Sharif Digital Repository

Molecularly imprinted polymers (MIPs) with synthetic recognition sites are capable of detecting and separating chemical species in complex environments. These characteristics are of increasing interest for bioanalytical applications. The chief advantages of MIPs are mechanical and chemical stability, low cost, and ease of preparation. Recently, imprinting technology has been used for fabrication polymer thin films with recognition sites of proteins, plant viruses, and yeasts. Also few investigations applied lithography for synthesis of cell imprinted polymers targeting cell detection and observation of cell morphology.
For the first time, we demonstrate surface imprinting for the... 

Porous polymeric particles have the extensive application in various sciences and various methods have been introduced for production of these particles. Depending on method of production, porous polymeric beads can be produced in diverse shapes, pore size, pores interconectivity, surface morphology and chemical properties. In common methods for production of porous polymeric particles, tuning the size and porosity is difficult or even impossible. Porous polymeric beads with the vast surface area and good functionality have been applied for adsorption of various materials. The purpose of this study is therefore to investigate a new procedure for the production of porous polymeric... 

In this study, different metal oxides were impregnated on the surface of ZSM-5 employed as photocatalysis for degradation of methylene blue dye used in the presence of ultraviolet light. The final products were characterized by powder X-ray diffraction (XRD) and fourier transform infrared (FT-IR) method. According to the proposed mechanism for the photocatalytic degradation of methylene blue based on these results, it was found that the reaction followed from the first-order mechanism. The results indicated that rate constant for pure ZSM-5 was 9.3〖 ₓ10〗^(-3) (min-1). Furthermore the impregnated ZSM-5 having 12% zinc oxide demonstrated the highest photocatalytic activity with rate constant... 

Disturbance is one of the inseparable components of the mechanical systems which cannot be avoided. In these systems a number of inner and outer sources exist which are the cause of disturbance. Abrupt changes in torque, uncertainty in parameters, mechanical impulses and external forces on robot’s parts all can be mentioned as examples which introduce disturbance that affects the output of mechanical and robotic systems. Therefore, disturbance rejection is considered indispensable in robotic control systems. There are number of problems which are associated with disturbance rejection. In several methods, mostly optimization based methods, system fails to completely reject the disturbance and... 

In this project, after studies about red mud, a product of the Bayer process in production of Alumina, its properties, and characteristics, red mud samples, taken from Jajarm Alumina production unit, were studied, tested, and processed. After primary preparation, characteristic determination experiments were performed on these wastes that contain iron oxide, TiO2, Al2O3, etc., and some of their physical, chemical and mineralogical characteristics were determined. These experiments include chemical analysis, XRD, XRF, compressive strength measurement, grain size distribution, prosity, etc. Considering the properties of this substance and its ceramic usages, processess of making ceramic... 

Nowadays, microfluidic flow appears in many applications, such as medical, biological, and chemical industries. Where as, micromixing, which deals with mixing of microfluidic flow in micro channels, appears to be an important issue to many researchers. In such systems, molecular diffusion plays an important role. On the other hand, lattice Boltzmann method is a relatively new simulation technique for complex fluid systems and has become interesting to many researchers in computational physics. In this study, computational simulation of such mixing process, using LBM is the main objective. Different obstacle layouts inside a microchannel have been investigated. Chaotic advection and jet... 

In the past few decades there has been rapid advance in the use of digital cameras in different fields of art and science. Photo editing softwares have provided extensive facilities for their users and graphic softwares have astonished people with artificial yet fabulous images. Under these circumstances, recognition and distinction of authentic images from digitally-manipulated ones have become a critically important but notoriously daunting task. Users of the internet and computers need to recognize authentic images from the manipulated ones, or distinguish a composite photo from an original one. Digital image forensicsa was born as a response to these demands and has so far provided... 

