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nematollahi--mohammad-reza
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An experimental and computational study on the rate constant of electrochemically generated n-acetyl-p- quinoneimine with dimethylamine
, Article International Journal of Electrochemical Science ; Vol.3, Issue 10 , September , 2008 , PP. 1092-1107 ; 14523981 ; Haqgu, M. (Mohammad) ; Nematollahi, D. (Davood) ; Gholami, M. R. (Mohammad Reza) ; Sharif University of Technology
2008
Abstract
Electrochemical oxidation of acetaminophen (N–acetyl–p–aminophenol) (1) has been studied in the presence of dimethylamine (2) as a nucleophile in aqueous solution, by means of cyclic voltammetry and controlled-potential coulometry. The results indicate the participation of electrochemically generated N-acetyl-p-quinoneimine (1a) in Michael reaction with dimethylamine (2). Based on ECE mechanism, the observed homogeneous rate constant (kobs) of the above mentioned reaction is estimated by comparing the experimental cyclic voltammograms with the digital simulated results. Further more; kinetics and mechanism of the reaction were studied with ab initio calculation, Monte Carlo and QM/MM...
The Effect of Metal Oxides on Gasochromic Properties of WO3 Thin Films Formed by Pulsed Laser Deposition
, M.Sc. Thesis Sharif University of Technology ; Mahdavi, Mohammad (Supervisor)
Abstract
Physical and chemical properties of tungsten oxide thin films change reversibly while exposure to hydrogen gas. This property is called gasochromic. To enhance optical properties of such films, nanostructured, amorphous and porous thin films of (WO3)1-x(MeO)x (MeO= TiO2, MoO3, NiO; x=0.09, 0.17, 0.23, 0.29, 0.33) were fabricated by Pulsed Laser Deposition. Molar percentage of Me/W (Me= Ti, Mo and Ni) was changed in films with respect to targets; for Ti and Ni always a reduction, but for Mo an enhancement for low percentages was observed. The reason is the existence of thermal ablation mechanism during deposition, in the other word is different vapor pressure effect. An increment in x for...
P Fister’s Local-Global Principle
, M.Sc. Thesis Sharif University of Technology ; Gholamzadeh Mahmoudi, Mohammad (Supervisor)
Abstract
This master’s thesis has two major parts. The first part which includes chapters 1 to 8, describes the article A. Pfister, Quadratische Formen in beliebigen Körpern, Invent. Math. 1, (1966)pp. 116-132, and expresses important facts about the Witt ring W(K) of quadratic forms over an arbitrary field K of characteristic unequal to 2. Among those, it is shown that the order of each element in the additive group of W(K) is a power of 2, the Witt ring doesn’t have any zero divisor of odd dimension and a necessary and sufficient condition for W(K) to be an integral domain is given. The connections between the square class number of a field and the cardinality of its Witt ring and, providing some...
Spectral Theory of Signed Graphs and Digraphs
, Ph.D. Dissertation Sharif University of Technology ; Akbari, Saieed (Supervisor)
Abstract
A signed graph is a pair like (G; ), where G is the underlying graph and : E(G) ! f1; +1g is a sign function on the edges of G. Here, we study the spectral determination problem for signed n-cycles (Cn; ) with respect to the adjacency spectrum and the Laplacian spectrum. In particular we prove that signed odd cycles and unbalanced even cycles are uniquely determined by their Laplacian spectrums, but balanced even cycles are not, and we find all L-cospectral mates for them. Moreover, signed odd cycles are uniquely determined by their spectrums but the signed even cycles, (except (C4;) and (C4; +)), are not and we find almost all cospectral mates for them. A mixed graph is obtained from a...
