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    , M.Sc. Thesis Sharif University of Technology Fathi, Shaghayegh (Author) ; Mtlobi Moghadam, Firouz (Supervisor)
    Abstract
    The one pot, three component 1,3-dipolar cycloaddition reaction of azomethine ylides with a series of new dipolarophiles (E)-3 -benzylidene- indolin-2 -ones in methanol under the reflux condition yields ,3′-dispiropyrrolidine oxindole library. The product is produced with high regioselectivity. Catalyst free, excellent yield , easy workup process, short reaction time, and convenient operation are the characteristics of this procedure. NMR and X-ray are used to determine the structure and stereochemistry of cycloadduct products.
     

    Synthesis of Pyrimidine Derivatives Fused to Pyrazol Ring Using Iodine-Catalyzed Two Component Reaction & Synthesis and Application of Magnetic Nickel Ferrite Nanoparticles in the C-N Bond Formation

    , M.Sc. Thesis Sharif University of Technology Moafi, Atiyeh (Author) ; Matloubi Moghadam, Firouz (Supervisor)
    Abstract
    The fused pyrimidine rings have many biological applications such as antibacterial, antiviral, antitumor and anti-inflammation activity. Therefore, their synthesis has attracted many attentions. In this thesis, the synthesis of fused pyrazolopyrimidine rings through two component reaction catalyzed by iodine was investigated. In this reaction, iodine is used to active the imine bond. Low toxicity, availability, low cost and stability to air are some benefits of iodine as a Lewis acid leading to widespread application of I2 in many different organic transformation. Mild reaction conditions, high yields and lower reaction times are among the main advantage of these reactions.
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    Design, Synthesis and Use of Transition Metal Oxide Spinels (Cobalt and Iron) as Catalysts in Organic Reactions

    , M.Sc. Thesis Sharif University of Technology Aghili, Sara (Author) ; Matloubi Moghadam, Firouz (Supervisor)
    Abstract
    Bread scraps with transition metals oxides spinels have been utilized to synthesize¬ magnetic nanocatalyst. The heterogeneous catalyst was characterized using Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), scanning electron microscopy (SEM), Brunauer-Emmett-Teller (BET), thermogravimetric analysis (TGA) and transmission electron microscopy (TEM). The reaction was performed for tandem Knoevenagel-Micheal reaction in the presence of synthesized nanocatalyst as a heterogeneous, environmentally benign, cost-effective catalyst with high catalytic activity using EtOH as a green solvent. The magnetic nanocatalyst was applied to synthesize tetraketones and pyranopyrazoles... 

    Synthesis and Characterization of some Heterocyclic Compounds Containing Nitrogen Using Oxindole Intermediate Skeleton

    , Ph.D. Dissertation Sharif University of Technology Moafi, Atiyeh (Author) ; Matloubi Moghadam, Firouz (Supervisor)
    Abstract
    In the first part of this thesis provided an efficient and easy method for the synthesis of 3-alkylidin-2-oxindoles containing tetrahydropyrazine structure in the absence of catalysts under green conditions. The oxindole unit represents an important structural motif found in natural products and biologically relevant compounds. On the other hand, pyrazines are important and well-known compounds found in nature and many medicinal compounds. According to the aforementioned, it seems that the oxindole compounds containing the pyrazine rings exhibit high biological activity.In the second chapter of this thesis, an efficient study to synthesize thiopyrano [2,3-b] quinoline containing indole... 

    Designing a New Ligand based on Pyridine for Immobilization of Gold Nanoparticles on Reduced Magnetic Graphene Oxide: A New Catalyst for the Reduction of Nitro Compounds and a Diastereoselective Construction of Functionalized Dihydro-Pyridazine based Spirooxindole Scaffold via C-3 Umpolung of Isatin N,N′-Cyclic Azomethine Imine

    , M.Sc. Thesis Sharif University of Technology Siahpoosh, Ali (Author) ; Matloubi Moghadam, Firouz (Supervisor)
    Abstract
    In this work, a new catalyst based on gold nanoparticles immobilized on magnetic GO (graphene oxide) has been introduced. A new ligand based on pyridine has been used to the functionalization of GO to design robust heterogeneous catalyst for reduction in a short time using a low amount of the catalyst. The prepared catalyst was employed in the synthesis of aromatic amines using various types of nitroarnes in water. This catalyst is readily prepared from available starting materials and also is a reusable catalyst having very good stability to air and moisture. The proposed procedure applied here can conduct the reactions under milder reactions. Finally, due to total removal of the... 

