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Immobilized palladium nanoparticles on silica functionalized N-propylpiperazine sodium N-propionate (SBPPSP): Catalytic activity evaluation in copper-free Sonogashira reaction
, Article Journal of the Iranian Chemical Society ; Volume 10, Issue 6 , 2013 , Pages 1291-1296 ; 1735207X (ISSN) ; Deris, A ; Panahi, F ; Hormozi Nezhad, M. R ; Sharif University of Technology
2013
Abstract
An efficient heterogeneous palladium catalyst system has been developed based on immobilization of Pd nanoparticles on silica-bonded N-propylpiperazine sodium N-propionate (SBPPSP) substrate. SBPPSP substrate can stabilize the Pd nanoparticles effectively so that it can improve their stability against aggregation. In addition, grafted piperazine species on to the silica backbone prevent the removing of Pd nanoparticles from the substrate surface. Transmission electron microscopy (TEM) of catalyst is shown the size of Pd nanoparticles, also it confirmed by particle size analyzer which shown the average size of 21 nm for Pd. The catalytic activity of these catalysts was investigated in the...
An investigation on the effect of cement and silica fume on properties of self-compacting concrete
, Article Proceedings of the 13th East Asia-Pacific Conference on Structural Engineering and Construction, EASEC 2013 ; September , 2013 ; Atashnama, A ; Panahi, M ; Gharebaghi, R ; Mahlouji, J ; Sharif University of Technology
Hokkaido University collection of Scholarly Academic Papers, HUSCAP
2013
Abstract
Self-Compacting concrete (SCC) is identified as a high performance concrete with the ability of self compaction, using its own weight without any external vibration. SCC is able to fill congested area and voids, even in highly reinforced concrete members whilst it flows without segregation. The fresh properties of SCC such as workability can be determined using different tests including slump-flow, J ring, V-funnel, U box, L box, GTM and column technique. In this paper the effect of different amount of cementitious material, silica fume and W/C ratios on workability and compressive strength of SCC are investigated. The results indicate that the workability of mixtures is reduced by...
A unified computational method for simulating dynamic behavior of planing vessels
, Article China Ocean Engineering ; Volume 23, Issue 3 , 2009 , Pages 517-528 ; 08905487 (ISSN) ; Jahanbakhsh, E ; Panahi, R ; Karimi, M. H ; Sharif University of Technology
2009
Abstract
High speed planing hulls have complex hydrodynamic behaviors. The trim angle and drafts are very sensitive to speed and location of the center of gravity. Therefore, motion simulation for such vessels needs a strong coupling between rigid body motions and hydrodynamic analysis. In addition, free surface should be predicted with good accuracy for each time step. In this paper, velocity and pressure fields are coupled by use of the fractional step method. On the basis of integration of the two-phase viscous flow induced stresses over the hull, acting loads (forces and moments) are calculated. With the strategy of boundary-fitted body-attached mesh and calculation of 6-DoF motions in each time...
Accurate detection and recognition of dirty vehicle plate numbers for high-speed applications
, Article IEEE Transactions on Intelligent Transportation Systems ; Volume 18, Issue 4 , 2017 , Pages 767-779 ; 15249050 (ISSN) ; Gholampour, I ; Sharif University of Technology
Institute of Electrical and Electronics Engineers Inc
2017
Abstract
This paper presents an online highly accurate system for automatic number plate recognition (ANPR) that can be used as a basis for many real-world ITS applications. The system is designed to deal with unclear vehicle plates, variations in weather and lighting conditions, different traffic situations, and high-speed vehicles. This paper addresses various issues by presenting proper hardware platforms along with real-Time, robust, and innovative algorithms. We have collected huge and highly inclusive data sets of Persian license plates for evaluations, comparisons, and improvement of various involved algorithms. The data sets include images that were captured from crossroads, streets, and...
Large scale image search
, M.Sc. Thesis Sharif University of Technology ; Moghaddasi, Reza (Supervisor)
Abstract
Searching for images of the same object or scene in a large number of images is a major problem in computer vision. It has many applications specially in the search engines.For the goal of efficient image search, we need descriptors that are not only discriminative, but also short and need small amount of memory.In this thesis we analyze the image search methods in two categories: The first methods are based on converting the existed descriptors such as gist into a compact binary code. The second methods are based on building short descriptors, especially by some modifications in the framework of bag of features descriptor.Finally we will introduce a novel descriptor "bag of codes" which...