A misbehavior‐tolerant multipath routing protocol for wireless Ad hoc networks [electronic resource]
, Article International Journal of Research in Wireless Systems (IJRWS) ; Vol. 2, Issue 9, pp. , Sep. 2013 ; Pakravan, Mohammad Reza ; Aref, Mohammad Reza ; Sharif University of Technology
Abstract
Secure routing is a major key to service maintenance in ad hoc networks. Ad hoc nature exposes the network to several types of node misbehavior or attacks. As a result of the resource limitations in such networks nodes may have a tendency to behave selfishly. Selfish behavior can have drastic impacts on network performance. We have proposed a Misbehavior-Tolerant Multipath Routing protocol (MTMR) which detects and punishes all types of misbehavior such as selfish behavior, wormhole, sinkhole and grey-hole attacks. The protocol utilizes a proactive approach to enforce cooperation. In addition, it uses a novel data redirection method to mitigate the impact of node misbehavior on network...
Bilateral Control of a Master-Slave Robotic System for Large-Organ Grasping with Haptic Feedback
, M.Sc. Thesis Sharif University of Technology ; Farahmand, Farzam (Supervisor) ; Behzadipour, Saeed (Co-Advisor)
Abstract
The age of minimally invasive surgery has brought forth astounding changes in the health care field. Less pain and quicker patient recovery have been demonstrated with several types of operations that were once performed by an open technique. With these changes have come reports of complications. The decreased sense of touch is just one of several limitations inherent to current techniques of minimally invasive surgery that limit detection of subtle or unapparent lesions on palpation, such as common duct stones and liver lesions. The purpose of this study is to design and implement a bilateral control on a master-slave robotic system for grasping large ogans and demonstrate the ability of a...
Simulation of Paramecium Swimming in an Environment with a Chemical Gradient
, M.Sc. Thesis Sharif University of Technology ; Ahmadian, Mohammad Taghi (Supervisor) ; Shamloo, Amir (Supervisor)
Abstract
In the recent decade, researchers in the field of minimally invasive medicine have come up to the idea of utilizing micro organisms as smart micro robots. The advantage with this idea is the fact that problems such as energy supply and maneuvering are resolved for these sorts of micro swimmers. In this current work, a new numerical method for investigation of micro swimming is developed which is computationally efficient in characterizing locomotion of micro swimmers and using a finite element method software, locomotion of Paramecium has been investigated inside and outside a capillary tube. According to simulation results, it is possible to design a controlling system which is capable of...
Analysis and Improvement of Intrusion Detection Methods in Data Network Routers
, M.Sc. Thesis Sharif University of Technology ; Aref, Mohammad Reza (Supervisor) ; Pakravan, Mohammad Reza (Co-Advisor)
Abstract
High-quality online services demand reliable and fast packet delivery at the network layer. However, clear evidence documents the existence of compromised routers in the ISP and enterprise networks, threatening network availability and reliability. A compromised router can stealthily drop, modify, inject, or delay packets in the forwarding path to launch Denial-of-Service, surveillance, man-in-the-middle attacks, etc. So researches tried to create intrusion detection methods to identify adversarial routers and switches. To this end, data-plane fault localization (FL) aims to identify faulty links and is an effective means of achieving high network availability. FL protocols use...
Numerical analysis of ciliary beat in Paramecium: Increasing ciliary spacing as a low energy cost method for maneuvering
, Article Recent Patents on Mechanical Engineering ; Volume 6, Issue 3 , September , 2013 , Pages 227-237 ; 1874477X (ISSN) ; Zand, M. M ; Sharif University of Technology
2013
Abstract
In recent years, a number of patents have been devoted to designing micro robots for minimally invasive therapies inspired by Paramecium. Paramecium changes its swimming direction due to application of an external magnetic or electric field. Changing ciliary beat direction and frequency have been identified as possible methods for maneuvering through water; however, effects of variations in ciliary spacing on swimming trajectory have been poorly studied. In this work, it is aimed to analyze the effects of adjusting the ciliary spacing on swimming trajectory. For determining the swimming trajectory, Paramecium membrane is discretized to boundary elements with length of 15μm on which there are...
