is designed in order to solve the tracking problem of a moving ground target by a quad-rotor in an unknown and uneven environment. This controller has internal and external predictive controller levels. In the lower layer of the controller, a constrained predictive controller is designed that is capable of rejecting perturbations and quickly tracking the reference path, and in the outer loop, a model predictive controller is designed to optimally detect the moving ground target where, the sub-cost functions were defined so that the quad-rotor would be able to track the moving ground target even if it was temporarily out of sight of the...
Investigation of Vibration and Stability of Graphene NanoRibbone under Magnetic field Effect
, Ph.D. Dissertation Sharif University of Technology ; Dehghani Firouzabadi, Rouhollah (Supervisor)
Abstract
This study aims at investigating the vibration analysis and stability of Graphene Nano-Ribbon (GNR) under a magnetic field using continuum mechanics approach and an efficient hybrid modal-molecular dynamics method. The force distribution on the GNR due to the magnetic field is determined by Maxwell's equations, Biot-savart law, magnetic dipoles and Lorentz force law.
Using the continuum mechanics model, the vibration of the GNR in a magnetic field is investigated by some problems and the resonance frequencies, stability boundaries and critical load are studied.
Furthermore, in this present study, an efficient hybrid modal-molecular dynamics method is developed for the vibration...
Using the continuum mechanics model, the vibration of the GNR in a magnetic field is investigated by some problems and the resonance frequencies, stability boundaries and critical load are studied.
Furthermore, in this present study, an efficient hybrid modal-molecular dynamics method is developed for the vibration...
Thermodynamic study of Cr+3 ions removal by "MnO2 /MWCNT" nanocomposite
, Article Oriental Journal of Chemistry ; Volume 31, Issue 3 , 2015 , Pages 1429-1436 ; 0970020X (ISSN) ; Gholami, M. R ; Aghaie, M ; Sharif University of Technology
Oriental Scientific Publishing Company
2015
Abstract
In this research "MnO2/MWCNT" nanocomposite was prepared firstly and then it was used as an adsorbent for Cr+3 ions removal from aqueous solutions. Our results showed that the prepared nanocomposite from modified multi-wall carbon nanotube and MnO2 has a good capacity for Cr+3 removal from aqueous solution. Morphology and Crystallinity of the modified MWCNT before and after deposition on MnO2 were examined by SEM and XRD. In turn, the experimental results were examined according to the Langmuir, Freundlich and Temkin Isotherms and Freundlich isotherm represented our experimental results
Thermodynamic study of Cr+3 ions removal by "MnO2/MWCNT" nanocomposite
, Article Oriental Journal of Chemistry ; Volume 32, Issue 1 , 2016 , Pages 591-599 ; 0970020X (ISSN) ; Gholami, M. R ; Aghaie, M ; Sharif University of Technology
Oriental Scientific Publishing Company
2016
Abstract
In this research "MnO2/MWCNT" nanocomposite was prepared firstly and then it was used as an adsorbent for Cr+3 ions removal from aqueous solutions. Our results showed that the prepared nanocomposite from modified multi-wall carbon nanotube and MnO2 has a good capacity for Cr+3 removal from aqueous solution. Morphology and Crystallinity of the modified MWCNT before and after deposition on MnO2 were examined by SEM and XRD. In turn, the experimental results were examined according to the Langmuir, Freundlich and Temkin Isotherms and Freundlich isotherm represented our experimental results
L1 Adaptive integrated guidance and control for flexible hypersonic flight vehicle in the presence of dynamic uncertainties
, Article Proceedings of the Institution of Mechanical Engineers. Part I: Journal of Systems and Control Engineering ; Volume 235, Issue 8 , 2021 , Pages 1521-1531 ; 09596518 (ISSN) ; Rezaee Ahvanouee, H ; Mohammadkhani, H ; Sharif University of Technology
SAGE Publications Ltd
2021
Abstract
In this article, an integrated guidance and control design method for general nonlinear flexible hypersonic flight vehicles in the presence of dynamic uncertainties based on the (Formula presented.) adaptive state feedback control approach is presented. Initially, the 6-degree-of-freedom integrated guidance and autopilot dynamic model is organized using the combination of flexible uncertain hypersonic flight vehicle dynamic model and hypersonic flight vehicle-target relative motion model whereas aerodynamic and model uncertainties, cross-coupling effects, and disturbances are considered. The proposed integrated guidance and control method based on (Formula presented.) adaptive control scheme...
