Sharif Digital Repository

Volatile organic compounds (VOCs) has harmful environmental and health effects and appropriate processes are needed to remove them from industrial and indoor environments. In this study, formaldehyde as one of the most toxic VOCs was investigated. Various methods have been developed to remove formaldehyde, however due to the to their low removal efficiencies, secondary pollution, and low energy efficiency, development of alternative methods will be beneficial. In recent years, the use of a combination of non-thermal plasma and catalyst technologies, called plasma-catalytic hybrid reactors, has provided significant results in the fields of chemical synthesis and removal of pollutants. In the... 

In this study, the micro and nano particles of substituted strontium hexaferrites with nominal composition of SrFe12-xTix/2Znx/2O19 (x=0, 0.5, 1, 1.5, 2 and 2.5) were prepared by a co-precipitaion method. Ferrite-PVA composites (70:30) with thickness of 1.8mm were prepared at 220°C and 50Mpa. X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), field emission scanning electron microscopy (FE-SEM), energy dispersive spectrometer (EDS), vibrating sample magnetometer (VSM) and vector network analyzer (VNA) were employed for characterization of synthesized powders and composites. XRD and FTIR results showed that single phase hexaferrite were obtained for almost all of the... 

In this thesis, following a short introduction to investment problem, this problem is investigated with both probabilistic and universal approach. Using the concept of the set of reference algorithms, we present a mathematical definition for universality. We then give examples of universal algorithms for investment and prove their universality. These algorithms are:
Universal Portfolios without Side Information, Universal Portfolios with Side Information, Universal Portfolios with Semi-Constant Rebalanced Portfolio, Universal Portfolios with Switching.
We then present a new algorithm called “Universal Portfolio with Multiple Side Information Sources”. This algorithm is applied in... 

The airport terminal is difficult to plan and design due to the different components and the intricate complexity of its parts. At the airport terminal, we face a queue system which simulation is always a good way to analyze. In addition, computer simulation using modern softwares with the capability to model different types of systems, including the airport terminal, while being less realistic than analytical models, is less costly than operational Exercise.In this study, a supportive approach for better and specific management of Iranian airport terminal buildings with discrete-event simulation is proposed, considering the need for managing the airport terminals building in the country and... 

Limited water resources in Iran have made dams an important part of the country’s infrastructure. As a result of the large number of in-progress and expected dam projects in the country, consideration of sustainability factors during planning, construction and operation phases of dam projects can create significant economical, social and environmental impacts in the long term. To come up with an inclusive sustainable development, new sustainability assessment approaches seek for sustainable development at the entire project’s life-cycle; they are looking for sustainable development at all design, construction, operation, maintenance and even demolition phases. In this research we have... 

In this research, a powder containing magnesium-aluminate spinel particles is prepared based on co-precipitation method and 5% , 10%, 15% and 20% zirconia-contained composites are produced as second phase from the synthesized powder. The raw materials used in the synthesis comprise hexa-hydrated magnesium nitrate, nona-hydrated aluminum nitrate, ammonium bicarbonate, 28% ammonium solution and distilled water. The properties of the powder is then investigated using STA, XRD and SEM tests. Also, XRD and SEM analyses as well as triple point flexural strength and Vickers hardness tests are carried out in order to investigate the effect of adding zirconia to the powders. The variations of the... 

The purpose of this thesis is the construction of hard and tough Zirconia bodies from economical raw materials using minimum sintering time and temperature.
Stabilizers cause tetragonal particles to be remained in cubic phase. Most additives are Ca, Ce, Mg and Y ions the whole of which are rare earth elements and make solid solutions with Zirconia.
In this project different percents of CaO, MgO, CeO2, and Y2O3 were mixed with ZrO2 and they were sintered after granulation, cold pressing and Cold Isostatic Pressing. Using jar milling and fast milling, the particle size of purchased ZrO2 was reduced to 0.7 um. The whole needed additives were purchased with particle size below 300 nm.... 

In this process transparent polycrystalline alumina ceramic was provided by submicron alumina gel casting and spark plasma sintering. The monomer system in this process including met acrylamide and methylene bis acrylamide was chosen as a monomer and cross linker. These two agents comprise 5%wt of the precursor with the ratio of 3 to 1 respectively. With the optimization of Dolapix CE64 as a dispersant and providing the suspension with 76%wt, a greenware with the density of 56.3% wt was obtained. Differential thermal analysis of green body showed that the existing monomers are removed by the time the body reaches 550°C. In order to access high real in-line transmittance, the microstructure... 

