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papari-moghaddam-borazjani--sadegh
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Mathematical Modeling of Slurry Reactor for Direct Synthesis of Dimethyl ether from Syngas and Carbon Dioxide
,
M.Sc. Thesis
Sharif University of Technology
;
Kazemeini, Mohammad
(Supervisor)
Abstract
In this study, both axial dispersion and perfect mix mathematical model to simulate a three-phase slurry bubble column reactor for direct synthesis of dimethyl ether (DME) from syngas and CO2 is developed. This large-scale reactor is modeled by using mass and energy balances, catalyst sedimentation and single-bubble as well as; two-bubbles’ class flow hydrodynamics. A comparison between the two hydrodynamic models with pilot plant experimental data from the literature showed that heterogeneous two-bubbles flow model is in better agreement with the experimental data than homogeneous single-bubbles gas flow model. Also, by investigating the heterogeneous gas flow and axial dispersion model for...
Mathematical modeling of a slurry reactor for DME direct synthesis from syngas
, Article Journal of Natural Gas Chemistry ; Volume 21, Issue 2 , March , 2012 , Pages 148-157 ; 10039953 (ISSN) ; Kazemeini, M ; Fattahi, M ; Sharif University of Technology
2012
Abstract
In this paper, an axial dispersion mathematical model is developed to simulate a three-phase slurry bubble column reactor for direct synthesis of dimethyl ether (DME) from syngas. This large-scale reactor is modeled using mass and energy balances, catalyst sedimentation and single-bubble as well as two-bubbles class flow hydrodynamics. A comparison between the two hydrodynamic models through pilot plant experimental data from the literature shows that heterogeneous two-bubbles flow model is in better agreement with the experimental data than homogeneous single-bubble gas flow model. Also, by investigating the heterogeneous gas flow and axial dispersion model for small bubbles as well as the...
Modelling-based optimisation of the direct synthesis of dimethyl ether from syngas in a commercial slurry reactor
, Article Chinese Journal of Chemical Engineering ; Volume 21, Issue 6 , June , 2013 , Pages 611-621 ; 10049541 (ISSN) ; Kazemeini, M ; Fattahi, M ; Sharif University of Technology
2013
Abstract
In the present study, we developed a multi-component one-dimensional mathematical model for simulation and optimisation of a commercial catalytic slurry reactor for the direct synthesis of dimethyl ether (DME) from syngas and CO2, operating in a churn-turbulent regime. DME productivity and CO conversion were optimised by tuning operating conditions, such as superficial gas velocity, catalyst concentration, catalyst mass over molar gas flow rate (W/F), syngas composition, pressure and temperature. Reactor modelling was accomplished utilising mass balance, global kinetic models and heterogeneous hydrodynamics. In the heterogeneous flow regime, gas was distributed into two bubble phases: small...
Well Injectivity during CO2Geosequestration: A Review of Hydro-Physical, Chemical, and Geomechanical Effects
, Article Energy and Fuels ; Volume 35, Issue 11 , 2021 , Pages 9240-9267 ; 08870624 (ISSN) ; Bedrikovetsky, P ; Borazjani, S ; Mahani, H ; Sharif University of Technology
American Chemical Society
2021
Abstract
Deep saline aquifers are among the most favorable geological sites for short- and long-term carbon geosequestration. Injection of CO2 into aquifers causes various hydro-physical, chemical, and geomechanical interactions that affect the injectivity of wellbores. Despite the extensive research conducted on carbon capture and storage (CCS), there exists a lack of focus on the concept of injectivity. The present study aims to identify the gaps by reviewing the major factors contributing to CO2 injectivity in deep saline aquifers. Moreover, the existing analytical and numerical mathematical models to estimate maximum sustainable injection pressure and pressure build-up are critically reviewed....