Synthesis and Characterization of Anticorrosive Hybrid Epoxy Coating based on Polyaniline/Nanodiamond Nanostructures
, M.Sc. Thesis Sharif University of Technology ; Shojaei, Akbar (Supervisor) ; Pirhady, Nahid (Co-Advisor)
Abstract
One of the ways that corrosion control is presented is the use of coatings that have good properties such as high adhesion, impact resistance, ultraviolet radiation, and so on. They also have other unique properties like anti-corrosion property. To achieve coatings with these advanced properties, they use special properties of nanocomposites. Nanocomposites can add or improve one or more properties to coating properties.In the present study, we tried to first synthesize NanoDiamond/Polyaniline hybrid nanoparticles in different percentages and then use this hybrid in epoxy ester coating. To characterize this hybrid, various analyzes such as FE-SEM, TEM, FT-IR, UV-Visible, TGA and XRD were...
Deep vision for navigation of autonomous motorcycle in urban and semi-urban environments
, Article 5th Iranian Conference on Signal Processing and Intelligent Systems, ICSPIS 2019, 18 December 2019 through 19 December 2019 ; 2019 ; 9781728153506 (ISBN) ; Majidi, B ; Manzuri, M. T ; Sharif University of Technology
Institute of Electrical and Electronics Engineers Inc
2019
Abstract
Deep neural networks are currently the best solution for road and traffic scene interpretation for autonomous and self-driving vehicles. Compared to the autonomous cars, motorcycles have significant flexibility and advantages in crowded traffic situations and especially in non-urban and off-road areas. Many off-road tracks especially for agriculture and environment management tasks are only traversable with motorcycles. In this paper, a deep neural network is used for design and implementation of the vision system for navigation of an autonomous motorcycle. The proposed framework is evaluated using real world scenarios captured by a real motorcycle in various complex situations. The...
Designing a dual-functional epoxy composite system with self-healing/barrier anti-corrosion performance using graphene oxide nano-scale platforms decorated with zinc doped-conductive polypyrrole nanoparticles with great environmental stability and non-toxicity
, Article Chemical Engineering Journal ; Volume 382 , 15 February , 2020 ; Ramezanzadeh, M ; Saadatmandi, S ; Ramezanzadeh, B ; Sharif University of Technology
Elsevier B.V
2020
Abstract
Designing a novel epoxy composite system with dual self-healing/barrier anti-corrosion functions using graphene oxide (GO) nano-platforms decorated by polypyrrole (PPy) nanoparticles doped with zinc metal ions is the major objective of this research attempt. GO-PPy-Zn nanoplatform was fabricated via one-pot polymerization of pyrrole monomers on GO and two direct/indirect methods of zinc doping. In order to verify the PPy nanoparticles synthesis on GO sheets several analyses such as UV–visible, XPS, HR-TEM and FE-SEM were performed. The epoxy nanocomposite coatings containing GO-PPy and GO-PPy-Zn nanoplatforms were fabricated and applied on carbon steel. The nanocomposite coatings...
High-throughput micro-solid phase extraction on 96-well plate using dodecyl methacrylate-ethylen glycol dimethacrylate monolithic copolymer
, Article Analytica Chimica Acta ; Volume 792 , August , 2013 , Pages 59-65 ; 00032670 (ISSN) ; Es'haghi, A ; Es-haghi, A ; Mohammadkhani, E ; Sharif University of Technology
2013
Abstract
A novel high-throughput device based on 96-micro-solid phase extraction (96-μ-SPE) system was constructed for multiresidue determination of nine pesticides in aquatic samples. The extraction procedure was performed on a commercially available 96-well plate system. The extraction module consisted of 96 pieces of 1cm×3cm of cylindrically shaped stainless steel meshes. The prepared meshes were fixed in a home-made polytetrafluoroethylene-based constructed ninety-six holes block for possible simultaneous immersion of meshes into the center of individual wells. Dodecyl methacrylate and ethylene glycol dimethacrylate was copolymerized as a monolithic polymer and placed in the cylindrically shaped...
Layer-by-layer self assembly deposition and characterization of TiO 2 nanoparticles by using a short chain polycation
, Article EPJ Applied Physics ; Volume 48, Issue 1 , 2009 , Pages 10602p1-10602p7 ; 12860042 (ISSN) ; Taghavinia, N ; Sharif University of Technology
2009
Abstract
Using low molecular weight polyethylenimine (PEI), transparent thin films of TiO2 nanoparticles were prepared by layer-by-layer self assembly method. UV-visible spectrophotometry was employed in a quantitative manner to monitor the adsorbed mass of TiO2 and PEI after each dip cycle. The adsorption of both TiO2 and PEI showed a saturation dip time of 10 min. The effect of dip time on the growth mode and surface morphology was investigated by scanning electron microscopy (SEM) and non-contact atomic force microscopy (AFM). It was found that growth proceeds in the form of laterally broad islands in case of short dip times, and taller but laterally smaller islands in case of longer dip times. A...
