Sharif Digital Repository

This paper concerns the design of a neural state observer for nonlinear dynamic systems with noisy measurement channels and in the presence of small model errors. The proposed observer consists of three feedforward neural parts, two of which are MLP universal approximators, which are being trained off-line and the last one being a Linearly Parameterized Neural Network (LPNN), which is being updated on-line. The off-line trained parts are able to generate state estimations instantly and almost accurately, if there are not catastrophic errors in the mathematical model used. The contribution of the on-line adapting part is to compensate the remainder estimation error due to uncertain parameters... 

Two tetranuclear Au2Cu2 cluster complexes [Au2Cu2(μ-(PPh2)2py)2(μ-OH)](PF6)3, 2, and [Au2Cu2Cl2(μ-(PPh2)2 py)2](OTf)2, 4, have been prepared by the reactions of precursor complexes [Au2(μ-(PPh2)2py)2](OTf)2, 1, and [Cu2(μ-(PPh2)2py)2(μ-SMe2)(OTf)2], 3, with [Cu(NCCH3)4]PF6 and AuCl(SMe2), respectively. The crystal structures of complexes 2 and 4 were determined by X-ray crystallography, indicating a butterfly-shaped Au2Cu2 metal core for 2 and a planar-shaped Au2Cu2 metal core for 4. In complex 2, the Cu atoms occupy the edge-sharing bond, while in complex 4, alternating Au and Cu atoms occupy the tetragon vertices. The optical properties of the complexes were investigated by experimental... 

This paper deals with the problem of optimal large-angle single-axis maneuvers of a flexible spacecraft with simultaneous vibration suppression of elastic modes. A spacecraft model with a cylindrical hub and one flexible appendage and tip mass is considered. Gravity gradient torque is considered as a disturbance torque. Multilayer perceptron neural networks are used to design a Neural Optimal Controller (NOC) for this multivariable non-linear maneuver. For NOC training, an off-line training procedure based on backpropagation through time algorithm is developed to minimize the general quadratic cost function in forward and backward pass stages. The proposed controller is also applicable to... 

Nano-sized particles of manganese oxides have been prepared by a very simple and cheap process using a decomposing aqueous solution of manganese nitrate at 100 °C. Scanning electron microscopy, transmission electron microscopy and X-ray diffraction spectrometry have been used to characterize the phase and the morphology of the manganese oxide. The nano-sized manganese oxide shows efficient catalytic activity toward water oxidation and the epoxidation of olefins in the presence of cerium(iv) ammonium nitrate and hydrogen peroxide, respectively  

Despite the fact that control charts are able to trigger a signal when a process has changed, it does not indicate when the process change has begun. The time difference between the changing point and a signal of a control chart could cause confusions on the sources of the problems. Knowing the exact time of a process change would help to reduce the time for identification of the special cause. In this article, a model for the change-point problem is first introduced and a maximum-likelihood estimator (MLE) is applied when a linear trend disturbance is present. Then, Monte Carlo simulation is applied in order to evaluate the accuracy and the precision performances of the proposed... 

Incorporation of calcium(ii), zinc(ii) and aluminium(iii) to manganese oxides greatly improved the activity of manganese oxide towards the epoxidation of olefins in the presence of anhydrous tert-butyl hydroperoxide as an oxidant  

Crystal-size distribution (CSD) is one of the most important parameters in sugar production. The objective is to grow crystals of uniform sizes or narrow CSD. CSD appears to be determined by the growth-rate history of the crystals and the relative supersaturation (SS) of the solution from which crystals growth takes place. Three methods for preparation of nucleation seeds were described and used for industrial crystallization of raw and white sugars; these are wet milling filtered sugar (ML), agitating saturated solution (AS) and powdered sugars (PD). Rosin-Rammler (RR) and mathematical models were adopted to investigate CSD and the uniformity of the produced crystals. Higher uniformity... 

Herein we describe the synthesis and characterization of the first platinum(IV) metal-organic cage [(Me3PtIV)8(byp)12](OTf)8 (2), in which the organometallic moieties trimethylplatinum(IV) (PtMe3) occupied the corners of a cubane structure and 4,4′-bipyridine ligands used as linkers. The first-principles density functional theory calculations showed that the highest occupied molecular orbitals were localized on the PtMe3 moieties, while the lowest unoccupied molecular orbitals were distributed on the organic linkers. © 2021 American Chemical Society  

Herein we describe the synthesis and characterization of the first platinum(IV) metal-organic cage [(Me3PtIV)8(byp)12](OTf)8 (2), in which the organometallic moieties trimethylplatinum(IV) (PtMe3) occupied the corners of a cubane structure and 4,4′-bipyridine ligands used as linkers. The first-principles density functional theory calculations showed that the highest occupied molecular orbitals were localized on the PtMe3 moieties, while the lowest unoccupied molecular orbitals were distributed on the organic linkers. © 2021 American Chemical Society  

The six-coordinated silver(I) complex [Au2Ag(μ-(PPh2)2py)2(OTf)2](OTf), 4 (py = pyridine, OTf = CF3SO3), and the five-coordinated silver(I) complex [Au2Ag(acetone)(μ-(PPh2)2py)2](PF6)3, 6, were prepared by the reaction of the precursor complexes 1(OTf)2 and 1(PF6)2, in which 1 = [Au2(μ-(PPh2)2py)2]2+, with 1 equiv of Ag(OTf) in dichloromethane and excess of Ag(PF6) in a mixture of dichloromethane/acetone, respectively. Also, the five-coordinated silver(I) complex [Au2Ag(μ-(PPh2)2py)2(py)(OTf)](OTf)2, 5, was obtained by the reaction of 4 with pyridine. The clusters 4-6 were characterized using multinuclear NMR spectroscopy and elemental microanalysis. The single-crystal X-ray diffraction... 

This paper presents synthesis and photophysical investigation of a very rare type of the ReI diimine complexes, [Re(diimine)(CO)3(OPR3)]+, R = Ph, Cy; diimine – phenanthroline and neocuproine, containing monodentate (unsupported) phosphine oxide ligands. The obtained compounds have been structurally characterized in solid phase by using XRD crystallography, which revealed unusual distortions in the pseudo octahedral rhenium environment, which may be ascribed to intramolecular interligand (phosphine oxide – diimine) interaction rather than to crystal packing effect. Optimization of the ground state structure of these molecules with the DFT method also confirmed intramolecular origin of the...