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A kinetic study of facile fabrication of MIL-101(Cr) metal-organic framework: effect of synthetic method
, Article Inorganica Chimica Acta ; Volume 471 , 2018 , Pages 513-520 ; 00201693 (ISSN) ; Kazemeini, M ; Sharif University of Technology
Elsevier S.A
2018
Abstract
MIL-101(Cr) metal–organic framework samples were successfully synthesized through the conventional electrical heating (CE), ultrasound (US), and microwave (MW) synthetic methods at three different temperatures and various synthesis times. These were done with the aim of understudying the crystallization kinetics of these complex MIL's structures. The nucleation and crystal growth steps were thus, quantified through measuring the relative crystallinity of the prepared MIL-101(Cr) utilizing the PXRD and FESEM analysis under various synthesis conditions. In addition, the textural properties of the fully crystallized samples measured through the N2 adsorption–desorption isotherms at 77 K. The...
Embedding graphene nanoplates into MIL-101(Cr) Pores: synthesis, characterization, and CO2 adsorption studies
, Article Industrial and Engineering Chemistry Research ; Volume 56, Issue 14 , 2017 , Pages 3895-3904 ; 08885885 (ISSN) ; Kazemeini, M ; Vafajoo, L ; Sharif University of Technology
2017
Abstract
In this research, the equilibrium and dynamic adsorption studies of the CO2 upon the MIL-101(Cr) metal-organic framework (MOF) as well as its GNP hybrid composites, the MIL-101(Cr)/GNP, were performed. First, the hybrid composite samples were synthesized by adding various amounts of GNP in an in situ manner during the preparation of the MIL-101(Cr). The prepared materials were characterized through several physicochemical analyses, including powder X-ray diffraction (PXRD), adsorption of nitrogen at 77.4 K, Fourier transfer infrared (FT-IR) spectroscopy, thermal analysis (DTG), and field emission scanning electron microscopy (FESEM). It was demonstrated that the synthesized MIL-101(Cr)/GNP...
Removal of the CO2 from flue gas utilizing hybrid composite adsorbent MIL-53(Al)/GNP metal-organic framework
,
Article
Microporous and Mesoporous Materials
;
Volume 218
,
2015
,
Pages 144-152
;
13871811 (ISSN)
; Kazemeini, M
; Ganji Babakhani, E
; Taheri, A
;
Sharif University of Technology
Elsevier
2015
Abstract
Abstract In this study, adsorption of the CO2 and N2 gases on the MIL-53(Al) and its hybrid composite with the graphene nano-plates (GNP), MIL-53(Al)/GNP, adsorbents were investigated. These materials were synthesized using the solvothermal reaction method. The prepared samples were characterized by means of the powder X-ray diffraction (PXRD), field emission scanning electron microscopy (FESEM), N2 adsorption-desorption isotherms (BET-BJH surface area measurement) and Fourier transfer infrared (FT-IR) spectroscopy methods as well as; thermogravimetric analysis (TGA). Adsorption equilibrium of the CO2 and N2 on the sorbents were...
The Removal of CO2 from Flue Gas by Using MOF/Graphene Hybrid Adsorbents
, M.Sc. Thesis Sharif University of Technology ; Kazemeini, Mohammad (Supervisor) ; Ganji, Ensieh (Supervisor) ; Bozorgzadeh, Hamid Reza ($item.subfieldsMap.e)
Abstract
Due to the increase in greenhouse gases in earth’s atmosphere in recent years and its devastating environmental outcomes, there has been an increase in research trying to reduce these gases especially CO2. Flue gas is one of the most important sources of CO2 emission. Among the many techniques of removal, capturing and CO2 separation from flue gas, physical adsorption by a solid adsorbent is considered as a suitable and economic option. Among the solid adsorbent that are used for adsorption of CO2, Metal-Organic frameworks have many interesting features such as high specific surface area and high internal free volume. Among the Metal-Organic frameworks, MIL-53 (Al) and MIL-101 (Cr) are two...
The relationship between an EFL teacher's gender and students' willingness to communicate
, Article International Journal of Communication and Linguistic Studies ; Volume 10, Issue 4 , 2013 , Pages 17-29 ; 23277882 (ISSN) ; Pakzadian, S. S
Common Ground Publishing
2013
Abstract
Learning a foreign language encompasses a process of trial and error that can lead to the progression of the learner's interlanguage, meaning that the learners make use of their language knowledge that receives feedback and brings about progress through diagnosis of the problems and being corrected by the teacher. Therefore, there exists a need to analyze the underlying reasons causing the students to remain taciturn with a low willingness to communicate (WTC) during a language class. There has been much work done investigating the role of the learner's stable personal characteristics (traits) along with their situational changes at a specific time (states) that influence the student's...