Effecive & efficient DSM configuration guidelines for low-cost development of complex systems
, Article Gain Competitive Advantage by Managing Complexity - Proceedings of the 14th International Dependency and Structure Modelling Conference, DSM 2012, 13 September 2012 through 14 September 2012 ; 2012 , Pages 125-137 ; 9783446433540 (ISBN) ; Sharif University of Technology
Institution of Engineering Designers
2012
Abstract
With the proliferation of more complex systems has come the need to find better solutions in both technical and management domains. Such complex systems are usually larger in size, have more parallel operations and contain more complex interfaces (Eisner, 2005). The Design Structure Matrix is a very useful tool in handling such complexities, provided that the system designer can use it properly. This paper addresses how effectiveness & efficiency are defined for a DSM and how these two important characteristics can be achieved. The importance of understanding the solution space in constructing an effective & efficient DSM is discussed and general guidelines are given on configuring the DSM...
Dme direct synthesis from syngas in a large-scale three-phase slurry bubble column reactor: transient modeling
, Article Chemical Engineering Communications ; Vol. 201, issue. 5 , Nov , 2014 , pp. 612-634 ; ISSN: 00986445 ; Kazemeini, M ; Fattahi, M ; Fatahi, M ; Sharif University of Technology
2014
Abstract
In this research, a new transient mathematical model based upon tanks-in-series configuration was developed to simulate the direct synthesis of dimethyl ether (DME) from syngas in a commercial-scale slurry bubble column reactor. A comparison between the simulation results and experimental data showed that the applied model might acceptably describe the behavior of the slurry reactor. Furthermore, simulation results in the heterogeneous bubble flow regime indicated that the proposed model with 10 tanks-in-series provided the optimum condition. Utilizing this transient model and considering catalyst deactivation, the effect of operating conditions on DME productivity and CO conversion were...
Aspects of alkaline flooding: Oil recovery improvement and displacement mechanisms
, Article Middle East Journal of Scientific Research ; Volume 18, Issue 2 , 2013 , Pages 258-263 ; 19909233 (ISSN) ; Ahadi, A ; Kordnejad, M ; Borazjani, Z ; Sharif University of Technology
2013
Abstract
Alkaline flooding is one of the newest chemical enhanced oil recovery (EOR) methods. Alkaline generates in situ surfactants when in reacts with acid content of the oil. This economic surfactant generated in oil-water interface, reduces interfacial tension (IFT) significantly that leads to increase in oil recovery by extracting oil from tiny pores. In this study, three alkaline i.e. Na2CO3, NaOH and KOH in various concentrations were flooded in a glassy micromodel to detect displacement mechanisms and compare oil recovery. According to the results, increase in alkaline concentration leads to increase in recovery. However, in this case, alkaline type does not play a significant role. In...
Modeling and control of dissolved oxygen concentration in the fermentation of glucose to gluconic acid
, Article Periodica Polytechnica: Chemical Engineering ; Volume 57, Issue 1-2 , 2013 , Pages 63-70 ; 03245853 (ISSN) ; Bamdad, H ; Papari, S ; Yaghmaei, S ; Sharif University of Technology
2013
Abstract
Fermentation systems are often highly nonlinear, with poorly understood dynamic behaviour of the reactor. In this work, mathematical modeling of the fermentation process based on aeration rate control was performed in a semi-batch airlift loop bioreactor. The bioconversion of glucose to gluconic acid by the Aspergillus niger strain was considered in an oxygen consuming system in the liquid phase. The proper kinetic model for the bioconversion of glucose to gluconic acid was investigated using experimental data from a 40 dm3reactor. Kinetic parameter estimation was used from the literature. The model was validated by experimental data and was compared with the Monod kinetic model. The...
Thin Film Thickness Measurement Using Colors of Interference Fringes
, M.Sc. Thesis Sharif University of Technology ; Amjadi, Ahmad (Supervisor)
Abstract
There are several methods for measuring thin film thickness, however, for the analysis of liquid film motors [1] we need a method which is capable of measuring the thickness using a single image of the film. In this work, we use the colors that appear on thin films, such as soup bubbles, which is a result of light interference to calculate the thickness of the layer
Measure for Macroscopic Quantumness via Quantum Coherence and Macroscopic Distinction
, M.Sc. Thesis Sharif University of Technology ; Raeisi, Sadegh (Supervisor)
Abstract
One of the most elusive problems in quantum mechanics is the transition between classical and quantum physics. This problem can be traced back to the Schrodinger's cat. A key element that lies at the center of this problem is the lack of a clear understanding and characterization of macroscopic quantum states. Our understanding of Macroscopic Quantumness relies on states such as the Greenberger-Horne-Zeilinger(GHZ) or the NOON state. Here we take a first principle approach to this problem. We start from coherence as the key quantity that captures the notion of quantumness and demand the quantumness to be collective and macroscopic. To this end, we introduce macroscopic coherence which is the...