Chemical Modification of Glassy Carbon Electrode by Carbon Nanostructures/Conductive Polymers Composites and Its Application in The Study of Electrochemical Behaviour and Determination of Salbutamol and Isoprenaline
, M.Sc. Thesis Sharif University of Technology ; Shahrokhian, Saeed (Supervisor)
Abstract
In the first part of thesis, the electropolymerization of pyrrole was performed in the presence of new coccine (NC) as a dopant anion on the surface of the electrode precoated with SWCNT. The modified electrode was used to study the voltammetric response of salbutamol (SAL). The results showed a remarkable increase in the anodic peak current of SAL in comparison to the bare GCE. The surface morphology PPY/CNT/GCE was thoroughly characterized by scanning electron microscopy (SEM) and cyclic voltammetry (CV) techniques. Under the optimized analysis conditions, the modified electrode showed two linear dynamic ranges of 0.02 – 0.1 μM and 0.1-10 μM with a detection limit of 6 nM for the...
Resource Allocation in Multi-project Scheduling with Resource Transfer Time and Cost
, M.Sc. Thesis Sharif University of Technology ; Shadrokh, Shahram (Supervisor)
Abstract
The project scheduling problem is one of the classic problems in project management that includes a range of optimization problems. One of the limitations we face in project scheduling problem is the resource constraint limitation. In many studies in the literature review, problems are based on the false assumption that a resource can be transferred between activities of a project or different projects without spending time and cost. The resource availability method in many fundamental researches in the context of resource constrained project scheduling problem (RCPSP) is considered as resource investment problems (RIP); while in many real world projects resources are rented for projects and...
Simultaneous alpha and gamma discrimination with a phoswich detector using a rise time method and an artificial neural network method
, Article Applied Radiation and Isotopes ; Volume 154 , 2019 ; 09698043 (ISSN) ; Feghhi, S. A. H ; Moghadam, S. R ; Zamzamian, S. M ; Sharif University of Technology
Elsevier Ltd
2019
Abstract
We used two digital methods—rise time discrimination (RTD) and an artificial neural network (ANN)—to simultaneously discriminate alpha particles and gamma rays detected by a phoswich detector (50 μm BC-400 coupled to 3 mm CsI(Tl)). The results for 10,000 pulses discriminated by the RTD method showed that the rise time distribution of the pulses is rather vast (between 200 and 800 ns for gamma rays and less than 40 ns for alpha particles). The same result was also observed in the dual-parameter diagram (pulse rise time versus area under the pulse) for an 241Am source. Then, as another approach, three pulse features—rise time, pulse height ratio, and charge ratio—were extracted from 2000...
Development a Double Cell Triaxial Permeameter for Measuring Saturated Hydraulic Conductivity of Highly Deformable Soils
, M.Sc. Thesis Sharif University of Technology ; Sadeghi, Hamed (Supervisor)
Abstract
The measurement of saturated hydraulic conductivity in conventional methods is based on the assumption of non-deformable porous media. However, this assumption is violated in most cases, especially when dealing with highly deformable soils such as collapsible and expansive soils. An alternative is to use flexible wall triaxial devices, yet the deformation characteristics during wetting and sample saturation are missed. This issue is of great importance in soils with considerable amount of volume changes (e.g., problematic soils). It should be noted that errors included in measuring sample volume changes, water inflow/outflow rates, and the creation of sidewall leakage are essential factors...