    Recovery of Platinum and Palladium from Waste Catalysts of Petroleum Industry

    , M.Sc. Thesis Sharif University of Technology Asadzadeh, Mojtaba (Author) ; Sajadi, Ali Akbar (Supervisor) ; Matloubi Moghadam, Firouz (Supervisor)
    Abstract
    The petroleum industry is one of the technological applications which more platinum-group metals (PGM) employs. Therefore, the recovery of the PGMs from the waste catalysts of petroleum industry could be an important source to obtain these precious metals, with economic and environmental consequences.
    In this work, the recovery of platinum and palladium from petroleum catalysts has been studied using waste RG-582 and LD-265 catalysts. Both catalyst were characterized through XRF, XRD and AAS. Aqua regia used as a leaching agent and The effect of dissolution temperature and time, liquid/ solid ratio (L/S), size of particles and elimination of coke was investigated. Under optimized... 

    , M.Sc. Thesis Sharif University of Technology (Author) ; Matloubi Moghaddam, Firouz (Supervisor)
    Abstract
    Fused pyrimidines have attracted considerable attention recently in synthetic organic chemistry because of their wide range of biological activities pharmaceutical, therapeutic properties, antibacterial, antiviral, antitumor, and anti-inflammatory activities. We have reported a new and efficient synthesis of dihydro and tetrahydro pyrimidines fused to 2H-chromen-2-oneand cyclohex-2-enone and pyrimidine fused to uracil via two component reaction of 4-amino-2H-chromen-2-one, 3-aminocyclohex-2-enone and6-aminouracilto 1-aryl-N,N'-bis(arylmethylene)methanediaminein the present of iodine as catalyst.Molecular iodine has received considerable attention in the last few years due to inexpensive,... 

    A novel cyber-secure algorithm in cooperative vehicles platoon

    , Article 2023 9th International Conference on Control, Instrumentation and Automation, ICCIA 2023 ; 2023 ; 979-835036601-3 (ISBN) Moghadam, A.S ; Haeri, M ; Sharif University of Technology
    Institute of Electrical and Electronics Engineers Inc  2023
    Abstract
    This paper studies the problem of secure and resilient distributed cooperative control for autonomous vehicles under false data injection attacks on the vehicular communication net-work. We propose a model-based scheme to detect unknown data falsification attacks using the predicted traj ectory in a distributed nonlinear model predictive control problem. First, as a local agent, each autonomous vehicle stores the information received from its neighboring vehicles to clarify anomalies. The recorded data is investigated over a temporal moving observation window which contains different prediction sequences of the distributed nonlinear model predictive control problem in the previous times. In... 

    On The Non-Linear Behavior of Continuous Beam to Column Connection

    , M.Sc. Thesis Sharif University of Technology Rahmani, Ahmad (Author) ; Moghadam, Hasan (Supervisor)
    Abstract
    A special steel beam-to-column connection, named Khor-jini, is commonly used for steel framing system in Iran. In this system, two continuous beams are passed next to the columns and are connected to the column side using seated brackets.This type of connection has been common in Iran from the late past. Unfortunately, the seismic behavior of Khorjini frames had not been sufficiently studied prior to Manjil Earthquake of 1990. Due to very large damages which occurred in steel structures especially in connections during the said earthquake, the seismic behavior of this type of connection was studied and some of its weak points were recognized.In this study non-linear... 

    Lifetime-Aware Resource Allocation in Cloud Computing for Energy Optimization

    , M.Sc. Thesis Sharif University of Technology Moghadam, Marziyeh (Author) ; Goudarzi, Maziar (Supervisor)
    Abstract
    Cloud computing is a way to increase capacity or add capabilities dynamically without investing in new infrastructure. The purpose of this project is the use of specialized algorithms for efficient energy management for cloud computing environments.One of the issues that is very important with respect to cloud computing is considering lifetime of servers or physical machines. Servers are some of the most important and critical elements of cloud computing. Server costseffect on the costs of the entire cloud computing system and the interference of serverseffects on entire system. Lifetime of each sever is dependent on a few factors, the most important of which is the number of switching... 

