Sharif Digital Repository

The crystallization behavior of fluorphlogopite, a glass-ceramic in the MgO-SiO2-Al2O3-K2O-B 2O3-F system, was studied by substitution of Li 2O for K2O in the glass composition. DTA, XRD and SEM were used for the study of crystallization behavior, formed phases and microstructure of the resulting glass-ceramics. Crystallization kinetics of the glass was investigated under non-isothermal conditions, using the formal theory of transformations for heterogeneous nucleation. The crystallization results were analyzed, and both the activation energy of crystallization process as well as the crystallization mechanism were characterized. Calculated kinetic parameters indicated that the appropriate... 

Nickel-dimethylglyoxime complex (NiDMG) modified nickel electrode (Ni/NiDMG) showed a catalytic activity towards methanol oxidation in NaOH solution. The modified electrode prepared by the dimethylglyoxime anodic deposition on Ni electrode in the solution containing 0.20 mol L-1 NH4Cl + NH4OH (pH 9.50) and 1.0 × 10-4 mol L-1 dimethylglyoxime. The modified electrode conditioned by potential recycling in a potential range of 100-700 mV (vs. SCE) by cyclic voltammetry in alkaline medium (0.10 M NaOH). The results show that the NiODMG film on the electrode behaves as an efficient catalyst for the electrooxidation of methanol in alkaline medium via Ni(III) species formed on the electrode with the... 

The effects of various ratios of Fe/Ni/MgO and growth temperatures on yield, diameter and quality of multi-walled carbon nanotubes (MWCNTs) were studied. Thermal gravimetric analysis (TGA) confirmed that the MWCNT yield depends on Fe/Ni ratio with the following order; Fe0.5 Ni0.5 > Fe > Fe0.75 Ni0.25 > Fe0.25 Ni0.75 > Ni. The results indicated that there is an optimum temperature (940 °C) for the MWCNT growth both from quality and quantity (yield) aspects as compared to other temperatures. Moreover, the changes on Fe/Ni to MgO ratio for the MWCNT growth revealed that Fe/Ni/MgO with the ratio of 17.5/17.5/65 had the highest quality and surface area as compared to the other ratios. The... 

The effects of HCl, HNO3, H2SO4 and HF acids on the purification and the electrochemical hydrogen storage of multi-walled carbon nanotubes (MWCNTs) were studied. The MWCNTs were synthesized on Fe-Ni catalyst by thermal chemical vapor deposition method. The X-ray diffraction and thermal gravimetric analysis results indicated that the MWCNTs purified by HF acid had the highest impurities as compared with the other acids. The N2 adsorption results at 77 K indicated that all the samples were mainly mesoporous and the purified MWCNTs by HF acid had the highest surface area as compared with the other acids. The hydrogen storage capacities of the purified MWCNTs by the following acids were in... 

The heat transfer Magnetohydrodynamics flows have been potentially used to enhance the thermal characteristics of several systems such as heat exchangers, electromagnetic casting, adjusting blood flow, X-rays, magnetic drug treatment, cooling of nuclear reactors, and magnetic devices for cell separation. Our concern in this article is to numerically investigate the flow of an incompressible Magnetohydrodynamics micropolar fluid with heat transportation through a channel having porous walls. By employing the suitable dimensionless coordinates, the flow model equations are converted into a nonlinear system of dimensionless ordinary differential equations, which are then numerically treated for... 

The purpose of the paper is to develop a mathematical foundation for exploring the complex interaction of Coriolis and Lorentz forces with the electromagnetohydrodynamic (EMHD) flow of a power-law fluid inside a microchannel with wall slip condition. Both the Lorentz and Coriolis forces act orthogonally to each other. Mathematical modeling of the problem is based on a set of classical Maxwell and Navier–Stokes equations, which are subsequently solved numerically by employing an implicit finite difference methodology. The numerical solution thus obtained has been found to be in an excellent agreement correlation with the ones reported in the scientific literature, for some limiting cases. A... 

Nano-fluids have considerable importance in the field of thermal development that relates to several industrial systems. There are some key applications in recent construction systems flow, as well as microscale cooling gadgets and microstructure electric gadgets for thermal migration. The current investigation concludes the study of electrically conducting nano-fluid flow and heat transfer analysis in two-dimensional boundary layer flow over a curved extending surface in the coexisting of magnetic field, heat generation and thermal radiation. The small sized particles of copper (Cu) are taken as nanoparticles and water is assumed to be the base fluid. We used quasi-linearization and central... 

Vortices grab the attention of many scientists while analyzing any flow model due to their importance in interpreting fluid mixing and mass transport phenomena. Since vortices exist in the natural environment, so researchers need to investigate them whenever they are encountered. Solar collectors, automobile cooling, engine applications, thermal management, and machine cutting, are just a few of the major areas in which most hybrid nanofluids could help to improve overall performance. The goal of this study is to demonstrate the highly complex dynamics of a Lorentz force, which governs the rotation of nanoparticles and the composition of the complex configuration of eddies inside the fluid... 

This work addresses the preparation of self-flowing lightweight aggregate foamed concrete (LAFC) resulting from the mixing of stable foam, expanded clay aggregate (ECA) and silica fume (SF) as main raw materials. Formulated LAFC mixtures were tested for the mechanical, thermal, sorption and high-temperature resistance properties. Results showed that the increase in the volume of foam from 0% to 20% considerably improved the flowability of LAFC and LAFC mixtures were categorized into high stable visual stability index. Compressive strength of LAFC mixtures was reduced from 24.75 MPa to 21.10, 15.95 and 12.05 MPa respectively when foam volume was increased from 0% to 10, 15 and 20%. Thermal...