Topological Defects in Confined Nematics by Planar Anchoring
, M.Sc. Thesis Sharif University of Technology ; Ejtehadi, Mohammad Reza (Supervisor) ; Mozaffari, Mohammad Reza (Supervisor)
Abstract
Confining nematic liquid crystal between two curved boundary conditions while the nematic molecules have a degenerate planar anchoring leads to complex and beautiful textures of molecular disparagement(defect) in the bulk and on the surfaces. Such the liquid crystal shells are made with double-emulsion techniques in microfluidic devices have provided applications for micro-scale colloidal linkers.In this work, we have numerically minimized the elastic energy in one-constant approximation in present of Fournier’s degenerate surface potential with finite element method. The nematic shell is confined between two spherical surfaces that we have studied the final energies and their related...
Solving Symmetric Nonlinear Equations System Using BFGS Trust Region Quadratic Method
, M.Sc. Thesis Sharif University of Technology ; Razvan, Mohammad Reza (Supervisor) ; Peyghami, Mohammad Reza (Supervisor)Effect of the Geometry of Colloidal Particles on Nematic Liquid Crystals
, Ph.D. Dissertation Sharif University of Technology ; Ejtehadi, Mohammad Reza (Supervisor) ; Mozaffari, Mohammad Reza (Co-Advisor)
Abstract
A liquid crystal is a state of matter composed of highly anisotropic building blocks. When liquid crystals are exposed to surfaces with given shapes and anchoring conditions, the orientation of their molecules gets spatially disordered and topological defects may form in the system. The interplay between liquid crystals and the geometry and topology of the colloidal particles has motivated extensive recent studies.In this thesis, we present the numerical modeling results for two faceted colloidal particles in a thermotropic nematic liquid crystal. To obtain the equilibrium nematic field with a finiteelement method, we numerically minimize the free energy of the system that based on the...
Design and Implementation of 2.5 Gbps Circuit Switching Fabric
, M.Sc. Thesis Sharif University of Technology ; Pakravan, Mohammad Reza (Supervisor) ; Movahhedy, Mohammad Reza (Supervisor)
Abstract
Providing high bandwidth network infrastructures for ever increasing need of data transport is of great importance. The underling infrastructure for many communication services such as GSM/3G/4G mobile networks and Internet services is Synchronous Digital Hierarchy (SDH) optical transport systems. SDH are standardized protocols that multiplex multiple lower rate digital bit streams, such as E1 and Ethernet, and transfer them synchronously over optical fiber using lasers or LEDs. In addition to high data transfer rates, flexible network management and protection mechanisms have great importance, hence are part of SDH standards. In order to obtain flexible network architecture and protected...
Preserving Privacy in Smart Grid
, M.Sc. Thesis Sharif University of Technology ; Aref, Mohammad Reza (Supervisor) ; Pakravan, Mohammad Reza (Co-Advisor)
Abstract
Development of Smart Grid and deployment of smart meters in large scale has raised a lot of concerns regarding customers’ privacy. Consequently, several schemes have been proposed to overcome the above mentioned issue. These schemes mainly rely on data aggregation as a method of protecting users’ privacy from the grid operators. However, the main problem with most of these schemes is the fact that they require a large amount of processing power at the meter side. This, together with the fact that smart meters don’t usually have a powerful processor, can cause the unavailability of smart meter data at the required time for operators of the grid, and at the same time disables smart meters from...
Improvement of Routing Security in Ad Hoc Networks Against Several Attacks
, M.Sc. Thesis Sharif University of Technology ; Aref, Mohammad Reza (Supervisor) ; Pakravan, Mohammad Reza (Supervisor)
Abstract
Secure routing is a major key to service maintenance in wireless ad hoc networks. Ad hoc nature exposes the network to several types of node misbehavior or attacks. Wormhole attack is one of the most severe active attacks to mobile ad hoc networks. Noting the resource limitations in such networks, nodes may have a tendency to behave selfishly. Selfish behavior can have drastic impacts on network performance. We have proposed a Misbehavior-Tolerant Multipath Routing protocol (MTMR) which detects and punishes all types of misbehavior such as selfish behavior, wormhole, sinkhole and grey-hole attacks. The protocol utilizes a proactive approach to enforce cooperation. In addition, it uses a...
