Sharif Digital Repository

ABSTRACT: Pyrolysis, so-called devolatilization, is one of the first steps of all thermochemical processes occurring in an inert atmosphere. The authors discuss the main kinetic features of heavy oil pyrolysis, on the basis of the data derived m from a TGA analysis and by using a kinetic model. The samples were heated over a range of temperature from 400 K to 430°C at various heating rates between 10 and 80°C/min. Experimental results showed that the effect of time is considerable in the case of tar conversion, compared to char and gases  

In this paper, we introduce new unblind and blind multiuser detectors for an optical code-division multiple-access system. The detectors have two soft and hard stages. In the soft stage, a soft estimation of the interference is obtained by solving an unconstrained maximum-likelihood problem via the iterative expectation-maximization (EM) algorithm. Then, the hard stage detects the user information bit by solving a one-dimensional Boolean constrained problem conditioned on knowing the interference. Our results reveal that the proposed detectors have very low complexity, and are robust against changes in parameters. Moreover, the numerical results illustrate that despite of their simplicities,... 

In this study, a novel approach for sensitive and extremely selective detection of copper ions has been developed based on fluorescence resonance energy transfer (FRET) between AuNPs as an acceptor and fluorescein isothiocyanate (FITC) as a donor. Initially, the fluorescence of the FITC molecule turns-off due to adsorption to the AuNPs surface. However, the fluorescence of the FITC-AuNPs system was switched to turn-on by adding d-Pencillamine (d-PC) to the solution mixtures as FITC molecules are released upon displacement by d-PC on the NPs surface. The higher affinity of d-PC toward the surface of AuNPs was further evidenced by controlling the fluorescence intensity enhancement of the... 

A new, simple and rapid carbon dot (CD) based fluorescent probe for speciation of Fe2+ and Fe3+ ions was developed. The as-prepared CDs contain phenol groups on their surfaces and due to the special coordination interaction of phenol groups with Fe3+ ions, this sensing system exhibits excellent sensitivity and selectivity toward Fe3+. In order to detect Fe2+ ions as well, a specific amount of H2O2 was introduced to the detection system to transform Fe2+ to Fe3+ of which the latter is the determinable form of iron. Under the optimum experimental conditions, the fluorescence intensity of the sensor decreased as the Fe3+ ion concentration increased. The relationship plot between the... 

Discrete kinematic synthesis of discretely actuated hyper-redundant manipulators is a new practical problem in robotics. The problem concerns with determining the type of each manipulator module from among several specific types, so that the manipulator could reach several specified target frames with the lowest error. This paper suggests using a breadth-first search method and a workspace mean frame to solve this problem. To reduce errors, two heuristic ideas are proposed: two-by-two searching method and iteration. The effectiveness of the proposed method is verified through several numerical problems  

The van der Walls interaction between a carbon nanotube sheet (CNTS) and a rare gas atom, is studied using both atomistic and continuum approaches. We present analytical expressions for the van der Waals energy of continuous nanotubes interacting with a rare gas atom. It is found that the continuum approach does not properly treat the effect of atomistic configurations on the energy surfaces. The energy barriers are small as compared to the thermal energy, which implies the free motion above the CNTS in heights about one nanometer. In contrast to the energy surface of a graphene sheet, the honeycomb lattice structure in the energy surface of a CNTS is imperceivable. Defects alter the energy... 

In this paper, a new method is proposed for solving the obstacle avoidance problem of discretely actuated hyper-redundant manipulators. In each step of the solution, the closest collision to the base is removed and then the configuration of the next part of the manipulator is modified without considering the obstacles. This process is performed repeatedly until no collision is found. The Suthakorn method is applied to solve the inverse kinematics problem. Two new ideas are proposed to reduce the errors of this method: the two-by-two searching method, and iterations. To verify the proposed method, some problems are solved numerically for 2D and 3D manipulators, each in two different obstacle... 

A hyper-redundant manipulator is made by mounting the serial and/or parallel mechanisms on top of each other as modules. In discrete actuation, the actuation amounts are a limited number of certain values. It is not feasible to solve the kinematic analysis problems of discretely actuated hyper-redundant manipulators (DAHMs) by using the common methods, which are used for continuous actuated manipulators. In this paper, a new method is proposed to solve the trajectory tracking problem in a static prescribed obstacle field. To date, this problem has not been considered in the literature. The removing first collision (RFC) method, which is originally proposed for solving the inverse kinematic... 

A hyper-redundant manipulator is made by mounting the serial and/or parallel mechanisms on top of each other as modules. In discrete actuation, the actuation amounts are a limited number of certain values. It is not feasible to solve the kinematic analysis problems of discretely actuated hyper-redundant manipulators (DAHMs) by using the common methods, which are used for continuous actuated manipulators. In this paper, a new method is proposed to solve the trajectory tracking problem in a static prescribed obstacle field. To date, this problem has not been considered in the literature. The removing first collision (RFC) method, which is originally proposed for solving the inverse kinematic... 

Discrimination of chiral targets is generally achieved with chiral nanomaterials. However, the limited number of intrinsic chiral nanostructures as well as their complex synthesis procedure has led to the production of chirality-induced nanomaterials as alternatives. Chirality can be induced in nanomaterials by either chirality transfer or the formation of chiral assemblies. Using the latter approach, in this work, we have provided chiral supramolecular assemblies of CdTe quantum dots (QDs) from achiral starting materials. CTAB-QD assemblies showed chiroptical activities, and their orange emission in combination with the blue emission of carbon dots was utilized as a ratiometric chiral... 