An automated simple algorithm for realistic pore network extraction from micro-tomography images
, Article Journal of Petroleum Science and Engineering ; Vol. 123, issue , 2014 , pp. 164-171 ; ISSN: 09204105 ; Jamshidi, S ; Salehi, S
2014
Abstract
Using 3-D scanned data to analyze and extract pore network plays a vital role in investigation of porous media's characteristics. In this paper, a new simple method is developed to detect pores and throats for analyzing the connectivity and permeability of the network. This automated method utilizes some of the common and well-known image processing functions which are widely accessible by researchers and this has led to an easy algorithm implementation. In this method, after polishing and quality control of images, using city-block distance function and watershed segmentation algorithm, pores and throats are detected and 3-D network is produced. This method can also be applied on 2-D images...
Discrimination of heart arrhythmias using novel features in heart rate phase space
, Article Computing in Cardiology ; Volume 40 , Sept , 2013 , Pages 1035-1038 ; 23258861 (ISSN); 9781479908844 (ISBN) ; Rezaei, S ; Salavatian, S
2013
Abstract
In this paper, we try to recognize and distinguish different groups of arrhythmia using novel features which have been obtained from the heart rate's phase space in recent years. For this purpose, we used Triangular Phase Space Mapping (TPSM) and Parabolic Phase Space Mapping (PPSM). For recognition, we used three groups of 15 subjects using the Physionet database (Arrhythmia, Congestive Heart Failure (CHF), and Atrial Fibrillation (AF)) with Normal Sinus Rhythm (NSR). The obtained features discriminate arrhythmia from NSR by p
An intelligent hybrid classification algorithm integrating fuzzy rule-based extraction and harmony search optimization: Medical diagnosis applications
, Article Knowledge-Based Systems ; Volume 220 , 2021 ; 09507051 (ISSN) ; Abdullah, S ; Akhavan Niaki, S. T ; Banihashemi, S ; Sharif University of Technology
Elsevier B.V
2021
Abstract
Uncertainty is a critical factor in medical datasets needed to be overcome for increasing diagnosis efficiency. This paper proposes an intelligent classification algorithm comprising a fuzzy rule-based approach, a harmony search (HS) algorithm, and a heuristic algorithm to classify medical datasets intelligently. Two fuzzy approaches, as well as orthogonal and triangular fuzzy sets, are first utilized to define the attributes of data. Then, an HS algorithm is integrated with a heuristic to generate fuzzy rules to select the best rules in the fuzzy rule-based systems. Moreover, to improve the performance of the proposed classification approach, a three-phase parameter tuning approach is...
Performance evaluation of shared hosting security methods
, Article Proc. of the 11th IEEE Int. Conference on Trust, Security and Privacy in Computing and Communications, TrustCom-2012 - 11th IEEE Int. Conference on Ubiquitous Computing and Communications ; 2012 , Pages 1310-1315 ; 9780769547459 (ISBN) ; Arshad, S ; Khoshkdahan, S ; Sharif University of Technology
2012
Abstract
Shared hosting is a kind of web hosting in which multiple websites reside on one webserver. It is cost-effective and makes the administration easier for websites' owners. However, shared hosting has some performance and security issues. In default shared hosting configuration, all websites' scripts are executed under the webserver's user account regardless of their owners. Therefore, a website is able to access other websites' resources. This security problem arises from lack of proper isolation between different websites hosted on the same webserver. In this survey, we have examined different methods for handling mentioned security issue. Also we evaluated the performance of mentioned...
The behaviour of an artificially cemented sandy gravel
, Article Geotechnical and Geological Engineering ; Volume 23, Issue 5 , 2005 , Pages 537-560 ; 09603182 (ISSN) ; Hosseini, S. M ; Toll, D. G ; Yasrebi, S. S ; Sharif University of Technology
2005
Abstract
The major section of the city of Tehran, Iran has been developed on cemented coarse-grained alluvium. This deposit consists of gravely sand to sandy gravel with some cobbles and is dominantly cemented by carbonaceous materials. In order to understand the mechanical behaviour of this soil, a series of undrained triaxial compression tests and unconfined compression tests were performed on uncemented and artificially cemented samples. Portland cement type I was used as the cementation agent for preparing artificially cemented samples. Uncemented samples and lightly cemented samples (1.5% cement) tested at high confining pressure showed contractive behaviour accompanied with positive excess pore...