Synthesis of some new 1,4-distyrylbenzenes using immobilized palladium nanoparticles on silica functionalized morpholine as a recyclable catalyst
, Article Synthesis ; Issue 10 , 2011 , Pages 1609-1615 ; 00397881 (ISSN) ; Gharavi, A ; Nezhad, M. R. H ; Panahi, F ; Sharbati, M. T ; Sharif University of Technology
2011
Abstract
Some new 1,4-distyrylbenzene derivatives were synthesized by using immobilized palladium nanoparticles on silica-bonded N-propyl morpholine (PNP-SBNPM) as a heterogeneous catalyst. These one-pot reactions afforded a range of stereoselective, symmetrical (E)-1,4-distyrylbenzene derivatives with high yields (78-90%). The green catalyst system is recyclable and allows facile product isolation. The recycled catalyst could be reused six times without appreciable loss of catalytic activity
Enhanced electrochemical activity of a hollow carbon sphere/polyaniline-based electrochemical biosensor for HBV DNA marker detection
, Article ACS Biomaterials Science and Engineering ; Volume 5, Issue 5 , 2019 , Pages 2587-2594 ; 23739878 (ISSN) ; Shahrokhian, S ; Panahi, S ; Sharif University of Technology
American Chemical Society
2019
Abstract
Herein, we present a novel, simple, and ultrasensitive electrochemical DNA (E-DNA) sensor based on hollow carbon spheres (HCS) decorated with polyaniline (PANI). A thiolated 21-mer oligonucleotide, characteristic of HBV DNA, is immobilized via electrodeposited gold nanoparticles on HCS-PANI. Cyclic voltammetry (CV), differential pulse voltammetry (DPV), and electrochemical impedance spectroscopy (EIS) are used to characterize the electrochemical properties of the prepared nanocomposite. Scanning electron microscopy is employed to investigate the morphological texture of the fabricated modifier. An enhanced intrinsic signal of PANI is probed to evaluate the biosensing ability of the prepared...
Nonlinear forced vibration analysis of micro-rotating shaft–disk systems through a formulation based on the nonlocal strain gradient theory
, Article Archives of Civil and Mechanical Engineering ; Volume 23, Issue 2 , 2023 ; 16449665 (ISSN) ; Asghari, M ; Borjalilou, V ; Sharif University of Technology
Springer Science and Business Media Deutschland GmbH
2023
Abstract
The paper presents an upgraded size-dependent formulation for micro-rotating shaft–disks system to study their nonlinear forced vibration behavior. The novel formulation is based on the nonlocal strain gradient theory (NSGT). To achieve this goal, first of all, by incorporating the geometrical nonlinearity within the Rayleigh beam theory, the governing equations of the lateral motion of the system are derived by the Hamilton principle and then converted into a complex form. By defining some dimensionless parameters, the normalized form of the complex governing equation is also extracted. In the next step, the Galerkin method is implemented to establish an infinite set of ordinary...
Error Resilient Coding of H.264 for Wireless Networks
, M.Sc. Thesis Sharif University of Technology ; Kasaei, Shohreh (Supervisor)
Abstract
Nowadays, wireless communications for multimedia purposes is widely spreaded especially due to video communication demands. One of important considerations in this area is to receive video stream with less effect of errors related to transition channel as well as optimal utilization of bandwidth. The H.264 is exploited as the most efficient video compression standard and because of its predictive nature of encoder and decoder, it is very sensitive to error propagation, so error resilient technics should be applied along with the video compression to reduce the visual impacts of error occurrence and propagation. In this thesis existing methods of video error resilience, video quality measures...
Guarding a Terrain by Watchtowers
, M.Sc. Thesis Sharif University of Technology ; Zarei, Alireza (Supervisor)
Abstract
Guarding terrains(or covering terrains) is a well known problem in the field of visibility and computational geometry. The aim of this problem is to select a minimal set of elements (such as points on terrain, line segment, points above terrain ,...),as guard set, such that every point of the terrain is visible from at least one member of the guard set.
This problem was introduced in 2-dimensions as art gallery problem. Various types of this problem have been defiend and studied in the literature. Guarding 3-dimensional terrains is an example of this problem. In 3-dimentional case, the guarded terrain can be modeled with triangulated irregullar network(TIN), as one of the surface models,...
This problem was introduced in 2-dimensions as art gallery problem. Various types of this problem have been defiend and studied in the literature. Guarding 3-dimensional terrains is an example of this problem. In 3-dimentional case, the guarded terrain can be modeled with triangulated irregullar network(TIN), as one of the surface models,...
Forced Vibration Analysis of Rotating Micro-Shaft Based on the Non-local Strain Gradient Theory
, M.Sc. Thesis Sharif University of Technology ; Asghari, Mohsen (Supervisor)
Abstract
Nowadays, with progresses made in manufacturing technologies, it is possible to produce micro-scale products such as micro-electromechanical systems. Micro-motors are one type of these systems that can be used in such applications as power supply of electronic devices. To achieve a better performance, these systems must rotate at high rotational speeds (about one million revolutions per minute). At such a high rotational speed, vibrational analysis is highly crucial. The results of recent studies indicate the inability of classical theories of continuum mechanics to analyze the behavior of these micro systems. Therefore, in this research, the rotor of micro-motors are modeled using the...
