Sharif Digital Repository

Shape memory alloys are referred to as a group of alloys that can retrieve the permanent deformation and strain applied to them and eventually return to their original form. So far, various studies have been done to determine the behavior of these alloys under cyclic loading. Most of the studies have mainly been conducted by using the foundations of Continuum Mechanics in order to examine the properties of memory alloys. In this study, instead of using the Continuum Mechanics, a Molecular Dynamics simulation method using Lennard-Jones potential is utilized. The changes in the behavior and properties of memory alloy under cyclic loading are being examined. First, the functional form... 

Shape memory alloys are referred to as a group of alloys that can retrieve the permanent deformation and strain applied to them and eventually return to their original form. So far, various studies have been done to determine the behavior of these alloys under cyclic loading. Most of the studies have mainly been conducted by using the foundations of Continuum Mechanics in order to examine the properties of memory alloys. In this study, instead of using the Continuum Mechanics, a Molecular Dynamics simulation method using Lennard-Jones potential is utilized. The changes in the behavior and properties of memory alloy under cyclic loading are being examined. First, the functional form... 

Promoting efficacious and low-cost catalysts for the oxygen evolution reaction (OER), as the sluggish half-reaction of the water splitting, is inevitable to make sustainable energy technologies more promising. In this work, we report a series of novel nanocomposites comprising CeO2 nanorods decorated with CoSe2 nanoparticles. The nanocomposites were prepared via a conventional hydrothermal synthesis or a rapid electrodeposition process, and their structure, morphology, and electrochemical performance toward OER in alkaline solution were compared. To tune the electrocatalytic activity, the mass ratio of CoSe2 to CeO2 was systematically varied. Compared with the hydrothermal synthesis, the... 

In this paper, a novel identification method for discrete-time linear systems when input–output observations are contaminated by coloured noise (errors-in-variables models) is proposed. To develop the new approach, modified prediction error and covariance matching methods are utilised. It is proved that the proposed approach leads to a consistent estimation. System identification through the proposed approach entails the existence of a flat frequency interval in power spectra of input and ratio of noise-free input to input signals which is a somewhat mild assumption. Two Monte Carlo simulations are provided to explain the efficiency, numerical complexity and the application of the proposed... 

This paper deals with identification of discrete-time errors-in-variables models where the input and output data are both perturbed by different additive noises. The goal is to study the effects of input noise on the model which is estimated based on the prediction error method. The obtained model is then improved by modifying the results and implementing the instrumental variable method. It is proved that the identification of the errors-in-variables models based on the proposed approach could result in an unbiased estimation in the presence of independent colour noises on the input and output data with adequate accuracy and mediocre complexity. © 2017 Informa UK Limited, trading as Taylor... 

This paper deals with identification of discrete-time errors-in-variables models where the input and output data are both perturbed by different additive noises. The goal is to study the effects of input noise on the model which is estimated based on the prediction error method. The obtained model is then improved by modifying the results and implementing the instrumental variable method. It is proved that the identification of the errors-in-variables models based on the proposed approach could result in an unbiased estimation in the presence of independent colour noises on the input and output data with adequate accuracy and mediocre complexity. © 2017, © 2017 Informa UK Limited, trading as... 

A targeted new dioxo molybdenum(VI) ONO Schiff base complex was prepared for catalyzing epoxidation of olefins in water. This complex was characterized by FT-IR, NMR, UV–Vis, and X-ray crystallography techniques. DFT calculations are additionally performed to find ground and transition states for finding electronic structure and UV–Vis assignment. Afterward, a new protocol was defined for sustainable catalytic epoxidation of olefin in water using this complex as a green catalyst, and also remarkable results are obtained, such as turn over number up to 1400. © 2020 Elsevier B.V  

Blood vessels, especially large vessels have a greater thermal effect on freezing tissue during cryosurgery. Vascular networks act as heat sources in tissue, and cause failure in cryosurgery and reappearance of cancer. The aim of this study is to numerically simulate the effect of probe location and multiprobe on heat transfer distribution. Furthermore, the effect of nanoparticles injection is studied. It is shown that the small probes location near large blood vessels could help to reduce the necessary time for tissue freezing. Nanoparticles injection shows that the thermal effect of blood vessel in tissue is improved. Using Au, Ag and diamond nanoparticles have the most growth of ice ball... 

In this work, the effects of the surface-modified nanodiamond particles (NDs) on the barrier, rheological, mechanical and thermal properties of ethylene vinyl acetate (EVA) composites for the packaging applications were investigated. Fourier transform infrared spectroscopy, as well as thermal gravimetric analysis were employed to study the grafting of vinyltriethoxy silane (VTS) on the surface of NDs. Afterwards, EVA samples containing 0, 0.1, 0.5, 1, 1.5 and 2 wt% of surface-modified NDs were prepared by a two-stage process including the solution and injection processes. In order to evaluate the physicochemical, rheological, mechanical and thermal properties of the EVA/NDs samples, field... 

The effect of temperature, pressure and bonding time on microstructure of temperature gradient transient liquid phase (TGTLP) diffusion bonded Al7075 alloy using liquid gallium interlayer was investigated. The selected bonding method relies on using the minimum amount of liquid gallium on faying surfaces, using a very fast heating rate to reach the joining temperature and imposing a temperature gradient across the bond region. The microstructure of the diffusion bonded joints was evaluated by light optical microscopy, scanning electron microscopy and energy dispersive spectroscopy (EDS). Results show that by increasing the temperature, pressure and time of joining, a more uniform... 

