Sharif Digital Repository

In this study, transient 2D/axisymmetric simulations of cavitating flows are performed using a modified 'Volume-of-Fluid' (VOF) technique. Simulation of the cavitation is based on a homogenous equilibrium flow model. To predict the shape of the cavity, the Navier-Stokes equations in addition to an advection equation for the liquid volume fraction are solved. Mass transfer between the phases is treated as a sink term in the VOF equation. The numerical method is used for different geometries in a wide range of cavitation numbers. Computed shapes of cavities were found to be in good agreement with those of the reported experiments. The simulation results also compared well with those obtained... 

One of the most prominent hybrid solar devices is the photovoltaic thermal system (PVTS), which is able to provide simultaneous electricity and thermal energy. The thermal energy is the heat absorbed by the photovoltaic (PV) module and transferred to the attached thermal collector and finally to the heat transfer fluid. Utilizing a proper heat transfer fluid is an effective means to increase in obtained thermal and electrical powers and enhance PV thermal management. Over the past decade, employing nanofluids thanks to their superior thermophysical properties became a proved strategy to improve the efficiency of the PVTS. This paper covers cutting-edge researches on nanofluid-based PVTS via... 

One of the most prominent hybrid solar devices is the photovoltaic thermal system (PVTS), which is able to provide simultaneous electricity and thermal energy. The thermal energy is the heat absorbed by the photovoltaic (PV) module and transferred to the attached thermal collector and finally to the heat transfer fluid. Utilizing a proper heat transfer fluid is an effective means to increase in obtained thermal and electrical powers and enhance PV thermal management. Over the past decade, employing nanofluids thanks to their superior thermophysical properties became a proved strategy to improve the efficiency of the PVTS. This paper covers cutting-edge researches on nanofluid-based PVTS via... 

Due to size minimization and increment in the frequency of electronic devices, efficient and reliable methods for thermal management are required to reduce operating temperature, enhance stability, increase lifetime and user comfort. To prevent the damages of leakage and corrosion which occur in conventional heat sinks, proposing innovative thermal management methods has always been welcomed. Regarding these issues and based on the energy storage unit concept, in this study, a passive heat sink (HS) is fabricated and characterized for electronic chipset cooling with heat fluxes of 2000 to 4000 W/m2 utilizing phase change material (PCM) and nano-additive PCM (NPCM). The presented cooling... 

An efficient method is reported for selective oxidation of various types of sulfides to sulfoxides and sulfones in good to high yields using 30% H 2O2 in the presence of catalytic amounts of molybdate-based catalyst in acetonitrile as solvent at room temperature. The catalyst can be easily recovered and reused for seven reaction cycles without considerable loss of activity  

1-Butyl-3-methylimidazolium tungstate ([BMIm] 2WO 4) ionic liquid supported onto silica sulphamic acid demonstrated desirable performance for oxidation of cyclohexene to adipic acid. Simple experimental procedure, easy product isolation, catalyst recovery and reusability are some attractive features of this protocol  

TiO2 layers were grown via pulse type microarc oxidation process under different applied voltages, frequencies, and duty cycles. Surface chemical composition and phase structure of the synthesized layers were studied utilizing X-ray photoelectron spectroscopy (XPS) and X-ray diffraction (XRD). Furthermore, scanning electron microscope (SEM) and atomic force microscope (AFM) were employed to investigate surface morphology and topography of the layers. It was revealed that the layers had a porous structure with both anatase and rutile phases. The anatase relative content in the layers increased with the applied frequency; meanwhile, it decreased with duty cycle at low applied voltages, but... 

The application of electropulsing treatment (EPT) is studied on the microstructure and hardness of cold-rolled low carbon steel. The effects of electrical pulses on the grain refinement, precipitate size evolution and hardness are investigated. It is found that applying electrical pulse decreases the grain and precipitate size and increases the hardness in the early stages of electropulsing, but the grain and precipitate size is increased and the hardness is decreased by continuing electropulsing. Also, the effect of electropulsing treatment variables as well as treated time and number of periods are discussed. It is demonstrated that increasing treated time can accelerate achieving maximum... 

The B3LYP/6-311++G (d,p) density functional approach was used to study the gas-phase metal affinities of Guanosine (ribonucleoside) for the Li +, Na +, K +, Mg 2+, Ca 2+, Zn 2+, and Cu + cations. In this study we determine coordination geometries, binding strength, absolute metal ion affinities, and free energies for the most stable products. We have also compared the results for Guanosine, with our previously reported results for 20-Deoxyguanosine. Based on the results, it is obvious that MIA is strongly dependent on the charge-to-size ratio of the cation. Guanosine interacts more strongly with Zn 2+ than do with Mg 2+, Ca 2+, and Cu? and therefore stronger interactions lead to higher MIA.... 

Natural convection heat transfer in a concentric horizontal annulus with annular fins is numerically studied. Due to the low thermal conductivity of water, CuO-water and Al2O3-water nanofluids were used as heat transfer fluids. The effect of three different parameters, including fin spacing, fin eccentricity, and fin thickness at different fin diameters and Rayleigh number range of 104 to 9 (Formula presented.) 105, were studied. The obtained results revealed that Al2O3-water nanofluid has the highest heat transfer rate. The calculated heat transfer rates for Al2O3-water nanofluid for Rayleigh numbers of 9 (Formula presented.) 105, 105, and 104 were respectively up to 12.1%, 26.2%, and 31.6%... 

