Sharif Digital Repository

Different types of morphologies and phase structures of crystalline TiO2 were synthesized by hydrothermal methods. For the first time, dandelion-like rutile TiO2 powder composed of numerous single crystalline nanorods was synthesized using TiCl4 as the main precursor. TiO2 Nanoparticles were produced using TTIP and 2-propanol, as precursor and solvent, respectively. Field emission scanning electron microscopy analyses revealed that the synthesized TiO2 nanoparticles had average crystallite size in the range 21–70 nm, whereas dandelion-like TiO2 showed diameter in the range 2-10 µm. According to the significant refractive index of TiO2, in particular rutile phase, it can be used in the... 

Condition monitoring and operation optimization framework of water and energy hybrid systems has been developed in the present research work, by taking into account the variation in behavior of the system over time under changing environmental conditions. System modeling is performed using the physical laws governing the behavior hybrid energy-water system. In addition, machine learning has been used to estimate the deviation of the mathematical model from system operation, which may be due to the effect of depreciation of machinery parts and other uncertain parameters. Using machine learning and mathematical modeling together results in increased accuracy in predicting system behavior over... 

During recent decade huge number of new malware samples and their complexity have caused challenges to malware detection procedure. additionally the use of kernel level rootkit has been grew up. while rootkits usually defeat current security products which are cheifly relied on Operating system for gathering information and also running, existing nti-rootkit solutions can not cover all kinds of rootkits.In this work we have studied the problem of kernel-level rootkits in Windows operating system. we believe that focusing on kernel drivers features, will result in an overall view needs for monitoring kernel activity of the rootkits. Thus with regards to proves for lower volume of obfuscation... 

Butadiene is one of the most widely used materials in the Iran polymer industry. In order to use this material in the first step, the inhibitor must be separated. Consequently, at the start of the project, the separation of Tert butylcatechol inhibitors from butadiene was studied by the adsorption process on active alumina. The results of the condensed butadiene gas chromatography–mass spectrometry test indicate that, by using the active alumina as an adsorbent, the tert butylcatechol will be removed completely. In the next step, 1,3 butadiene, acrylonitrile, acrylic acid acid terpolymer, which one of its applications is manufacturing of artificial teeth, was synthesized by emulsion... 

This thesis presents the results of three tests to evaluate cyclic behavior of special moment resisting frames (SMRFs) with slitted web section. Typically, in SMRFs energy is dissipated by formation of plastic hinges at the beam ends. Nevertheless, based on the codes, the span-to-depth ratio of beams in SMRFs should be larger than a minimum value to assure the development of plastic hinges with sufficient length at beam ends, reducing application of short span beams. Reduced beam section (RBS) was developed to improve the performance of steel moment frame connections by weakening the flanges at a short distance from the columns. In this thesis, an alternative approach is proposed for short... 

Data collected from street networks show that travel time in urban street networks is a stochastic variable, whose range of variation increases with the congestion level. Work and school trips comprise the major part of morning peak volumes, whose common characteristic is that they need to be made on time. For this reason, these travelers are pessimistic in their route choice, and try to choose routes which are more reliable. Travel time standard deviation is one of the common measures for estimating travel time reliability that is related to properties of day-to-day travel time distribution on a particular route. Based on the empirical data collected from Tehran street network, this paper... 

Noise or noise pollution, is defined as an unwanted sound, produced mostly by motor vehicles in urban areas. If the noise exceeds its limit, adverse effects on users and citizens are expected. Thus the assessment of the noise level and its comparison with allowable values is mandatory. Traffic induced noise depends upon different factors such as traffic, weather, and, sound barriers. Noise pollution study has a long history all over the world. Many studies, mostly representing the outdoor noise pollution models, have been done in recent years. This paper presents an assessment of traffic-induced noise in a heavily traveled tunnel, locally referred to as Resalat tunnel, which is located in... 