Graphene oxide nanoplatforms reduction by green plant-sourced organic compounds for construction of an active anti-corrosion coating; experimental/electronic-scale DFT-D modeling studies
, Article Chemical Engineering Journal ; Volume 397 , 1 October , 2020 ; Ramezanzadeh, M ; Akbarzadeh, S ; Bahlakeh, G ; Ramezanzadeh, B ; Sharif University of Technology
Elsevier B.V
2020
Abstract
In this study, the Peganum harmala seed extract (PHSE) was used as a green reducing agent of graphene oxide with high deoxygenation capability. PHSE not only acts as a reducing agent of GO due to the high amount of nitrogen-rich compounds but also plays an essential role in the particles' active anti-corrosion performance improvement. In order to add more active inhibition property, the zinc cations were doped successfully on the chemical structure of GO nanosheets, and eventually, the RGO-PHSE-Zn nanocomposite was obtained. The FT-IR results and UV–visible achievements declared that the epoxide (-C-O-C-) functional groups attached to the surface of the GO nanosheets had been successfully...
PO43--Loaded zif-8-type metal-organic framework-decorated multiwalled carbon nanotube synthesis and application in silane coatings for achieving a smart corrosion protection performance
, Article Industrial and Engineering Chemistry Research ; Volume 61, Issue 32 , 2022 , Pages 11747-11765 ; 08885885 (ISSN) ; Ramezanzadeh, M ; Fedel, M ; Ramezanzadeh, B ; Mahdavian, M ; Sharif University of Technology
American Chemical Society
2022
Abstract
In this research study, interfacial assembled nanoporous zeolitic imidazolate framework (ZIF-8) multiwalled oxidized carbon nanotubes (MW-OCNTs) were developed and introduced into a silane coating. To analyze the destructive behavior of the nanoparticles exposed to salty solutions with three distinctive pHs of 2, 7.5, and 12, various types of tests such as X-ray diffraction (XRD), field emission scanning electron microscopy (FESEM), and inductively coupled plasma (ICP) were accomplished. The XRD test revealed that the main characteristic peaks of ZIF-8 were eliminated and/or their intensity decreased. In accordance with the obtained data from the XRD test, nanoparticles at pH = 2 had been...
A modified molecular structural mechanics model for the buckling analysis of single layer graphene sheet
, Article Solid State Communications ; Volume 225 , 2016 , Pages 12-16 ; 00381098 (ISSN) ; Moshrefzadeh Sany, H ; Mohammadkhani, H ; Sarmadi, M ; Sharif University of Technology
Elsevier Ltd
2016
Abstract
In this paper the classical molecular structural mechanics model of graphene is modified to improve its accuracy for the analysis of transverse deformations. To this aim, a sample graphene sheet under a uniform pressure is modeled by both molecular dynamics and molecular structural mechanics methods. The sectional properties of the beam element, by which the covalent bonds are modeled, are modified such that the difference between the results of the molecular mechanics model and molecular dynamics simulation is minimized. Using this modified model, the buckling behavior of graphene under a uniform edge pressure is investigated subjected to different boundary conditions for both zigzag and...
Synthesis and characterization of polyaniline/nanodiamond hybrid nanostructures with various morphologies to enhance the corrosion protection performance of epoxy coating
, Article Diamond and Related Materials ; Volume 120 , 2021 ; 09259635 (ISSN) ; Shojaei, A ; Rahmani, P ; Pirhady Tavandashti, N ; Amouzegar, M ; Sharif University of Technology
Elsevier Ltd
2021
Abstract
In this study, nano-sized diamond particles (ND) were functionalized in two consecutive stages. First, dry thermal oxidation was employed to obtain carboxylated ND. In the next step, carboxylated ND was properly surface modified through wet chemistry to acquire aminated-ND (ND-NH2). Then, polyaniline (PANI) was synthesized in the presence of aminated-ND particles at a broad concentration from 1 wt% to 70 wt% to obtain PANI/ND hybrid nanostructures. The chemical structure, morphology, and thermal stability of nanoparticles were comprehensively characterized by different techniques such as FT-IR, UV–visible, TGA, XRD, FESEM, and TEM. It was observed that the morphology of PANI/ND...