Natural convection heat transfer in a concentric horizontal annulus with annular fins is numerically studied. Due to the low thermal conductivity of water, CuO-water and Al2O3-water nanofluids were used as heat transfer fluids. The effect of three different parameters, including fin spacing, fin eccentricity, and fin thickness at different fin diameters and Rayleigh number range of 104 to 9 (Formula presented.) 105, were studied. The obtained results revealed that Al2O3-water nanofluid has the highest heat transfer rate. The calculated heat transfer rates for Al2O3-water nanofluid for Rayleigh numbers of 9 (Formula presented.) 105, 105, and 104 were respectively up to 12.1%, 26.2%, and 31.6%... 

Connecting your system or device to an insecure network can create the possibility of infecting by the unwanted files. Malware is every malicious code that has the potential to harm any computer or network. So, detecting harmful files is a crucial duty and an important role in any system. Machine learning approaches use a variety of features such as Opcodes, Bytecodes, and System-calls to achieve accurate malware identification. Each of these feature sets provides a unique semantic view, while, considering the effect of altogether is more reliable to detect attacks. Malware can disguise itself in some views, but hiding in all views will be much more difficult. Multi-View Learning (MVL) is an... 

One of the significant challenges in urbanization is the air pollution. This highlights the need of the green city concept with reconsideration of houses, factories, and traffic in a green viewpoint. The literature review confirms that this reconsideration for green space has a positive effect on the air quality of large cities and to reduce the air pollution. The purpose of this study is to evaluate the annual vegetation changes in the green space of Mashhad, Iran as a very populated city in the middle east to study the air pollution. To investigate the relationship between the air pollution and vegetation, the Landsat 8 satellite images for summer seasons of 2013–2019 were used to extract... 

One of the significant challenges in urbanization is the air pollution. This highlights the need of the green city concept with reconsideration of houses, factories, and traffic in a green viewpoint. The literature review confirms that this reconsideration for green space has a positive effect on the air quality of large cities and to reduce the air pollution. The purpose of this study is to evaluate the annual vegetation changes in the green space of Mashhad, Iran as a very populated city in the middle east to study the air pollution. To investigate the relationship between the air pollution and vegetation, the Landsat 8 satellite images for summer seasons of 2013–2019 were used to extract... 

Influence of the addition of water molecules (n = 1-6) on the interaction energy between Li +, Na +, K + cations and indole molecule as tryptophan amino acid residue is considered at MP2(FULL)/6-311++G(d, p)//B3LYP/6-311++G(d,p) levels of theory. The calculations suggest that the size of cation and the number of water molecules are two important factors that affect the interaction energy between the hydrated metal cation and indole molecule. The strength of cation-π interactions get substantially reduced when the metal ion is solvated or the size of metal cation increases. Quantum theory of atoms in molecules analysis of cation-π interaction indicates that there is a correlation between the... 

Density functional theory method and B3LYP/6-311++G(d,p) level of theory were used to determine the acidity of alkyl sulfonic acids and polyolalkyl sulfonic acids in the gas and solution (H2O, DMSO, and CH 3CN) phase. Polarized continuum model was applied to calculate pKa values of alkyl sulfonic acids and polyolalkyl sulfonic acids. A comparison between acidity of alkyl sulfonic acids and polyolalkyl sulfonic acids in the gas and solution phase indicates that the acidity strength of polyolalkyl sulfonic acids enhances with the increase of the cooperativity effect of intramolecular hydrogen bonds in polyolalkyl sulfonic acids. Natural bond orbital and quantum theory of atoms in molecules... 

The optimized minimum-energy geometries of different macrocyclic amines and their protonated structures were determined by using ab initio and density functional theory (DFT) calculations. All the gas phase optimizations and energy calculations were performed at the DFT/B3LYP/6-311++G(d,p) level of theory. The HF/6-31 + G(d,p) level was used for all single point calculations in the solution phase. Geometry optimizations indicate that the most stable structures are stabilized by intramolecular hydrogen bonds. The proton affinity (PA) of macrocyclic amines is controlled by the strength of intramolecular hydrogen bonds of macrocyclic amines. These hydrogen bonds strongly influence the basicity... 

Horizontal ground heat exchangers (GHEs) have a lower initial installation cost in comparison to vertical ones; however, they require more land area. In order to reduce the required land area of horizontal GHEs, their heat exchange rate per unit land area needs to be enhanced. A remedy to this problem is installing horizontal GHEs in an arrangement with maximum heat exchange rate per unit land area. However, such arrangements have not been introduced for different types of horizontal GHEs thus far. To this end, in this study, the thermal performance of various GHE pipe arrangements for three different types (linear, spiral, and slinky) of horizontal GHEs is evaluated. Comparing the obtained... 

In an attempt to prolong the performance of the conventional Solar Chimney (SC) and enhance its efficiency, this contribution presents a kind of novel compound SC with the Photovoltaic (PV) module and Phase Change Material (PCM) called the SC-PV-PCM system. Using PCM not only improves the PV module performance but also extends the productive period of the SC. A three-dimensional quasi-steady computational fluid dynamics (CFD) model of the proposed system is developed. The developed model is used to investigate the effect of using PCMs with different melting points on the performance of the proposed system. It is demonstrated that the RT-50 provides superior performance among the studied...