Hyperbolic branching Brownian motion is a branching diffusion process in which individual particles follow independent Brownian paths in the hyperbolic plane H2, and undergo binary fission(s) at rate λ > 0. It is shown that there is a phase transition in λ : For λ ≤ 1/8 the number
of particles in any compact region of H2 is eventually 0, w.p.1, but for λ > 1/8 the number of particles in any open set grows to ∞ w.p.1. In the subcritical case (λ ≤ 1/8) the set Λ of all limit points in ∂H2 (the boundary circle at ∞) of particle trails is a Cantor set, while in the supercritical case (λ > 1/8) the set Λ has full Lebesgue measure. For λ ≤ 1/8 it is shown that w.p.1 the Hausdorff dimension of Λ... 

The present research was conducted to numerical simulation and phenomenology of the pressure fluctuations and instability of the diffuser with the ratio of the diffuser inlet to the nozzle outlet of 1.91. The numerical simulation has been done with k-ω-SST and k-ω-GEKO turbulence models with both steady and unsteady methods for the nozzle with an expansion ratio of 30. Validation of the numerical solution has been done with the help of the experimental test data of the high-altitude test simulator available in the Research Institute of Space Transportation Systems. Tests were conducted by cold gas. Investigations indicate that two types of start occur in the system, stable and unstable... 

In order to test the performance of engines used at high altitudes, a vacuum simulator system is used. In the vacuum test stand the supersonic exhaust diffuser is used to create the vacuum conditions and the automatic discharge of combustion gases into the atmosphere. usually, the exhaust gas temperature of the engine nozzle is much higher than the temperature that steel body of diffuser can stand (above 2500 K). The purpose of this study is to design and analyze a cooling system to protect the diffusers body. In this study, first by comparing different cooling methods, a spray-cooled water treatment method has been selected for the problem. A new algorithm for designing a spray cooling... 

Depending on the geometry and nozzle pressure, increasing the ratio of the diffuser inlet area to the nozzle outlet area can lead to instability in the high-altitude simulator vacuum chamber startup process. This instability results in the formation of harmonic pressure oscillations throughout the diffuser and the vacuum chamber. In this study, a scaled down second throat diffuser with compressed air has been utilized. The performance of the diffuser has been investigated using four conical nozzles with different expansion ratios to simulate instability at area ratios of 1.27, 1.91, 4.1, and 7.81 with rapid nozzle pressure rise. Experiments were conducted by measuring wall pressures along... 

Recovery of low-rank matrices from compressed linear measurements is an extension for the more well-known topic of recovery of sprse vectors from underdetermined measurements.Since the natural approach (i.e., rank minimization) for recovery of low-rank matrices is generally NP-hard, several alternatives have been proposed. However, there is a large gap between what can be achieved from these alternatives and the natural approach in terms of maximum rank of the unique solutions and the error of recovery. To narrow this gap, two novel algorithms are proposed. The main idea of both algorithms is to closely approximate the rank with a smooth function of singular values and then minimize the... 

In this work, a high-order accurate gas kinetic scheme based on the compact finite-difference Boltzmann method (CFDBM) is developed and applied for simulating the compressible rarefied gas flows. Here, the Shakhov model of the Boltzmann equation is considered and the spatial derivative term in the resulting equation is discretized by using the fourth-order compact finite-difference method and the time integration is performed by using the third-order TVD Runge-Kutta method. A filtering procedure with three discontinuity-detecting sensors is applied and examined for the stabilization of the solution method especially for the problems involving the discontinuity regions such as the shock. The... 

Often in a vacuum test facility, a supersonic exhaust diffuser uses the energy of the outflow from the nozzle to create and maintain a vacuum condition in the engine test chamber. In this system, the temperature of the motor exhaust gas, which directly hits the diffuser walls, is much higher than the tolerance of the metal body of the diffuser. The purpose of this research is to design a cooling system for thermal protection of diffuser walls of a vacuum simulator using a water-jacket tool. At the beginning of this study, the effective parameters in the design of the water-jacket cooling system were identified. Then, a new algorithm to design and optimize the water-jacket cooling system was...