Sharif Digital Repository

Up to early seventies, Gas turbine combustor design was very time consuming and costly process including trial and errors through test rigs. Over the time analytical-experimental relationships take place as one of the key rules in the design processes. With the increasing power of computer calculations, computational fluid dynamics find its way in the procedure. Obtaining a deeper understanding of flow conditions and geometry inside the chamber, a great reduction in production time and cost of revisions to rigs and samples were achieved. Finding a precise prediction of polluting elements like NOx (less than 10 ppm) after many run hours and enormous computing resources, CFD methods must... 

Fed-batch fermentation is a valuable and cost-effective method for bio-based production of various products such as ethanol, which has various applications in various industries.In recent years, bioethanol production has been given special attention in many countries. For this reason, the mathematical modeling of production of these products is very important for their optimal and cost-effective production. Given the transient and dynamic nature of fermentation and its specific complexity, mathematical modeling of fed-batch bioreactors is difficult and complicated. In this research, an unstructured model was used to predict the production of ethanol from blackstrap sugar cane molasses based... 

Although the moment frame can show deformable behavior against seismic loads, but its flexibility and low stiffness, especially in tall structures, cause the governance criterion to be designed. The use of eccentrically braced frames was able to solve the displacement problem to some extent, because it has the characteristics of both flexural frame systems and conccentric bracing. Different methods have been proposed to eliminate residual displacements in this type of system, one of which is the use of post tensioned cables. The aim of this study was to investigate the seismic behavior of a steel structure with a eccentrically braced frame system with post tension cable.The cables are anchor... 

A Balanced Scorecard (BSC) model is proposed to evaluate performance of Health, Safety and Environment (HSE) management systems. This model includes key performance indicators at three integrated levels. It has been tested and verified in a project-based organization in Iran, active in the area of power and energy. Results show that the company has done well in implementing HSE management processes, but no so well in growth and learning. This model may be used as a basis for comparing different companies and various proposed programs in the field of HSE management systems. The model includes indicators and sub-indicators in each category particularly related to stakeholders, processes, and... 

Fischer-Tropsch process (FT ) is one of the most important processes gas-to-liquid (GTL) conversion. This process converts synthesis gas into hydrocarbons. Depending on the catalyst and operating conditions of the process, heavy paraffins (Wax) are the most important products in this process. These products can be used to heavy paraffin catalyst hydrocracking in a process for the production of diesel fuel and gasoline to lighter products are suitable to be converted. The aim of this project is to develop a suitable kinetic model to describe the process of producing heavy paraffin hydrocracking process Fisher - Tropsch to be lighter products. In this regard, each 5 continuous mass model... 

Articular cartilage Function is vital to joint tasks and its motion. The main biomechanical tasks of articular cartilage are a) the distribution of loads occurred in joints; b) providing joints with frictionless surface. The particular mechanical properties of articular cartilage make it possible for the Cartilage tissue to do its duty successfully. The biological factor that causes articular cartilage to damage is still unknown. It is believed that mechanical factors are the main reason for the cartilage destruction in osteoarthritis. Factors like age, heavy exercises and impact can begin tissue destructions and result in change in mechanical properties. To study the process of the... 

Due to recent advancements and wide usage of location detection devices, huge amount of data are collected by GPS and cellular technologies which exhibits moving objects trajectories. Using this information, it is possible to track a set of objects over a long period of time, as happens for instance in studying animal migration. Always, in these situations it is undesirable or even impossible (due to process and storage limits) to store the complete stream of positioning data. Then, simplifying a trajectory as a data reduction technique is the option for resolving such problems. Moreover, there is an increasing interest in queries capturing ”aggregate” behavior of trajectories as groups like... 

Ease of solar hydrogen production using water splitting and its environmental benefits, distinct hydrogen from other energy carriers. Hydrogen is the most abundant material in the world that make up more than 90% of the world compounds. So applying this material as a clean fuel is the best way to prevent environmental problems caused by fossil fuels. For efficient hydrogen production from water, a suitable electrocatalyst with low overpotential, high mechanical strength and reasonable catalytic activity must be utilized. In this research, cobalt based electrocatalyst was used considering that electrodepositon conditions play an important role in its final efficiency. On the other hand,... 

The bis-cyclometalated platinum(II) complexes [Pt(ptpy)2], 3, and [Pt(fppy)2], 4, in which, ptpy = 2-(p-tolyl)pyridine and fppy = 2-(2,4-difluorophenyl)pyridine have been prepared. The reaction of 3 with one equiv [Au(PPh3)]+ (prepared from the reaction between AuCl(PPh3) and AgOTf) gave the heterobinuclear complex [Pt(ptpy)2Au(PPh3)].OTf, 5, by formation of a Pt→Au dative bond. The structure of all complexes were characterized using multinuclear NMR spectroscopy in solution phase and the structures of 4 and 5 determined using X-ray crystallography in solid state. The structure of heterobinuclear complex 5 shows an unusual Pt-Au bond that supported by Au-Cipso bond. The absorption and...