Sharif Digital Repository

We study Hydrogen sulfide gas detection properties of pure and 1% copper oxide added WO3 thin films. The spin coated deposits on alumina substrates were annealed at 500 C for 1 hour in order to improve the crystallinity of the films. The sensitivity of pure tungsten oxide is poor even at temperatures of about 100 C but the doped samples exhibit good response to H2S gas. Our data show sensitivity of about 1500 in 10 ppm diluted gas in air at 100 C. The films are sensitive to the gas even at 250 ppb (sensitivity about 2) H2S concentration at 100 C but with rather long recovery time. Crystal structure, morphology and chemical composition of samples were studied by X-Ray diffraction (XRD),... 

Cuprous oxide powder was added to WO3 sol as a catalyst and the composite sol was deposited on alumina substrates by spin coating process and annealing at 500 °C for 1 hour. Sensing properties of the pure and doped tungsten oxide samples to H2S gas were analyzed. WO 3-Cu2O (1%) samples showed good sensitivity towards 250 ppb of the gas at 100 °C and 1 ppm at room temperature (25 °C). Crystal structure, morphology and chemical composition of the sample were studied by X-ray diffraction (XRD), Scanning Electron Microscopy (SEM), Energy Dispersive X-ray (EDAX) analyses and X-ray photoelectron spectroscopy (XPS). Based on these data, possible reaction mechanisms of hydrogen sulfide over WO... 

Modeling and analysis of information system vulnerabilities helps us to predict possible attacks to networks using the network configuration and vulnerabilities information. As a fact, exploiting most of vulnerabilities result in access rights alteration. In this paper, we propose a new vulnerability analysis method based on the Take-Grant protection model. We extend the initial Take-Grant model to address the notion of vulnerabilities and introduce the vulnerabilities rewriting rules to specify how the protection state of the system can be changed by exploiting vulnerabilities. Our analysis is based on a bounded polynomial algorithm, which generates the closure of the Take-Grant graph... 

We study the translocation of stiff polymers through a nanopore, driven by the chemical-potential gradient exerted by binding proteins (chaperones) on the trans side of the pore. Bound chaperones prevent backsliding through the pore and, therefore, partially rectify the polymer passage. We show that the sequence of chain monomers with different binding affinity for the chaperones significantly affects the translocation dynamics. In particular, we investigate the effect of the nearest-neighbor adjacency probability of the two monomer types. Depending on the magnitude of the involved binding energies, the translocation speed may either increase or decrease with the adjacency probability. We... 

Combining the advection-diffusion equation approach with Monte Carlo simulations we study chaperone driven polymer translocation of a stiff polymer through a nanopore. We demonstrate that the probability density function of first passage times across the pore depends solely on the Péclet number, a dimensionless parameter comparing drift strength and diffusivity. Moreover it is shown that the characteristic exponent in the power-law dependence of the translocation time on the chain length, a function of the chaperone-polymer binding energy, the chaperone concentration, and the chain length, is also effectively determined by the Péclet number. We investigate the effect of the chaperone size on... 

The amount of rippling in graphene sheets is related to the interactions with the substrate or with the suspending structure. Here, we report on an irreversibility in the response to forces that act on suspended graphene sheets. This may explain why one always observes a ripple structure on suspended graphene. We show that a compression-relaxation mechanism produces static ripples on graphene sheets and determine a peculiar temperature Tc, such that for T