A major problem in real-time packet-based communication systems, is misrouted or delayed packets which results in degraded perceived voice quality. If packets are not available on time, the packets are considered as lost. The easiest solution in a network terminal receiver is to replace silence for the duration of lost speech segments. In a high quality communication system, to avoid degradation in speech quality due to packet loss, a suitable method or algorithm is needed to replace the missing segments of speech. In this paper, we introduce an adaptive filter for replacement of lost speech segment. In this method Kalman filter as a state-space based method will be used to predict the... 

In this study, the effects of the type and content of reactive diluents on the permeation/separation of carbon dioxide/nitrogen (CO2/N2) through acrylate-terminated polyurethane (APU)-acrylate/acrylic diluent (APUA) composite membranes was investigated. A series of APUs based on poly(ethylene glycol) (PEG)-1000 g mol−1, toluene diisocyanate, and 2-hydroxyethyl methacrylate was synthesized and then diluted with several reactive diluents. The results obtained from differential scanning calorimetry (DSC) and Fourier transform infrared analyses showed that the microphase interference of hard and soft segments increased with increasing reactive diluent content. Furthermore, with increasing alkene... 

Using two techniques of thermogravimetry and differential scanning calorimetry under O2 gas atmosphere from 25 to 600°C, the thermal behavior of laboratory-produced compound lead(IV) oxide α-PbO2 was investigated. The identity of products at different stages were confirmed by XRD technique. Both techniques produced similar results supporting the same decomposition stages for the compound. Three distinct energy changes were observed, namely, two endothermic and one exothermic in DSC. The amount of ΔH for each peak is also reported. © 2008 Springer Science+Business Media, LLC  

The compound, alkaline lead acetate, Pb(CH3COO)2·PbO·H2O (ALA), was purchased from the Fluka Company. The X-ray diffraction film and SEM electron microgaph of this compound were obtained and reported in this paper for the first time. The thermal behavior of alkaline lead acetate (ALA) was studied using thermogravimetery (TGA) and Differential Scanning Calorimetery (DSC) techniques under an O2 gas atmosphere from 25 to 600°C. Four distinct energy changes associated with weight changes were observed, all of them being exothermic in the DSC results. The amount of ΔH for each peak is reported. © Sharif University of Technology  

The compound, lead hydroxide Pb6O4(OH)4, was prepared by a method used for the first time in the authors laboratory. The compound was identified by XRD and it's purity was determined by analytical methods (100%). The thermal characteristics of this compound were investigated by using a thermogravimetry (TGA). This compound was found to be stable at room temperature and at 160°C will decompose completely to produce lead (II) oxide. © Sharif University of Technology, April 2007  

The effects of hydrophilic and hydrophobic nanosilica (SiO2) on the morphology, mean diameter distribution of fibers, mechanical and piezoelectric properties of poly (vinylidene fluoride) (PVDF) nanofibers were studies. We prepared Nanofibers by the electrospinning of PVDF solutions containing 1.5 wt.% both hydrophilic and hydrophobic nano-SiO2 loadings. Morphology and diameter distribution of the electrospun nanofibers were studied using field emission scanning electron microscopy (FE-SEM) analysis. Tensile test was used to study the effect of both types of nanosilica on the tensile strength, young's modulus and strain at break. Piezoelectric characterization of the electrospun fibers were... 

In order to determine the activity of C137s in soil resulting from nuclear accidents or fallouts, the best choice is to use HPGe detectors due to their best energy resolutions. In this regard, in order to enhance the detection efficiency, the Marinelli beakers have been used to increase the radiation interaction with the sensitive volume of the detector. In previous works, to optimize the dimension of Marinelli beakers, the assumption was that the emission rate of the source is homogeneous in beaker volume. In the present study, to investigate the effect of the inhomogeneous emission rate of the source on the optimum dimensions of the beaker, in a simple case, the beaker was divided into two... 

Background: Nowadays, study and application of modified membranes for water treatment have been considered significantly. The aim of this study was to prepare and characterize a polysulfone (PSF)/graphene oxide (GO) nanocomposite membrane and to evaluate for arsenate rejection from water. Materials and methods: The nanocomposite PSF/GO membrane was fabricated using wet phase inversion method. The effect of GO on the synthesized membrane morphology and hydrophilicity was studied by using FE-SEM, AFM, contact angle, zeta potential, porosity and pore size tests. The membrane performance was also evaluated in terms of pure water flux and arsenate rejection. Results: ATR-FTIR confirmed the... 

The main purpose of this paper is modeling and simulation of in-situ releasing of smart nano-sized core-shell particles at the water-oil interface during polymer flooding. During the polymer flooding process, when these nano-particles reach the water-oil interface, migrate to the oil phase and the hydrophobic layer of them dissolves in this phase. After dissolution of this protective nano-sized layer, the hydrophilic core containing a water-soluble ultra high molecular weight polymer diffuses back into the water phase and with dissolving in this phase, dramatically increases viscosity of flooding water in the neighborhood of the water-oil interface. In this study, two different...