Sharif Digital Repository

Electrochemical oxidation of acetaminophen (N–acetyl–p–aminophenol) (1) has been studied in the presence of dimethylamine (2) as a nucleophile in aqueous solution, by means of cyclic voltammetry and controlled-potential coulometry. The results indicate the participation of electrochemically generated N-acetyl-p-quinoneimine (1a) in Michael reaction with dimethylamine (2). Based on ECE mechanism, the observed homogeneous rate constant (kobs) of the above mentioned reaction is estimated by comparing the experimental cyclic voltammograms with the digital simulated results. Further more; kinetics and mechanism of the reaction were studied with ab initio calculation, Monte Carlo and QM/MM... 

In recent years, a number of patents have been devoted to designing micro robots for minimally invasive therapies inspired by Paramecium. Paramecium changes its swimming direction due to application of an external magnetic or electric field. Changing ciliary beat direction and frequency have been identified as possible methods for maneuvering through water; however, effects of variations in ciliary spacing on swimming trajectory have been poorly studied. In this work, it is aimed to analyze the effects of adjusting the ciliary spacing on swimming trajectory. For determining the swimming trajectory, Paramecium membrane is discretized to boundary elements with length of 15μm on which there are... 

Paramecium or other ciliates have the potential to be utilized for minimally invasive surgery systems, making internal body organs accessible. Paramecium shows interesting responses to changes in the concentration of specific ions such as K+, Mg2+, and Ca2+ in the ambient fluid. Some specific responses are observed as, changes in beat pattern of cilia and swimming toward or apart from the ion source. Therefore developing a model for chemotactic motility of small organisms is necessary in order to control the directional movements of these microorganisms before testing them. In this article, we have developed a numerical model, investigating the effects of Ca2+ on swimming trajectory of... 

Herein, the CO methanation reaction is studied over Ni/Fe–Al mixed oxides with various Fe and Al contents. The mesoporous nanocrystalline supports are prepared by a novel sol–gel process using propylene oxide as a gelation agent. The deposition–precipitation method is used for the deposition of nickel on the catalyst support. The samples are characterized by Brunauer–Emmett–Teller (BET), X-ray diffractometry (XRD), temperature programmed reduction (TPR), temperature programmed oxidation (TPO), scanning electron microscopy (SEM), and transmission electron microscopy (TEM). The results indicate that increasing the iron content and reducing the Al percentage in the catalyst support reduces the... 

In this paper, a comprehensive study was conducted on the application of various MeAl2O4 spinels (Me = Fe, Co, Ni, Cu, Zn, Mg) as the catalyst support for the preparation of nickel-based catalysts in the combined dry reforming and partial oxidation. These supports were synthesized by a novel facile sol-gel method using propylene oxide as the gelation agent and nickel was deposited on these supports by the deposition-precipitation method. The prepared samples were characterized by N2 adsorption/desorption, XRD, TPR, TPO, CO2-TPD, SEM, and TEM techniques. In addition, the temperature-programmed methane dissociation (TPMD) was performed to evaluate the effect of nickel-support interaction on... 

A circular zero-sum flow for a graph G is a function f: E(G) → R { 0 } such that for every vertex v, ∑e∈Evf(e)=0, where Ev is the set of all edges incident with v. If for each edge e, 1 ≤ | f(e) | ≤ r- 1 , where r≥ 2 is a real number, then f is called a circular zero-sum r-flow. Also, if r is a positive integer and for each edge e, f(e) is an integer, then f is called a zero-sum r-flow. If G has a circular zero-sum flow, then the minimum r≥ 2 for which G has a circular zero-sum r-flow is called the circular zero-sum flow number of G and is denoted by Φ c(G). Also, the minimum integer r≥ 2 for which G has a zero-sum r-flow is called the flow number for G and is denoted by Φ (G). In this... 

Photocatalytic reduction of CO2 is considered as a promising strategy for production of a wide range of renewable hydrocarbon fuels by solar energy. In this investigation, a series of Ni and Bi doped TiO2 catalysts with different Ni and Bi contents were synthesized by the conventional sol-gel method and tested for CO2 photoreduction under visible light irradiation. Synthesized nano-photo-catalysts were characterized by XRD, FESEM, TEM, DRS, PL, FTIR and BET analyses. BET results indicated that the doping of Ni or/and Bi in the TiO2 framework resulted in BET specific surface area increment with respect to pure TiO2. DRS analysis showed that Ni doped TiO2, Bi doped TiO2, and co-doped samples... 