In recent years lithium-air batteries captured worldwide attention because of their high energy density. Solid state electrolytes is one of the main components of lithium-air batteries. Lithium almunium titanium phosphate(LATP) is a nasicon type ion conduction which may be of great potential as solid electrolyte. The object of this thesis was the preparation of LATP solid electrolyte which can be used in a lithium-air battery. To reach this goal LATP powder was synthesized using a solution-based method and an appropriate crystallization temperature was selected based on obtained results of X-ray diffraction analysis. In the next step solid electrolytes was prepared under different pressing... 

The goal of the present study is to analyze the effect of CaF2 and nano-TiO2 as additives on formulation and properties of common dental glass-ceramics. To achieve the goal, a glass system based on SiO2-Al2O3-Li2O-K2O-P2O5-ZnO-ZrO2 was considered to produce glass-ceramic samples and the additives, nano-TiO2 and CaF2, with the 0.5, 1, and 1.5 %Wt was added to the system. After the melting process, the glass samples poured in the water and ferrite was produced. In the next step, the ferrite was milled and pressed. In the heat treatment step, the samples were treated in the temperature range of 650-850°C in order to gain lithium disilicate glass-ceramics. In the last step, the chemical... 

Magnesia-Doloma refractories has advantages such as stability in alkaline environments, clean steel production, resistance to acid slag, good cement kiln coating flexibility, low production cost. It also has some weaknesses such as low resistance to thermal shock and quick hydration. In the present study using Birjand Mines Magnesite powders and Dolomites from Zefreh, Esfahan, Magnesia-Doloma clinkers were pressed under the pressure 90 MP and prepared at 1650⁰C in furnace under air atmosphere. The effect of adding 0, 2, 4, 6, and 8% of the Microparticles and Nanoparticles of α-Alumina on microstructure, physical properties, hydration resistance and Thermal shock resistance was studied. Phase... 

TiO2 has been considered the most promising photocatalyst for the degradation of pollutants in air or water; however, it shows poor absorption of visible light and requires ultraviolet (UV) light for activation. We have successfully synthesized a visible-light-active carbon and nitrogen and yttrium tridoped TiO2 catalyst. In this study, Nanocrystalline photocatalysts of TiO2 doped with yttrium, codoped with carbon and nitrogen and tridoped with carbon and nitrogen and yttrium were prepared by the sol–gel method and investigated by X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), diffuse reflectance spectroscopy ( DRS), Scanning electron microscopy (SEM/EDS) and... 

The main purpose of this research was simultaneous doping of carbon and nickel in the structure of barium strontium titanate, in order to investigate its dielectric and optical properties. Powders and films of BST, was synthesized by the sol-gel method in six different compositions: without any dopant, 0.04mol nickel dopant, 0.04mol nickel dopant accompanied by different amounts of carbon (0.01, 0.02, 0.03 and 0.04 mol). Suspensions were dip coated on alumina and quartz substrates. Structural features and chemical bonds, were studied through thermal analysis, XRD, FT-IR, FESEM and AFM. For electrical and optical properties, LCR-meter and UV-Vis were used. XRD and FESEM proved that nickel... 

This study investigates the effect of titanium dioxide and magnesium oxide additives on hydroxyapatite synthesized by sol-gel and composite with the predominant phase of hydroxyapatite by in situ method to improve mechanical properties. Scaffold samples were synthesized with nanometer-sized hydroxyapatite and composite powder particles by gel casting and sintered at 1200 ° C. Then, to evaluate the synthesized powders, simultaneous thermal analysis (STA), X-ray diffraction test, FTIR test, FESEM, EDS, and MAP analysis were used. Also, to evaluate the mechanical properties of the scaffolds, a compressive test was used, and to evaluate the scaffolds' density, the Archimedes method was used.... 

To reduce material consumption needed in production as well as avoiding thousands of tons of contaminations produced by spent materials in the battery industry, recycling was taken into consideration. In this study silica was recycled from spent lead-acid battery separators by the pyrolysis process. silica along with high-density polyethylene (HDPE), can be used as supporting material for fabricating form-stable phase change materials (FSPCM). FSPCMs are of great ability to be used as thermal energy storage (TES) in different parts of a building e. g. wallboards to reduce energy consumption. In this line, an eutectic mixture of lauric acid, palmitic acid and paraffin with the melting point... 

In this project, the nanostructured titanium oxide with heaily doping of oxides of cerium and tin was synthesized using the sol-gel process and its properties were studied. To synthesize TiO2, titanium tetraisopropoxide precursor was used. Cerium nitrate and aqueous tin chloride precursors were utilized for cerium and tin synthesis. Then, they were mixed with Titania precursor causing a severe doping. After that, a gel was produced and it was aged and eventually, it was dried and calcined. XRD and SEM were used to determine the phase and particle size SEM and XRD results showed that doping had great impact on TiO2 crystals. The approximate size of nanoparticles was calculated using...