    Model-Based Reasoning Based on Giere’s Explanation of Model

    , M.Sc. Thesis Sharif University of Technology Hashemi, Amin (Author) ; Heidari, Moghadam (Supervisor)
    Abstract
    In the present research, model-based reasoning is introduced and explained based on Giere’s explanation of model. In other word, this research could be regarded as a reconstruction of model in Giere’s books and papers due to prpose a clear explanation of model-based reasoning. In the second chapter, after the introduction, the concept of model in Giere’s distinguished book, “Explainnig Science: A Cognitive Approach” (1988) is introduced and analyzed. In the second chapter, however, the concept of model in Giere’s recent works is traced. “An agent-based account of model” and “focusing on functionality rather than ontology” could be explained as the two important differences between his... 

    Assessment of three preconditioning schemes for solution of the two-dimensional Euler equations at low Mach number flows

    , Article International Journal for Numerical Methods in Engineering ; Volume 89, Issue 1 , 2012 , Pages 20-52 ; 00295981 (ISSN) Hejranfar, K ; Kamali Moghadam, R ; Sharif University of Technology
    2012
    Abstract
    Three preconditioners proposed by Eriksson, Choi and Merkel, and Turkel are implemented in a 2D upwind Euler flow solver on unstructured meshes. The mathematical formulations of these preconditioning schemes for different sets of primitive variables are drawn, and their eigenvalues and eigenvectors are compared with each other. For this purpose, these preconditioning schemes are expressed in a unified formulation. A cell-centered finite volume Roe's method is used for the discretization of the preconditioned Euler equations. The accuracy and performance of these preconditioning schemes are examined by computing steady low Mach number flows over a NACA0012 airfoil and a two-element... 

    Sol-gel-based molecularly imprinted xerogel for capillary microextraction

    , Article Analytical and Bioanalytical Chemistry ; Volume 404, Issue 5 , September , 2012 , Pages 1597-1602 ; 16182642 (ISSN) Bagheri, H ; Piri-Moghadam, H ; Sharif University of Technology
    Springer  2012
    Abstract
    A novel molecularly imprinted xerogel (MIX) based on organically modified silica (ORMOSIL) was successfully prepared for on-line capillary microextraction (CME) coupled with high-performance liquid chromatography (HPLC). The sol-gel-based xerogel was prepared using only one precursor and exhibited extensive selectivity towards triazines along with significant thermal and chemical stability. Atrazine was selected as a model template molecule and 3-(trimethoxysilyl)propylmethacrylate (TMSPMA) as a precursor in which the propylmethacrylate moiety was responsible for van der Waals, dipole-dipole, and hydrogen-bond interactions with the template. This moiety plays a key role in creation of... 

    Preconditioned characteristic boundary conditions for solution of the preconditioned Euler equations at low Mach number flows

    , Article Journal of Computational Physics ; Volume 231, Issue 12 , 2012 , Pages 4384-4402 ; 00219991 (ISSN) Hejranfar, K ; Kamali Moghadam, R ; Sharif University of Technology
    2012
    Abstract
    Preconditioned characteristic boundary conditions (BCs) are implemented at artificial boundaries for the solution of the two- and three-dimensional preconditioned Euler equations at low Mach number flows. The preconditioned compatibility equations and the corresponding characteristic variables (or the Riemann invariants) based on the characteristic forms of preconditioned Euler equations are mathematically derived for three preconditioners proposed by Eriksson, Choi and Merkle, and Turkel. A cell-centered finite volume Roe's method is used for the discretization of the preconditioned system of equations on unstructured meshes. The accuracy and performance of the preconditioned characteristic... 