Fabrication of Vascularized Scaffold Containing Cardiac Tissue-derived Decellularized Extracellular Matrix Using Bioprinter
, M.Sc. Thesis Sharif University of Technology ; Mashayekhan, Shohreh (Supervisor)
Abstract
In this study, a new bioink was introduced for the production of tubular tissue structures for cardiac tissue engineering by bioprinter using the FRESH (Freeform Reversible Embedding of Suspended Hydrogels) method. The novel bioink that we used was a combination of cardiac extracellular matrix (cECM) and oxidized alginate. The cardiac extracellular matrix was used to increase the biomimetic of the printed structures to the actual tissue of the body, and also to create sites for cell adhesion, and to improve cell growth and survival. We used alginate oxide (oxidation degree: 5%) to increase the mechanical properties of the tissue. Alginate oxidation has been due to extracellular matrix (ECM)...
The Effect of Shear Connectors in the Protected Zone of the Connection of Composite Beams to Steel Columns
, M.Sc. Thesis Sharif University of Technology ; Kazemi, Mohammad Taghi (Supervisor)
Abstract
The use of concrete and steel composite structural systems has been extensively studied both numerically and experimentally. Composite concrete and steel beams consist of a steel beam on which the concrete slab is constructed using shear connections. The performance of concrete slabs and steel beams in steel composite concrete structures is generally provided by welded shear connectors on the upper flange of the steel beam. In this study, a more accurate model in numerical form will be conducted to investigate the effect of shear connectors installed in the composite beam in the critical area of beam to column connection, which is considered as a protected zone. The main objective of this...
Electromechanical resonator based on electrostatically actuated graphene-doped PVP nanofibers
, Article Nanotechnology ; Volume 24, Issue 13 , 2013 ; 09574484 (ISSN) ; Mohammadi, S ; Zad, A. I ; Sarvari, R ; Shariat Panahi, S. P ; Jokar, E ; Sharif University of Technology
2013
Abstract
In this paper we present experimental results describing electrical readout of the mechanical vibratory response of graphene-doped fibers by employing electrical actuation. For a fiber resonator with an approximate radius of 850 nm and length of 100 m, we observed a resonance frequency around 580 kHz with a quality factor (Q) of about 2511 in air at ambient conditions. Through the use of finite element simulations, we show that the reported frequency of resonance is relevant. We also show that the resonance frequency of the fiber resonators decreases as the bias potential is increased due to the electrostatic spring-softening effect
Terahertz time domain spectroscopy for mixture detection: A quantitative study
, Article 4th International Conference on Millimeter-Wave and Terahertz Technologies, MMWaTT 2016, 20 December 2016 through 22 December 2016 ; 2017 , Pages 17-19 ; 21570965 (ISSN); 9781509054145 (ISBN) ; Yahyaei, B ; Kouhanestani, M. K ; Mousavi, M ; Darbani, M. R ; Majde, A. E ; Sharif University of Technology
Institute of Electrical and Electronics Engineers Inc
2017
Abstract
Terahertz spectroscopy is a useful and an efficient method for detection of pure materials and also mixture compounds. In the present study the terahertz spectra of the α-lactose, high explosives RDX and also the binary mixture of mentioned materials has been obtained in the transition mode. The obtained spectra of the pure materials were in a very good agreement with literatures in the range of 0.1 to 1.5 terahertz. The spectra of mixture samples which show the specific fingerprint characters of each component, declare that terahertz spectroscopy can be used effectively for the detection of explosives and chemical compounds even in the mixture samples. © 2016 IEEE
Effect of samarium oxide on the electrical conductivity of plasma-sprayed SOFC anodes
, Article JOM ; Volume 68, Issue 10 , 2016 , Pages 2569-2573 ; 10474838 (ISSN) ; Samadi, H ; Nemati, A ; Sharif University of Technology
Minerals, Metals and Materials Society
2016
Abstract
Solid oxide fuel cells (SOFCs) are rapidly becoming recognized as a new alternative to traditional energy conversion systems because of their high energy efficiency. From an ecological perspective, this environmentally friendly technology, which produces clean energy, is likely to be implemented more frequently in the future. However, the current SOFC technology still cannot meet the demands of commercial applications due to temperature constraints and high cost. To develop a marketable SOFC, suppliers have tended to reduce the operating temperatures by a few hundred degrees. The overall trend for SOFC materials is to reduce their service temperature of electrolyte. Meanwhile, it is...