An imperialist competitive algorithm approach for multi-objective optimization of direct coupling photovoltaic-electrolyzer systems
, Article International Journal of Hydrogen Energy ; Vol. 39, Issue 33 , 11 November , 2014 , pp. 18743-18757 ; ISSN: 03603199 ; Sayedin, F ; Khavas, S. S
2014
Abstract
In the context of sustainable clean hydrogen production pathways, photovoltaic-electrolyzer systems are one of the most promising alternatives for acquiring hydrogen from renewable energy sources. In fact, determining the optimal set of design and operating variables are always a key issue while coupling directly renewable electricity sources to PEM electrolyzers. Few previous studies have attempted to find the optimal size and operational condition of directly coupled photovoltaic-electrolyzer (PV/El) systems in order to maximize the hydrogen production or to minimize energy transfer loss between photovoltaic devices and the electrolyzer. Nevertheless an easy and efficient approach still...
Kalman filter based packet loss replacement in presence of additive noise
, Article 2012 25th IEEE Canadian Conference on Electrical and Computer Engineering: Vision for a Greener Future, CCECE 2012 ; 2012 ; 9781467314336 (ISBN) ; Ghorshi, S ; Tahaei, A
2012
Abstract
A major problem in real-time packet-based communication systems, is misrouted or delayed packets which results in degraded perceived voice quality. If packets are not available on time, the packets are considered as lost. The easiest solution in a network terminal receiver is to replace silence for the duration of lost speech segments. In a high quality communication system, to avoid degradation in speech quality due to packet loss, a suitable method or algorithm is needed to replace the missing segments of speech. In this paper, we introduce an adaptive filter for replacement of lost speech segment. In this method Kalman filter as a state-space based method will be used to predict the...
Investigation of Mesh Sensitivity Influence to Determine Crack Characteristic by Finite Element Methods
, Article Journal of Failure Analysis and Prevention ; Volume 16, Issue 3 , 2016 , Pages 506-512 ; 15477029 (ISSN) ; Mirjavadi, S. S ; Asli, S. A ; Sharif University of Technology
Springer New York LLC
2016
Abstract
In this research, an extended finite element model has been investigated. Investigation of opening and closure stress always has been one of the difficult parameters to analysis of results; therefore, the utilization of finite element methods would be a good and logical alternative for this purpose. In addition, linear elastic fracture criteria are used for validation of numerical results from the simulation. In this work, a detailed analysis of the influence of different parameters in the results of a specific specimen with a semi-elliptical tooling groove in terms of closure and opening stress is presented, and the impact of optimum element size in fracture characteristic in various load...
Investigation of the effect of nanosilica on rheological, thermal, mechanical, structural, and piezoelectric properties of poly(vinylidene fluoride) nanofibers fabricated using an electrospinning technique
, Article Industrial and Engineering Chemistry Research ; Volume 56, Issue 44 , 2017 , Pages 12596-12607 ; 08885885 (ISSN) ; Ahmad Ramazani, S. A ; Talebi, S ; Fattahpour, S ; Hasany, M ; Sharif University of Technology
2017
Abstract
The effects of different nano-SiO2 contents on the rheological properties of poly(vinylidene fluoride) (PVDF) solution and mechanical, thermal, structural, and piezoelectric properties of composite nanofibers were investigated. Results showed an increase in fiber diameter (∼125 to 350 nm) and ∼450% increase in tensile strength as the content of nano-SiO2 particles increased. The degree of crystallinity decreased by 19% as the nano-SiO2 content increased by 2% (w/w). Further investigation demonstrated that silica could significantly improve the piezoelectric properties of PVDF nanofibers as the output voltage showed an increase in the presence of silica attributed to change in the crystalline...
A method for real-time safe navigation in noisy environments
, Article 2013 18th International Conference on Methods and Models in Automation and Robotics, MMAR 2013, Miedzyzdroje ; 2013 , Pages 329-333 ; 9781467355063 (ISBN) ; Kamali, E ; Niknezhad, M. R ; Monfared, S. S. M. S ; Sharif University of Technology
2013
Abstract
The challenge of finding an optimized and reliable path dates back to emersion of mobile robots. Several approaches have been developed that have partially answered this need. Satisfying results in previous implementations has led to an increased utilization of sampling-based motion planning algorithms in recent years, especially in high degrees of freedom (DOF), fast evolving environments. Another advantage of these algorithms is their probabilistic completeness that guarantees delivery of a path in sufficient time, if one exists. On the other hand, sampling based motion planners leave no comment on safety of the planned path. This paper suggests biasing the Rapidly-exploring Random Trees...