An experimental study of a lab scale rotating detonation combustor (RDC) has been conducted to identify and classify its modes of operation under different feeding conditions. The chamber uses air as oxidizer and hydrogen as fuel. The stability diagram of the RDC has been determined based on the detonation chamber Reynolds number and reactants mixture equivalence ratio values. The Reynolds number is based on the air volume flow rate, chamber annulus size, and the reactants mixture feeding slot area. Hence the effects of geometrical parameters and operational parameters on the detonation wave stability can be presented in a single stability map. This diagram identifies different zones in... 

An experimental study of a lab scale rotating detonation combustor (RDC) has been conducted to identify and classify its modes of operation under different feeding conditions. The chamber uses air as oxidizer and hydrogen as fuel. The stability diagram of the RDC has been determined based on the detonation chamber Reynolds number and reactants mixture equivalence ratio values. The Reynolds number is based on the air volume flow rate, chamber annulus size, and the reactants mixture feeding slot area. Hence the effects of geometrical parameters and operational parameters on the detonation wave stability can be presented in a single stability map. This diagram identifies different zones in... 

A statistical algorithm is introduced to improve the false inference of active loci, in the population in which members are admixture. The algorithm uses an advanced clustering algorithm based on a Bayesian approach. The proposed algorithm simultaneously infers the hidden structure of the population. In this regard, the Monte Carlo Markov Chain (MCMC) algorithm has been used to evaluate the posterior probability distribution of the model parameters. The proposed algorithm is implemented in a bundle, and then its performance is widely evaluated in a number of artificial databases. The accuracy of the clustering algorithm is compared with the STRUCTURE method based on certain criterion. © 2019... 

Background: Long reads provide valuable information regarding the sequence composition of genomes. Long reads are usually very noisy which renders their alignments on the reference genome a daunting task. It may take days to process datasets enough to sequence a human genome on a single node. Hence, it is of primary importance to have an aligner which can operate on distributed clusters of computers with high performance in accuracy and speed. Results: In this paper, we presented IMOS, an aligner for mapping noisy long reads to the reference genome. It can be used on a single node as well as on distributed nodes. In its single-node mode, IMOS is an Improved version of Meta-aligner (IM)... 

An indirect colorimetric method is presented for spectrophotometric determination of hydrazine, phenylhydrazine, and isoniazid. Reduction of silver ions to silver nanoparticles (AgNPs) by these analytes as active reducing agents in the presence of polyvinylpyrrolidone (PVP) and also cetyltrimethylammonium chloride (CTAC) as a stabilizer is the basis of the proposed method. The changes in plasmon absorbance of the AgNPs at λ = 415 nm in the presence of PVP were proportional to concentration of hydrazine, phenylhydrazine, and isoniazid in the ranges of 4.0-150.0 μM, 1.0-55.0 μM, and 2.0-30.0 μM, respectively, and the detection limit obtained was 0.79 μM. In the presence of CTAC, the linear... 

A nano-based sensor array has been developed for identification and discrimination of catecholamine neurotransmitters based on optical properties of their oxidation products under alkaline conditions. To produce distinct fluorescence response patterns for individual catecholamine, quenching of thioglycolic acid functionalized cadmium telluride (CdTe) quantum dots, by oxidation products, were employed along with the variation of fluorescence spectra of oxidation products. The spectral changes were analyzed with hierarchical cluster analysis (HCA) and principal component analysis (PCA) to identify catecholamine patterns. The proposed sensor could efficiently discriminate the individual... 

A nano-based sensor array has been developed for identification and discrimination of catecholamine neurotransmitters based on optical properties of their oxidation products under alkaline conditions. To produce distinct fluorescence response patterns for individual catecholamine, quenching of thioglycolic acid functionalized cadmium telluride (CdTe) quantum dots, by oxidation products, were employed along with the variation of fluorescence spectra of oxidation products. The spectral changes were analyzed with hierarchical cluster analysis (HCA) and principal component analysis (PCA) to identify catecholamine patterns. The proposed sensor could efficiently discriminate the individual... 

Herein, we demonstrate a simple yet novel luminescence assay for visual chiral discrimination of cysteine. Thioglycolic acid (TGA)-capped cadmium-telluride (CdTe) quantum dots (QDs) exposing green emission were directly synthesized in aqueous solution. The interaction between cysteine molecules and CdTe QDs induced the aggregation of QDs via hydrogen bonding. As a result of electronic coupling within these aggregates, a redshift both in the absorption and emission spectra of QDs occured. The difference in the kinetics of the interactions between L- A nd D-cysteine with CdTe QDs led to chiral recognition of these enantiomers. Addition of D-cysteine to CdTe QDs in a basic media caused a... 

Monitoring the ratio of 40- and 42-residue amyloid β peptides (i.e., Aβ40 and Aβ42) in human plasma is considered one of the hallmarks of detection of the early stage of Alzheimer's disease (AD). Therefore, development of a specific, yet non-antibody-based method for simultaneous detection of Aβ40 and Aβ42 may have considerable clinical applications. Here, we developed a 'nanoparticle-based colorimetric sensor array' utilizing label-free gold and silver nanoparticles for visual detection of Aβ42 and Aβ40. Different aggregation behaviors of nanoparticles through their conjugation with Aβ42 and Aβ40 followed by the coordination of Aβ42 and Aβ40 with Cu(ii) led to diverse spectral and color... 

A new strategy has been proposed to expand color-tunability of ratiometric fluorescent probes. It was shown that the combination of blue emissive color (as an internal standard) and yellow emissive color (as a probe) is an efficient way to create an extensive color range in ratiometric probes. However, due to the nature of the interaction between the analyte and the probe in terms of fluorescence quenching, occurance of the redshift in the emission is the major provision of such a probe. Our developed ratiometric fluorescence probe consists of blue emissive carbon dots (BCDs) and thioglycolic acid (TGA)-capped yellow emissive cadmium telluride (CdTe) quantum dots (YQDs). The ratiometric...