In this thesis, we introduce a novel Artificial Intelligence (AI) system inspired by the philosophical and psychoanalytical concept of imagination as a ``Re-construction of Experiences". Our AI system is equipped with an imagination-inspired module that bridges the gap between textual inputs and other modalities, enriching the derived information based on previously learned experiences. A unique feature of our system is its ability to formulate independent perceptions of inputs. This leads to unique interpretations of a concept that may differ from human interpretations but are equally valid, a phenomenon we term as ``Interpretable Misunderstanding". We employ large-scale models,... 

In this research, non-isothermal annealing process at temperatures ranging between 400°C to 830 °C was investigated in warm and cold-rolled austenitic stainless steel 304L. First, the wide variety of austenitic to martensitic structure was produced by the multi-pass rolling process at room temperature -8 °C, 200 °C, and 280°C. The n exponent in Olson-Cohen equation was governed 2.83 after non-linear curve fitting to assess the fraction of deformation-induced martensite as a function of strain. Afterward, Abaqus/Explicit method was utilized to achieve the stored energy and plastic strains distribution through the thickness. Then, Cellular automata and Galerkin-finite element models were... 

Isopropanol purifying denotes dehydration of it to utilize in industries become important these days. Conventional process like distillation could not produce this product in high purity. Using membrane-based process, pervaporation, to dehydrate Isopropanol and other organic compound has been noticed in the last years. Among all type of membranes to dehydrate alcohols, poly (vinyl alcohol) is more effective due to its high hydrophilic characteristic. But it swallows in aqueous solutions and decrease its selectivity. To enhance structural and separation properties Chitosan, TiO2 and glurataldehyde added to polymeric membranes. Nine membranes have been made in this study that can be grouped in... 

composite membranes with PVC as the matrix, Alumina nanoparticles as filler and PVP as additives, were optimized and built. First, the interaction of PVC, PVP and alumina particles on the membrane structure and its performance was investigated by using Design expert software. The membranes which the software proposed were prepared and pure water permeability and flux decline tests were done according to evaluate the membranes performance in membrane bioreactor (MBR). And the results were imported in software and material effects on the performance of each membrane were analyzed. In order to better assess the efficiency and effectiveness of alumina nanoparticles on membrane, different values... 

There are different types of sensors for measuring the concentration of gases that usually have high prices because of their complicated method of production. We can produce much cheaper sensors in special conditions by using polymer membranes. Different gases can be separated by using appropriate polymer membranes and the difference between diffusion rate of these gases is the basis of the separation method and gases pass through the membrane with different flow rates in the specific entrance pressure. The flow rate of total gas which flows will be different for a binary gaseous mixture at specific temperature and pressure with different concentrations because the flow rate is relative to... 

In This thesis the properties of a compatible rubber compound for a specific chemical environment (acidic media) with high temperature and high pressure (HTHP) is studied. After primary studies, six formulations are designed on the basis of Nitrile rubber. after tensile and hardness tests at ambient temperature and 120 °C, samples putted in aging reservoir for aging tests. After that, tensile and hardness tests were performed again. Finally, by analyzing the results, the best formulation have chosen. Test results show that the NBR / PVC compound with higher filler load, has the best chemical resistance  

Clean water is a growing need for humanity all around the Earth. Due to the shortage of clean water resources in most parts of our planet, wastewater treatment and reuse has been of great value in past decades. Much research has been conducted to improve treatment systems. One of the most recent advancements in water and wastewater treatment field is application of membrane bioreactor systems. Despite many advantages of these systems, membrane fouling has been the main drawback since the creation and application of them. The main objective of this research is to investigate the probable fouling reduction and head loss in flat sheet UF membranes due to the application of an anaerobic... 

In this study, the pervaporation method was used for desulfurization of gasoline. Thiophene was used as a sulfur agent and n-heptane as a representative of hydrocarbon compounds in gasoline. The composite membranes of the active PDMS layer containing the UiO-66 metal-organic framework nanoparticles are based on porous membrane PVDF. The effect of adding PVP polymer on the porosity of the PVDF membrane has been investigated. Scanning electron microscopy (SEM), Fourier transform infrared spectrum (FTIR) and X-ray diffraction (XRD) have been used to characterize nanoparticles and synthesized membranes. The effect of adding nanoparticles on the membrane performance and its sowelling effect in...