Solving Nonlinear Systems of Mixed Iqualities and Inequalities Via Trust Region Quadratic Methods
, M.Sc. Thesis Sharif University of Technology ; Razvan, Mohammad Reza (Supervisor) ; Payghami, Mohammad Reza (Supervisor)Jamming Resilient Algorithms for Rendezvous in Cognitive Radio Networks
, M.Sc. Thesis Sharif University of Technology ; Aref, Mohammad Reza (Supervisor) ; Pakravan, Mohammad Reza (Co-Advisor)
Abstract
Dynamic spectrum access with the aid of cognitive radio (CR) technology is a viable solution to spectrum scarcity. There are many military and emergency applications that require the use of cognitive radio ad-hoc networks (CRAHNs). In these net- works, nodes must first find each other in a wide spectrum and then exchange their desired data. The process of finding each other in a multichannel environment is a challenging task and is usually known as rendezvous. Since rendezvous is the first step in communication, disrupting will disable the nodes from establishing proper communication sessions. That results in a drastic degrade in the performance of the network. Therefore, it is important to...
Numerical Study of Spray Impingement to Solid Wall
, M.Sc. Thesis Sharif University of Technology ; Morad, Mohammad Reza (Supervisor) ; Jahannama, Mohammad Reza (Co-Supervisor)
Abstract
Spray-wall impingement is one of the phenomenon that associated in different subject such as spray cooling, combustion chamber and gas turbine. With the impingement of spray to the wall, liquid film begins to form. Wall film characteristics is still an important subject to study. Due to the various stages of liquid film formation from injection of spray till spray-wall impingement, the investigation of this phenomenon is far more complicated. This paper is meant to provide detailed data on spray-wall impingement and wall film formation physics with the help of computational analysis of OpenFOAM . A Lagrangian-Eulerian method based on discrete phase model (DPM) was employed to model...
Assessing and Improving Algorithms to Control the Propagation of Light through Scattering Media
, M.Sc. Thesis Sharif University of Technology ; Rahimitabar, Mohammad Reza (Supervisor) ; Nasiriavanaki, Mohammad Reza (Supervisor)
Abstract
Light propagation through turbid media, such as biological tissues, experience scattering due to inhomogeneous distribution of refractive indices of their microscopic structure. Scattering and diffusion of light not only limit many optical imaging techniques, but are also big challenges for telecommunication, spectroscopy, and other optical techniques. Recently many new imaging methods are developed that work in strongly scattering media such as optical coherence tomography, diffusion tomography, and laser speckle velocimetry. In this thesis, we have studied how wavefront shaping techniques can tackle the problem of scattering. By spatially shaping the wavefront of the incident beam, using...
Enhancing the Accuracy of Temperature and Pressure Variables in Global Weather Models Using Machine Learning and Wavelet Transformation in the Urmia Basin
, M.Sc. Thesis Sharif University of Technology ; Safaie Nematollahi, Ammar (Supervisor)
Abstract
The objective of this research is to enhance the accuracy of temperature and pressure variables derived from global meteorological models such as ERA5 using machine learning and deep learning (ML-DL) techniques. Since variables like temperature and pressure are critical metrics for various processes and decision-making in fields such as agriculture and limnology, and they serve as input variables in most hydrological, hydrodynamic, and meteorological models, accessing high-precision time series with appropriate temporal resolution is of great importance. Currently, global meteorological models like ERA5 provide relatively long time series of these variables on a grid with spatial resolutions...