Structural Health Monitoring using Bayesian Optimization of the finite element model of structures and Kalman filter
, M.Sc. Thesis Sharif University of Technology ; Bakhshi, Ali (Supervisor)
Abstract
With confidence in the recorded observations, the RLS method no longer estimates the recorded measurements by sensors, i.e. the displacement and speed of the floors, and only estimates the parameters. In contrast, in the EKF method, in addition to estimating the structure's parameters, a more precise estimation of the observations recorded by the sensors has been done by accepting the noise in the recorded observations. These methods, which are based on the Bayesian updating, investigate the two primary sources of uncertainty in a problem: a) measurement noise or observation noise, and b) process noise, which includes modeling errors. In these methodologies, the unknown system parameters,...
Comparison of two methods of iridium impregnation into HZSM-5 in the methanol to propylene reaction
, Article Catalysis Communications ; Volume 16, Issue 1 , 2011 , Pages 150-154 ; 15667367 (ISSN) ; Mohammadrezaei, A ; Asadi, M ; Golhosseini, R ; Naderifar, A ; Sharif University of Technology
2011
Abstract
In this paper, the effects of two methods of iridium impregnation into HZSM-5 on catalyst stability, selectivity for propylene and byproducts in the conversion of methanol to propylene (MTP) were investigated in a continuous flow isotherm fixed-bed reactor. XRD, BET surface area, NH 3-TPD and ICP-AES analytical techniques were applied to define the physical and chemical characteristics of zeolites. The reaction was conducted at 480°C and 1 bar with WHSV = 1 h -1, and with an equal weight percent of methanol and water in the feed. The results revealed that iridium impregnation into HZSM-5 powder led to enhanced propylene selectivity (8%) and catalyst stability while iridium impregnation into...
Finding Semi-Optimal Measurements for Entanglement Detection Using Autoencoder Neural Networks
, M.Sc. Thesis Sharif University of Technology ; Raeisi, Sadegh (Supervisor)
Abstract
Entanglement is one of the key resources of quantum information science which makes identification of entangled states essential to a wide range of quantum technologies and phenomena.This problem is however both computationally and experimentally challenging.Here we use autoencoder neural networks to find semi-optimal measurements for detection of entangled states. We show that it is possible to find high-performance entanglement detectors with as few as three measurements. Also, with the complete information of the state, we develop a neural network that can identify all two-qubits entangled states almost perfectly.This result paves the way for automatic development of efficient...
Numerical Analysis and Optimization of A Vortex Tube with Differential Evolution Algorithm
, M.Sc. Thesis Sharif University of Technology ; Mazaheri, Karim (Supervisor)
Abstract
The vortex tube is a simple device that injects compressed gas (air) tangentially into the vortex chamber through one or more injection nozzles. After entering, the flow becomes rotational and an axial cold flow goes towards the cold outlet and a peripheral hot flow goes towards the hot outlet. Besides all the different applications of the vortex tube, the main application of this device is cooling. Here, the goal is to optimize the geometry and physical conditions to improve the performance, which is done by using a commercial software and numerical analysis of a vortex tube to understand the flow physics and optimization. In this research, we use experimental and numerical data for...
Content Based Community Extraction in Social Networks from Stream Data
, M.Sc. Thesis Sharif University of Technology ; Abolhassani, Hassan (Supervisor)
Abstract
Increasing in social communication via electronic ways has been made social network analysis of these communications more important each day. One of the most important aspects in social network analysis is community detection in such networks. There are many different ways to extract communities from social graph structure which in some of them the content of communication between actors has been noticed in community extraction algorithm. In this thesis after a short survey over advantages and disadvantages of existing methods for community detection, a new method for extracting communities from social networks has been suggested which in addition to streaming property of data it spot the...
