Sharif Digital Repository

Electrical and magnetic thin films have attracted many researchers’ attentions in random access memories, sensors, actuators and Nano electronic systems industries in recent years. Recent tendencies on decreasing the dimensions of the electronic equipment generate important investigations on coupling the electrical and magnetic properties. In this way multiferroic material as it has these two properties and has a significant between other similar materials, attracted much attention of researchers. So in this research at the first step, it has proceeded to make a multiferroc composite with depositing of barium titanate and strontium hegzaferrite by pulsed laser depositions and for decreasing... 

In this research the microstructural, electrical and optical properties of Strontium Titanate and Barium Strontium Titante thin films, fabricated through Pulsed Laser Deposition (PLD), were investigated. X-ray Photoelectron Spectroscopy and X-ray Diffraction study showed that the stoichiometry of the target material was highly preserved by using PLD method. Scanning Electon Microscopy as well as Atomic Force Microscopy depicted that the using of pressed and sintered target is a suitable metod for improving the surface quality of the thin films. Using the pressed target decreased the quality of the thin films and the average roughness of the films increased. The main reason for this... 

Sialons are materials which crystallize in four elements system (Si-Al-O-N). These materials have been widely observed by researchers because of their suitable properties like: high toughness and strength in high temperatures, high resistance to corrosion and stability in thermal shock. Because of these properties,Sialons are anti erosion materials. In this research, by controling the situations, mullite has been synthesized by sol-gel procedure. Then the powder has been ground by ballmill for 12 hours and by spex for 30 minutes. Then the produced powder was mixed with distinct amount of graphite and nano silica and was nitrided in the furnace at 1500 ̊C and was heated for 5 hours. Also... 

Barium Strontium Titanate (BST) thin films are a promising candidate for dielectric capacitors due to their excellent ferroelectric properties. It is well known that BST has a high dielectric constant, low loss tangent, low leakage current and low Curie temperature. Pulse laser deposition (PLD) has been used extensively as it can maintain the stoichiometry of the target in the deposited film and also has high coverage ability, which both are important in capacitors. In this paper, Ba0.6Sr0.4TiO3 (BST) thin film has been deposited on the SiO2/Si substrate by pulsed laser deposition technique. The effect of post-annealed temperature, oxygen pressure deposition ambience and number of pulses on... 

Particulates are a group of air pollutants. They can enter the respiratory system by breathing and cause adverse effects on its performance. Also, inhaled drugs, recently have found many applications in the field of drug delivery. Prediction of particle deposition in the lungs during breathing, can provide useful information on the effects of deposited particles on the respiratory system. When a person is exposed to breathable particulates, after a while with completion of a few respiratory cycles, particle deposition rate, reaches a certain amount at the quasi-steady state. A lot of researchers have investigated particle deposition in the lung, but all of them have studied a single... 

Environmental heterogeneity, or environmental interactions in evolutionary graphs can drastically change the population dynamics compared to the uniform environment. Such heterogeneity can be imposed in different ways. In this study we choose periodic pattern for the environmental heterogeneity with different values for amplitude and period. Imposing periodic heterogeneity on cyclic graphs, we studied the fixation probability and time. We use birth-death Moran model as the update rule. We observe that with such heterogeneity, an advantageous type in the uniform environment can turn into deleterious in the presence of heterogeneity. Also, the opposite way can happen. The results show that... 

The commercial breakthrough of micro-tubular solid oxide fuel cells (MT-SOFCs) is still facing so many challenges because of the complexity of their manufacturing process and the high cost associated with them. By deploying electrophoretic deposition as a simple and cost-effective method, the different components of the fuel cells (the anode, electrolyte, and cathode) can deposit on the graphite rod as a sacrificial substrate. The next step is eliminating the sacrificial substrate which will make hollow rods of cell components. The results of this study show that the use of a particular type of pencil lead will have a minimal negative impact on the overall fuel cell performance, leading to a... 

In recent years, there are continuous researches on replacing new dielectrics with suitable dielectric properties (including high dielectric coefficient, low loss factor, high breakdown voltage, and high nonlinear coefficient simultaneously). One of these new materials is co-doped titanium oxide with donor and acceptor of electron, which in spite of having high dielectric coefficient and low loss factor. it has low breakdown voltage and researches on improving the disadvantages of this dielectric are ongoing. Due to the structural similarities between tin oxide and titanium oxide, the tin oxide can be an interesting system for studying and improving disadvantages in this field. In this study... 

In this project, synthesis of sol-gel derived Pb(Zr0.52Ti0.48)O3 nanotubes in the form of PZT-CNT hybrid, was accomplished by using multi-walled carbon nanotubes as sacrificial template. Simultaneous thermal analyses proved that the as-derived amorphous material crystallized at a significantly low temperature by a considerably low activation energy. X-ray diffraction and selected area electron diffraction patterns showed that the final crystal structure is tetragonal perovskite. Raman spectroscopy results proved that significant changes happened at the surface of carbon nanotubes which are believed to be due to coating. Electron images supported the deposition of a coating on the surfaces of... 

