Sharif Digital Repository

Nowadays cobalt is mostly produced through the electrowinning process of sulfate solutions. Regarding to the competition between the precipitation of cobalt ions and evolution of hydrogen gas on the cathode surface during the reduction process in a sulfate bath, investigation on the mechanism of metal precipitation is of great importance. In the present work, study on the kinetics of cobalt electrowinning and the mechanism of the involved reactions have been carried out. The obtained results, confirm the mechanism of cobalt precipitation by depletion of hydroxides. The effects of temperature and scan rate parameters were studied on electrowinning of cobalt by cyclic voltammetry technique.... 

In this report the important factors affecting the levitation melting of nickel are discussed. The relationship between the temperature of a levitated sample to factors such as coil design, gas flow rate, power input, and sample weight are studied. Different coil designs were investigated and compared. It was found that for satisfactory sustained levitation melting, the sample weight, depending on the material, must be within a particular range. Furthermore, increasing the power input would result in a decrease in the droplet temperature; and increasing the weight of the sample results in an increase in the temperature. The flow rate of a cooling gas has a reverse relationship to the... 

The ion exchange process is a promising method for lithium extraction from brine and seawater having low concentrations of this element. To achieve this goal, it is vital to use an effective adsorbent with maximum lithium adsorption potential together with a stable structure during extraction and insertion of the ions. In this study, titanium dioxide and then lithium titanate spinel with nanotube morphology was synthesized via a simple two-step hydrothermal process. The produced Li4Ti5O12 spinel ternary oxide nanotube with about 70 nm diameter was then treated with dilute acidic solution in order to prepare an adsorbent suitable for lithium adsorption from local brine. Morphological and... 

The ion exchange process is a promising method for lithium extraction from brine and seawater having low concentrations of this element. To achieve this goal, it is vital to use an effective adsorbent with maximum lithium adsorption potential together with a stable structure during extraction and insertion of the ions. In this study, titanium dioxide and then lithium titanate spinel with nanotube morphology was synthesized via a simple two-step hydrothermal process. The produced Li4Ti5O12 spinel ternary oxide nanotube with about 70 nm diameter was then treated with dilute acidic solution in order to prepare an adsorbent suitable for lithium adsorption from local brine. Morphological and... 

One-dimensional (1D) MgO structures were successfully synthesized via carbothermic reduction of mechanically activated mixture of MgO and graphite. Mechanical activation of source materials before carbothermic reduction can substantially enhance the formation of MgO products at a temperature (1000 °C) relatively lower than that required in previous approaches (≥1200 °C). However, the morphology of MgO formed is dependent on the degree of mechanical activation and the condition of the subsequent carbothermic reduction. Two distinctive morphologies were found for MgO products synthesized using our method: single crystalline nanorods with rectangular cross-sections whose diameters range from 50... 

A mixture of MgO and graphite with a molar ratio (1:1) was subjected to planetary ball milling for 1, 2, 4, and 8 h with the intention of enhancing carbothermic reduction reaction of MgO during subsequent thermal treatment. Unmilled and milled mixtures were characterized using a combination of X-ray diffraction (XRD) analysis, Raman spectroscopy, scanning electron microscopy (SEM), surface area analysis (SSA), and thermogravimetric analysis (TGA). The reduction reaction of milled samples occurred at lower temperature than that of the unmilled sample. A longer milling time engenders a lower reaction temperature. These results are attributable to the increased interfacial area of the sample... 

Secure routing is a major key to service maintenance in ad hoc networks. Ad hoc nature exposes the network to several types of node misbehavior or attacks. As a result of the resource limitations in such networks nodes may have a tendency to behave selfishly. Selfish behavior can have drastic impacts on network performance. We have proposed a Misbehavior-Tolerant Multipath Routing protocol (MTMR) which detects and punishes all types of misbehavior such as selfish behavior, wormhole, sinkhole and grey-hole attacks. The protocol utilizes a proactive approach to enforce cooperation. In addition, it uses a novel data redirection method to mitigate the impact of node misbehavior on network...