A generalization of the swartz equality
, Article Glasgow Mathematical Journal ; Vol. 56, issue. 2 , May , 2014 , pp. 381-386 ; ISSN: 00170895 ; Fakhari, S. A. S ; Yassemi, S ; Sharif University of Technology
2014
Abstract
For a given (d-1)-dimensional simplicial complex Γ, we denote its h-vector by h(Γ)=(h 0(Γ),h 1(Γ),...,hd (Γ)) and set h -1(Γ)=0. The known Swartz equality implies that if Δ is a (d-1)-dimensional Buchsbaum simplicial complex over a field, then for every 0 ≤ i ≤ d, the inequality ihi (Δ)+(d-i+1)h i-1(Δ) ≥ 0 holds true. In this paper, by using these inequalities, we give a simple proof for a result of Terai (N. Terai, On h-vectors of Buchsbaum Stanley-Reisner rings, Hokkaido Math. J. 25(1) (1996), 137-148) on the h-vectors of Buchsbaum simplicial complexes. We then generalize the Swartz equality (E. Swartz, Lower bounds for h-vectors of k-CM, independence, and broken circuit complexes, SIAM J....
Hardware-in-the-loop optimization of an active vibration controller in a flexible beam structure using evolutionary algorithms
, Article Journal of Intelligent Material Systems and Structures ; Vol. 25, issue. 10 , 2014 , p. 1211-1223 ; Hosseini Kordkheili, S. A ; Afshari, S. S ; Sharif University of Technology
2014
Abstract
In this study, active vibration control of a cantilevered flexible beam structure equipped with bonded piezoelectric sensor/actuators is investigated. The linear quadratic regulator technique together with an observer is adopted to design the controller as well as to provide the full-state feedback. Two different approaches are subsequently used for simultaneously integrated optimization of the controller and observer parameters. In the first approach, a linear experimental model of the system is obtained using identification techniques, and the optimization is then performed based on a computer simulation of the system. However, in the second approach, a hardware-in-the-loop optimization...
An efficient inference in meanfield approximation by adaptive manifold filtering: (Machine learning & data mining)
, Article Proceedings of the 4th International Conference on Computer and Knowledge Engineering, ICCKE 2014 ; 2014 , p. 581-585 ; Ramezanpur, S ; Kasaei, S ; Sanaei, E ; Sharif University of Technology
2014
Abstract
A new method for speeding up the approximate maximum posterior marginal (MPM) inference in meanfield approximation of a fully connected graph is introduced. Weight of graph edges is measured by mixture of Gaussian kernels. This fully connected graph is used for segmentation of image data. The bottleneck of the inference in meanfield approximation is where the similar bilateral filtering is needed for updating the marginal in the message passing step. To speed up the inference, the adaptive manifold high dimensional Gaussian filter is used. As its time complexity is 0(ND), it leads to accelerating the marginal update in the message passing step. Its time complexity is linear and relative to...
Dominating coloring number of claw-free graphs
, Article Electronic Notes in Discrete Mathematics ; Vol. 45, issue , January , 2014 , pp. 91-97 ; ISSN: 15710653 ; Akbari, S ; Hossein Ghorban, S ; Qajar, S ; Sharif University of Technology
2014
Abstract
Let G be a graph. It is well-known that G contains a proper vertex-coloring with χ(G) colors with the property that at least one color class of the coloring is a dominating set in G. Among all such proper vertex-coloring of the vertices of G, a coloring with the maximum number of color classes that are dominating sets in G is called a dominating-χ-coloring of G. The number of color classes that are dominating sets in a dominating-χ-coloring of G is defined to be the dominating-χ-color number of G and is denoted by dχ(G). In this paper, we prove that if G is a claw-free graph with minimum degree at least two, then dχ(G)≥2
A hybrid root transformation and decision on belief approach to monitor multiattribute Poisson processes
, Article International Journal of Advanced Manufacturing Technology ; Volume 75, Issue 9-12 , December , 2014 , Pages 1651-1660 ; ISSN: 02683768 ; Javadi, S ; Fallahnezhad, M. S ; Sharif University of Technology
2014
Abstract
Most of industrial applications of statistical process control involve more than one quality characteristics to be monitored. These characteristics are usually correlated, causing challenges for the monitoring methods. These challenges are resolved using multivariate quality control charts that have been widely developed in recent years. Nonetheless, multivariate process monitoring methods encounter a problem when the quality characteristics are of the attribute type and follow nonnormal distributions such as multivariate binomial or multivariate Poisson. Since the data analysis in the latter case is not as easy as the normal case, more complexities are involved to monitor multiattribute...