    Recent advances in capillary microextraction

    , Article TrAC - Trends in Analytical Chemistry ; Volume 73 , November , 2015 , Pages 64-80 ; 01659936 (ISSN) Bagheri, H ; Piri Moghadam, H ; Sharif University of Technology
    Elsevier  2015
    Abstract
    This review is mostly focused on the recently emerged methodologies for preparing the appropriate extracting media with enhanced capacity, stability and selectivity, which could be used in capillary microextraction (CME). We particularly consider conductive polymers, sol-gel-based materials, monolithic coatings, molecularly-imprinted polymers and xerogels. Moreover, we discuss recent advances in configuration of CME, array capillaries and unbreakable substrates  

    New correlation for calculating natural gas Z-factor

    , Article Hydrocarbon Processing ; Volume 89, Issue 10 , 2010 ; 00188190 (ISSN) Ashrafi Moghadam, A ; Ghotbi, C ; Sharif University of Technology
    2010

    Solving fuzzy quadratic programming problems based on ABS algorithm

    , Article Soft Computing ; Volume 23, Issue 22 , 2019 , Pages 11343-11349 ; 14327643 (ISSN) Ghanbari, R ; Ghorbani Moghadam, K ; Sharif University of Technology
    Springer Verlag  2019
    Abstract
    Recently, Ghanbari and Mahdavi-Amiri (Appl Math Model 34:3363–3375, 2010) gave the general compromised solution of an LR fuzzy linear system using ABS algorithm. Here, using this general solution, we solve quadratic programming problems with fuzzy LR variables. We convert fuzzy quadratic programming problem to a crisp quadratic problem by using general solution of fuzzy linear system. By using this method, the crisp optimization problem has fewer variables in comparison with other methods, specially when rank of the coefficient matrix is full. Thus, solving the fuzzy quadratic programming problem by using our proposed method is computationally easier than the solving fuzzy quadratic... 

    Warm and hot deformation behaviors and hot workability of an aluminum-magnesium alloy using artificial neural network

    , Article Materials Today Communications ; Volume 35 , 2023 ; 23524928 (ISSN) Moghadam, N. N ; Serajzadeh, S ; Sharif University of Technology
    Elsevier Ltd  2023
    Abstract
    In this work, flow stress behavior, softening mechanisms and processing maps during deformation of aluminum-magnesium alloy i.e. AA5052, were investigated. Firstly, tensile tests were carried out in the range of room temperature up to 450 °C under different strain rates between 0.001 s-1 to 0.05 s-1. Then, neural network algorithms together with dynamic materials modeling were employed for determination of stain rate sensitivity parameter and processing maps under different working conditions. Moreover, the governing constitutive equations as well as the activation energies of dynamic strain aging and hot deformation were defined. Accordingly, the processing maps were developed for different... 

    Electrochemical degradation of ciprofloxacin from water: Modeling and prediction using ANN and LSSVM

    , Article Physics and Chemistry of the Earth ; Volume 132 , 2023 ; 14747065 (ISSN) Abbasi, P ; Bahrami Moghadam, E ; Sharif University of Technology
    Elsevier Ltd  2023
    Abstract
    Ciprofloxacin is a widely used antibiotic that is also a persistent contamination that causes major health and environmental risks. This study investigated the electrochemical removal of ciprofloxacin using a boron-doped diamond anode and a non-supportive electrode to get an accurate understanding of the anode's performance. The effects of current density, initial ciprofloxacin concentration, time, pH, and electrolyte concentration on the removal efficiency of ciprofloxacin were investigated. Additionally, ANN and LSSVM models were used to predict ciprofloxacin removal. The results showed that the BDD anode was effective in removing ciprofloxacin from water, with complete removal of 10 mg... 

    Dynamic lane changing control of vehicle platoon

    , Article 2023 31st International Conference on Electrical Engineering, ICEE 2023 ; 2023 , Pages 432-436 ; 979-835031256-0 (ISBN) Saadati Moghadam, A ; Haeri, M ; Sharif University of Technology
    Institute of Electrical and Electronics Engineers Inc  2023
    Abstract
    In this paper, a cooperative approach for control heterogeneous connected and autonomous vehicles (CAVs) platoon considering lane-change maneuvers is proposed. In complex dynamic traffic environment, the speed of the surrounding vehicles of CAVs changes dynamically. Thus, the lane changing vehicle requires considering velocity fluctuations to achieve safe driving. The aim of this study is to combine dynamic path planning based on a cubic curve and model predictive control (MPC) with collision avoidance constraint to track an optimally generated path. The proposed control performs as a maneuver switching model including the vehicle's continuous states and discrete maneuver transition rule for...