A signed graph is a pair like (G,σ), where G is the underlying graph and σ:E(G)→{−1,+1} is a sign function on the edges of G. In this paper we study the spectral determination problem for signed n-cycles (Cn,σ) with respect to the adjacency spectrum and the Laplacian spectrum. In particular, for the Laplacian spectrum, we prove that balanced odd cycles and unbalanced cycles, denoted, respectively, by C2n+1 + and Cn −, are uniquely determined by their Laplacian spectra (i.e., they are DLS). On the other hand, we determine all Laplacian cospectral mates of the balanced even cycles C2n +, so that we show that C2n + is not DLS. The same problem is then considered for the adjacency spectrum,... 

Wind turbine size has increased to megawatt capacity, and the related technologies and facilities have improved, including the cooling systems. Currently, all of the heat generated by wind turbine components is wasted to the environment. This study presents a conceptual design of a novel method for waste heat recovery of a wind turbine using an organic Rankine cycle (ORC). An organic Rankine cycle is implemented to the wind turbine as a part of the cooling system. The proposed system is thermodynamically modeled to evaluate the amount of recovered energy. Seven working fluids are chosen and investigated in the simulations to estimate the working fluid effect. The results revealed that the... 

A mixed graph is obtained from a graph by orienting some of its edges. The Hermitian adjacency matrix of a mixed graph with the vertex set {v1,…,vn}, is the matrix H=[hij]n×n, where hij=−hji=i if there is a directed edge from vi to vj, hij=1 if there exists an undirected edge between vi and vj, and hij=0 otherwise. The Hermitian spectrum of a mixed graph is defined to be the spectrum of its Hermitian adjacency matrix. In this paper we study mixed graphs which are determined by their Hermitian spectrum (DHS). First, we show that each mixed cycle is switching equivalent to either a mixed cycle with no directed edges (Cn), a mixed cycle with exactly one directed edge (Cn 1), or a mixed cycle... 

Electrochemical oxidation of acetaminophen (N-acetyl-p-aminophenol) (1) has been studied in the presence of dimethylamine (2) as a nucleophile in aqueous solution, by means of cyclic voltammetry and controlled-potential coulometry. The results indicate the participation of electrochemically generated N-acetyl-p-quinoneimine (1a) in Michael reaction with dimethylamine (2). Based on ECE mechanism, the observed homogeneous rate constant (kobs) of the above mentioned reaction is estimated by comparing the experimental cyclic voltammograms with the digital simulated results. Further more; kinetics and mechanism of the reaction were studied with ab initio calculation, Monte Carlo and QM/MM... 

In this contribution, spinel MgAl2O4 nanospheres prepared by the combustion method were coupled with thermally-exfoliated g-C3N4 nanosheets (TE-GCN) through an efficient isoelectric point-assisted calcination technique. Physical characteristics of the synthesized nanocomposite were understudied utilizing the XRD, FT-IR, FE-SEM, TEM, BET-BJH, UV–Vis DRS, PL, and EIS analyses. This material was used as a novel nano-photocatalyst for degradation of reactive red 195 (RR195) industrial dye contaminant. Results revealed that, a successful synthesis of a heterojunction between the components of the nanocomposite was achieved. This exhibited an enormously improved electron-hole separation leading to... 

Let G be a graph with the vertex set {v1,…,vn}. The Seidel matrix of G is an [Formula presented] matrix whose diagonal entries are zero, ij-th entry is −1 if vi and vj are adjacent and otherwise is 1. The Seidel energy of G, denoted by [Formula presented], is defined to be the sum of absolute values of all eigenvalues of the Seidel matrix of G. Haemers conjectured that the Seidel energy of any graph of order n is at least [Formula presented] and, up to Seidel equivalence, the equality holds for Kn. Recently, this conjecture was proved for [Formula presented]. We establish the validity of Haemers’ Conjecture in general. © 2020 Elsevier Ltd  

Image processing applications employ various filters for several purposes, such as enhancing the images and extracting the features. Recent studies show that filters in image processing applications take a substantial amount of the execution time, and it is crucial to boost their performance to improve the overall performance of the image processing applications. Image processing filters require a significant amount of data sharing among threads which are in charge of filtering neighbor pixels. Graphics Processing Units (GPUs) attempt to satisfy the demand of data sharing by providing the scratch-pad memory, shuffle instructions, and on-chip caches. However, we observe that these mechanisms...