Sharif Digital Repository

Sulfur compounds are very undesirable and result in Corrosion in metal equipment, air pollutions and poisoning of refinery Catalysts such as reforming Catalyst. Therefore, application of Hydrodesulfurization (HDS) process in order to decrease the amount of sulfur in petroleum cuts has a great importance. HDS process is the most usual and efficientmethod for sulfur removal. In this method sulfur compounds at vigorous operating conditions such as high temperature and pressure in the presence of catalyst react with hydrogen and produce hydrogen disulfide and hydrocarbon. Sulfided Co–Mo catalysts are widely used in this process.
The aim of this study is to prepare and improve CoMo/γ-Al2O3... 

Common Object Request Broker Architecture (CORBA) is a standard for hybrid applications that is designed and supported by Object Management Group (OMG). This standard defines protocols and Relational Data Model Objects / Services which can be connected into heterogeneous software (written in different languages). So we can use CORBA to share the distributed object platform, without worrying about where they are located or who has designed them. CORBA can package the codes (in some programming languages) and add the packaging information, such as the ability to execute the codes and how to implement them. So this package or object code can execute some other programs or CORBA objects that... 

The purpose of this thesis is to design haptic control system for vehicle steering mechanism in a tele-driving system. Thus the subject is a developed subject in comparison with a steer by wire system. The difference is that in the steer by wire system, due to the lack of delay in sending and receiving data, possibility of instability is very low. This subject makes haptic control more difficult in vehicle tele-driving. Control of vehicle tele-driving steering system has been done by different bilateral control structures available in the literature. simulation results of the case that there is no delay in the transmission block suggest that used different control structures in order to... 

SIS and SIR are common models for describing and predicting the epidemics of the contagious diseases. But these models fail to predict patterns of spreading dynamics in the case of co-infective diseases, i.e. getting infected by one disease, alters the chance of getting infected by the other one. Coinfection has been studied in the mean field approximation and on complex networks with different topologies. Another study shows temporal correlations of the underlying transmission network, play role on co-infection dynamics.In this research we investigate the effects of various temporal correlation on epidemic order parameters of independent infection and co-infection.For this purpose, we... 

Kinetics and mechanism of 4,4-dicyano-5-ethyl-1,5-heptadiene rearrangement reaction, a pericyclic type reaction, were studied with ab initio calculations in gas and solution phases. This reaction is one of the cope rearrangement in which secondary kinetic isotope effect is observed. Theoretical study on these reactions showed that probability of radicalic mechanism is inconsiderable and reaction proceeds through out a concerted mechanism with cyclic transition state. Isotope effect was studied by replacement of H1, H2 and H4,H5 with deuterium. The isotope effect data confirmed the concerted mechanism. Solvent effects on this reaction were studied by CPCM model. Solvation energies at... 

An understanding of the effect of degree of cementation on static and dynamic behaviour of cemented soils is becoming increasingly important in design and analysis of geotechnical engineering problems. Naturally cemented coarse-grained soils are widely present in many parts of the world. Misunderstanding of the behaviour of such soils could lead to underestimate or overestimate of the soil parameters. Previous studies conducted by Haeri and his co-workers show that most of the alluvial deposit of Tehran, the capital city of Iran, has a soil with cemented nature. The amount and characteristics of the cementation of the deposit varies in different parts from highly cemented in the north to... 

In Hemodialysis, membrane dialyser and commonly hollow fibers are used to treat patients who suffer from end stage renal failure. When blood flows into membrane, it loses uremic toxins such as urea and creatinine. On the other hand, some of the vital proteins of blood pass through the membrane or they are adsorbed on the membrane surface. The more hydrophilicity of the membrane, the less adsorption of proteins is. In this study, to achieve high hydrophilicity and low adsorption of proteins on the polysulfone membrane surface, the presence of hydrophilic nano-particles SBA-15 in membrane composition is investigated. The nano-particles with mass percentages 0.25%, 0.5 % and 1 % to one mass of... 

The low female labor force participation rate in the Iranian labor market relative to the global average and even to countries that do not differ significantly from the socio-economic characteristics of our country is one of the important questions of the Iranian labor market. In this study, we seek to answer the question of whether the economic participation rate of married women will increase if the gender gaps in wages, job findings and job losses among women and men are eliminated in the Iranian labor market. To answer this question using household expenditure and income data and labor force data, we show that between the two categories of occupations, in terms of the share of women's... 