Particulate porous mateials have always been of interest in terms of reducing shock waves effects in different protective applications. Therefore, the physics governing the flow in porous media is especially significant for which different models have been presented by the researchers. The complexities of these media have caused many existing models to be unable to properly predict the behavior of granular media under shock loadings. On the other hand, the complexity of the equations makes the numerical solution of them cumbersome and costly in a way that many researchers do not solve the whole coupled equations and reduce their number. In addition, current high-resolution TVD solutions of... 

Microemulsion is one of the major processing techniques to synthesize a nano, homogeneous, and almost agglomerate-free powders. Any kind of oxide ceramics such as piezoelectric ceramics can be synthesis via this method in nano scale without the formation of any intermediate phase. In this study, Lead zirconate titanate (PZT) powders with composition near the morphotropic phase boundary (MPB) have been synthesized via a microemulsion processing route. This emulsion system is a thermodynamically stable mixture of oil (cyclohexane), nonionic surfactant (Triton X100), and an aqueous solution containing specific amount of Pb2+, Zr4+ and Ti4+. The ratio of these ions was adjusted with using ICP.... 

Nowday, one of the important goals of researchers is to develop and improve the properties of intermediate tempreture solid oxide fuel cells with range of 600-800˚C. Therefore, choosing the right material as a cathode with good performance in this temperature range is very important. For this purpose, various materials with ionic and electron conductivity mixtures (MIECs) are used, especially oxides with a Radelsden-Paper structure. These oxides are shown by the formula An+1BnC3n+1, which are actually composed of a combination of perovskite layers (ABO3) that are alternately superimposed between two layers of rock salt (AO). In the present study, Sr3Fe2O7 powder with different amounts... 

Interconnects in SOFC’s has oxidation problems which is Because of high temperature operation. Also Cr migration to cathode make chroumiom poisoning problems and all of this affects SOFC’s efficiency. To solve this problem researchers decided to use some protective coating on interconnect. The best group of coatings is Mn-Co Spinels. In this thesis (Mn,Co)3O4 spinels was synthesized via solid state reaction. MC reffered to Mn1.5Co1.5O4 was calcined at 850°C and then sintered at 1200°C. It’s electrical conductivity measured by 4-point probe DC method. It had the lowest ASR (17mΩ.cm2) among other stochiometries. To reduce the sintering temperature, Cu and Y was added as dopants. Among the... 

The main purpose of this research was functionalizing graphene, in order to achieve higher hydrophobicity, and producing nanocomposite of functionalized graphene and titanium dioxide by hydrothermal method, and sequently invastigation on photocatalytic properties of the powders and corrosion properties of EPD coated samples. Graphene oxide was synthesized by improved Hummers method and reduced and sequently was functionalized through the chemical process with hydrazine and octadecylamine respectively. Then the nanocomposite of functionalized graphene-titania was synthesized by use of titanium isopropoxide precursor and its photocatalytic properties were measured. The analysis of the... 

In this thesis, following a short introduction to investment problem, this problem is investigated with both probabilistic and universal approach. Using the concept of the set of reference algorithms, we present a mathematical definition for universality. We then give examples of universal algorithms for investment and prove their universality. These algorithms are:
Universal Portfolios without Side Information, Universal Portfolios with Side Information, Universal Portfolios with Semi-Constant Rebalanced Portfolio, Universal Portfolios with Switching.
We then present a new algorithm called “Universal Portfolio with Multiple Side Information Sources”. This algorithm is applied in... 

Hydroxyapatite is the most substantial inorganic component of bone tissue which displays great biocompability and bioactivity. Nevertheless, its mechanical properties is not appropriate for a bone substitiues. Therefore, it is used to improve the mechanical properties of polymer matrix composite scaffolds. In the present work chitosan as a polymeric matrix was employed to fabricate hydroxyapatite- chitosan biocomposite scaffolds. Sol-Gel method was employed to synthesize hydroxyapatite nano particles. Porous scaffolds were fabricated via freeze-drying by introducing two different cross linkers, Glutaraldehyde and Sodium Tripolyphosphate. Mechanical (compressive strength), biocampability and... 

The fabrication of potassium sodium niobate piezoceramic with oriented microstructure and study of its piezoelectric properties is one of the main objectives of the present study. For this purpose, first the raw materials were synthesized. solid state reaction and topochemical reaction were used for the synthesis of potassium sodium niobate and sodium niobate respectively. The X-ray diffraction results determined that the powder synthesized by the solid state method in the binary system KNbO3-NaNbO3 is closer to the morphotropic phase boundary compared to the powder synthesized in the ternary system Na2CO3-K2CO3-Nb2O5. Particles morphology also includes coarse cubic shape and small equiaxed... 

Solid oxide fuel cells are used to convert solid-state energy to direct electrical current by electrochemistry mixing a gas fuel and an oxidant in an oxide electrolyte. One of the most interesting aspects of this field for the researchers is the reaction between the metal interconnect and the glass sealant. In the current research, deposition of the YSZ coating onto the metal interconnect in order to impede the reaction with glass sealant and prohibition of its oxidation in oxidizing/reducing environment in high temperature, was mainly investigated. Effect of applying YSZ Thin layer in the intersection of Crofer steel and glass sealant on strength and chemical durability of these two...