Quantum Information Processing with NMR Spectroscopy
, M.Sc. Thesis Sharif University of Technology ; Raeisi, Sadegh (Supervisor)
Abstract
Quantum Information Processing (QIP) is one of the active areas of research in both theoretical and experimental physics. Any experimental technique that is used for a scalable implementation of QIP must satisfy DiVincenzo’s criteria [17]. Nuclear Magnetic Resonance (NMR) satisfies many of these conditions, but it is not scalable and cannot initialize the qubits to pure state [28]. NMR can be a great platform for studying the fundamentals of QIP. In this project, for a twoqubit system, we prepare pseudo pure states from the initial mixed states by using unitary operations and implement CNOT gates. According to the results of our experiments, we can apply all the gates with high fidelity....
Natural convection from a confined horizontal cylinder: The optimum distance between the confining walls
, Article International Journal of Heat and Mass Transfer ; Volume 44, Issue 2 , 2001 , Pages 367-374 ; 00179310 (ISSN) ; Razi, Y. P ; Sharif University of Technology
2001
Abstract
The laminar natural convection from an isothermal horizontal cylinder confined between vertical walls, at low Rayleigh numbers, is investigated by theoretical, experimental and numerical methods. The height of the walls is kept constant, however, their distance is changed to study its effect on the rate of the heat transfer. Results are incorporated into a single equation which gives the Nusselt number as a function of the ratio of the wall distance to cylinder diameter, t/D, and the Rayleigh number. There is an optimum distance between the walls for which heat transfer is maximum. © 2000 Elsevier Science Ltd. All rights reserved
A coarse relative-partitioned index theorem
, Article Bulletin des Sciences Mathematiques ; Volume 153 , 2019 , Pages 57-71 ; 00074497 (ISSN) ; Esfahani Zadeh, M ; Sadegh, A ; Sharif University of Technology
Elsevier Masson SAS
2019
Abstract
It seems that the index theory for non-compact spaces has found its ultimate formulation in the realm of coarse spaces and K-theory of related operator algebras. Relative and partitioned index theorems may be mentioned as two important and interesting examples of this program. In this paper we formulate a combination of these two theorems and establish a partitioned-relative index theorem. © 2019 Elsevier Masson SAS
Simultaneous determination of gas–water relative permeability and capillary pressure from steady-state corefloods
, Article Journal of Hydrology ; Volume 598 , 2021 ; 00221694 (ISSN) ; Hemmati, N ; Behr, A ; Genolet, L ; Mahani, H ; Zeinijahromi, A ; Bedrikovetsky, P ; Sharif University of Technology
Elsevier B.V
2021
Abstract
For traditional calculations of relative phase permeability (Kr) from coreflood Steady-State Test (SST), the capillary pressure (Pc) is required. Usually, Pc is determined from a separate test, using a centrifuge or porous-plate methods. However, during SSTs, water cut and pressure drop are measured during the transition period between two sequential fractional-flow steps. We developed a novel method for simultaneous determination of Kr and Pc from SST by using both steady-state and transient data. In the proposed method, the transition data on the pressure drop across the core are used instead of the traditionally utilised Pc-curve. The main idea is that the stabilisation period during each...
Determining water-oil relative permeability and capillary pressure from steady-state coreflood tests
, Article Journal of Petroleum Science and Engineering ; Volume 205 , 2021 ; 09204105 (ISSN) ; Hemmati, N ; Behr, A ; Genolet, L ; Mahani, H ; Zeinijahromi, A ; Bedrikovetsky, P ; Sharif University of Technology
Elsevier B.V
2021
Abstract
This study aims at the simultaneous determination of relative permeability and capillary pressure from steady-state corefloods. Besides using the measurements of pressure-drop across the core and average saturation under steady-state conditions, we use the transient data between the sequential steady states. The inverse algorithm is based on four type curves “stabilizsation period versus water-cut” revealed by asymptotic analysis of the transient solution near end-point saturations, and on the exponential shape of transition data histories observed by direct numerical runs. The transition measurements are approximated in the stabilisation periods by the type curves using non-linear...