Fatigue crack growth can have harmful effects on the reliability rotary machine. While an early warning to crack, can be used to extend the life of these expensive machines and increase reliability.Structural Vibration Condition Monitoring as a primary fault detection method, achieved to a lot amazing result and for this reason studies vibration behavior of cracked rotational shaft is a big issue for engineers of dynamic machine.In this research, first check the fault detection methods based on structural vibration condition monitoring, mode shape methods were extracted. Then by modeling rotational shaft in computer and creation of crack on it, fault detection quality of these methods have... 

In the present study, the effects of increasing the value of shale gas production, either due to increased production or price increases, have been studied on economic variables such as employment, wage, property value and the number of births. In this regard, the data for each of these variables was used at the county level in the United States of America between 2000 and 2011. In order to estimate the desired effects, counties are divided into two types of boom and non-boom counties. The findings indicate that increasing natural gas production will lead to more employment and wage growth in boom counties than non-boom counties. Also, during the period of increasing production, the value of... 

It is important to provide an appropriate and economically method with technical and engineering considerations to stabilize excavated underground spaces. The necessity of this, especially for the construction of underground metro stations located in the cities which faces many problems, is more evident. In this research, it has been tried to introduce an optimal method according to the type of area for the construction of the underground station. In order to obtain stress and strain condition in structural elements and surface deformations due to different stages of excavating, numerical modeling in FLAC3D has been used. By examining the parameters that affect the sustainability of this... 

In this study, we aim to learn representations from microscopic cell images that effectively capture the features of drugs affecting the cells, allowing us to identify effective drugs for treating a disease. We employ two parallel learning paths using predictive and generative models. Specifically, we have achieved a predictive model on the RxRx19a dataset that, unlike previous models, is interpretable, optimized, and robust to dras- tic changes in drug properties. Additionally, we have developed the first generative model on this dataset, which not only generates high-quality images but also discovers a meaningful latent space. This latent space divides the representation into relevant... 

Co-movement between inflation and nominal interest in response to an interest rate shock, dubbed neo-fisherianism, has been the subject of contentious debate since the advent of non-inflationary ZLB environment. We design an economic model rich with banking features to understand the economic responses to permanent and long-term interest rate shocks. We find that responses to a permanent positive interest rate shock depend on the monetary authorities’ speculation of the new long-term inflation rate, with the most probable outcome being a permanent increase in inflation. Responses to a long-term positive interest rate shock depict an increase and then decrease in inflation. We also discover... 

Influence of excavating the Tehran metro line 7 tunnel on surface settlement, stresses and deformations induced in Towhid tunnel is investigated using numerical modeling. Construction of Metro tunnel as the new one must be carried out without imposing any damage to the Towhid tunnel as the existing tunnel. Towhid tunnel is a set of twin tunnels along the Chamran highway in Tehran. The tunnels were constructed using sequential excavation method and lined with cast in place reinforced concrete; on the other side metro line 7 is being constructed using 2 EPB tunnel boring machines and lined with reinforced concrete segments. This research consists of the study of the effects of pillar width,... 

Foam injection for enhanced oil recovery is concerned by petroleum engineers because it decreases adverse effects of fingering and gravity segregation caused by the injected fluid .Obviously foam stability is an important factor in the efficiency of this process. So investigating it is an imperative. One of the ways that less studied and can improve foam stability is using of nanoparticles. In this project effect of nanoparticles on foam stability and displacement mechanism during foam flooding has been discussed.
Study consisted of two sets of experiments. In the first part, the static foam stability in the presence of silica nanoparticles has been investigated. Also influence of... 

Miscible displacement in fluid flowing through a porous medium plays an important role in many environmental and industrial applications; for instance, miscible displacements in enhanced oil recovery processes and pollutant spreading in groundwater. A large number of numerical approaches have been developed to solve the advection-dispersion equation that describes the behavior of miscible displacement in porous media. Most of these numerical models suffer from numerical dispersion. Random walk seems to be an effective method to overcome this problem especially in heterogeneous media. Here, a random walk model was developed and used for simulating miscible displacement in heterogeneous porous... 

The use of air bearings was began the last decade. Oil-free air bearing technology is implemented in rotating machines such as turbines, Micro gas turbines and turbocharged, this technology has improved the efficiency of rotating systems. In rotating machines, at high speeds, passing through the critical speed happens. As a result, the natural frequency of the system is crossing the critical speed, which causes system instability and lack of system amplitude control. Instability causes damage to the system. The aim of this thesis is to investigate the nonstationary vibrations of a flexible rotor with air bearings in the passing critical speeds. Behavior of air bearings is also considered to...