Preparation, Characterization and Catalytic Application of Some Polyoxometalates for Esterification Reaction
, M.Sc. Thesis Sharif University of Technology ; Rahman Setayesh, Shahrbanoo (Supervisor)
Abstract
Catalytic esterification of acetic acid with 1-hexanol was investigated over polyoxometalates. H3PW12O40 and H3PMo6W6O40 polyoxometalates with keggin structures were synthesized. Catalytic activity and recyclability of them were improved by loading on the γ-Al2O3 with impregnation method and Cs, K and NH4 salts preparing.Catalysts were characterized by XRD, SEM, FT-IR, BET, DRS and NMR techniques. According to XRD's results, catalysts have ace-centered cubic crystal systems. Loading on supports and preparing the salts do not destroy the structures of polyoxometalates. SEM images show the uniformity of catalysts' surface and catalysts' fixing on the support. It was seen that the keggin...
Prediction of Density, Surface Tension and Viscosity of Ionic Liquids using Artificial Intelligence
, M.Sc. Thesis Sharif University of Technology ; Rahman Setayesh, Shahrbanoo (Supervisor)
Abstract
Ionic liquids due to their unique physical and chemical properties are widely used in various fields of chemistry and chemical engineering. Determining properties of ionic liquids can be difficult, time consuming or even impossible. In first step of this study the IL thermo database was chosen as source of experimental data of ionic liquids. Viscosity, density, surface tension and melting temperature of ionic liquids based on bis(trifluoromethylsulfonyl)imide anion with cations imidazolium, pyridinium, pyrrolidinium, piperidinium and ammonium were modeled using QSPR approach. Linear and nonlinear models were built by means of multiple linear regression (MLR), multilayer perceptron neural...
Theoretical Study of Organic Pollutants Adsorption on Graphene, Doped Graphene and Defective Graphene Nanosheets
, M.Sc. Thesis Sharif University of Technology ; Rahman Setayesh, Shahrbanou (Supervisor)
Abstract
Among the xenobiotic compounds, chlorophenols are considered to be as the most dangerous compounds for the environment and living organisms. These compounds are abundantly found in the wastewater of many chemical industry factories. In this research, by using Gaussian software and density functional theory at the level of B3LYP / 6-31G (d, p),the adsorption of molecules such as phenol, 2-chlorophenol, 4-chlorophenol and 2,4-dichlorophenol over graphene, nitrogen and boron doped graphene sheet are studied. The most stable configurations were determined and adsorption energies were calculated. In addition, to understand the adsorption mechanism, electron properties such as state density and...
Theoretical and Experemental Study of Solid Base Nanocatalysts (Metal Oxides) Modified by Ionic Liquids and Kinetics Investigation of Organic Reactions Such as Hillman and Biodiesel in the Presence of These Nanocatalysts
, Ph.D. Dissertation Sharif University of Technology ; Rahman Setayesh, Shahrbanoo (Supervisor)
Abstract
Thermodynamic quantities such as proton affinity (PA) and molecular basicity (GB) for (CaO)n nanoclusters with n=2–16 have been calculated using three computational models of the DFT (B3LYP, M06, PW91, CAM–B3LYP and ωB97XD functionals), MP2, and HF with the cc-PVNZ (n = D and T) basis set in the gas phase. Absolute deviation error (AAD%) indicates that obtained PA and GB values using DFT model and the B3LYP method with mean percentage errors of 0.77 and 0.90 %, respectively, have the higher accuracy than the other methods and models. Owing to the unique physical and chemical properties of ILs, can be used as catalysts, promoters and modifiers of catalyst in many organic reactions. Therefore,...
Theoretical Investigation of Basicity and Proton Transfer Energy of Protic Energetic Ionic Liquids in the Gas Phase and in Solution
, M.Sc. Thesis Sharif University of Technology ; Rahman Setayesh, Shahrbanoo (Supervisor)
Abstract
The use of energetic ionic liquids as hypergolic fuels, has low toxicity and environmental risk relative the hypergolic fuels such as the hydrazine. In this research by using Gauss view and Gaussian softwares and density functional theory and MP2 methods at the level of B3LYP/6-311G(d,p), the proton transfer from the cations to anions for a set of hypergolic ionic liquids in the gas and solution phases were studied. The most stable configuration of cations and anions are determined. The interaction energies of the selected cations and anions, proton affinities and basicity properties of these hypergolic anions are calculated. The result represents that the lower proton affinity and basicity...